收藏切换
Preparation and Thermal Conductivity of Carbon Nanotubes Modified Silicon-Containing Polyarylacetylene Resin
收藏切换
PDF
Yuqiao WANG, Qiaolong YUAN, Farong HUANG
Insulating Materials | 2021, 54(10) : 33 - 40
Less
收藏切换
Insulating Materials | 2021, 54(10): 33-40
Material Research
Preparation and Thermal Conductivity of Carbon Nanotubes Modified Silicon-Containing Polyarylacetylene Resin
Full
Yuqiao WANG, Qiaolong YUAN, Farong HUANG
Affiliations
  • Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
Published: 2021-10-20 doi: 10.16790/j.cnki.1009-9239.im.2021.10.005
Outline
收藏切换

A triethoxyacetylenic silane (TEOAS) was synthesized to treat the surface of hydroxylated multiwalled carbon nanotubes (MWCNTs), and then the MWCNTs-T was obtained and characterized. PSA/MWCNTs and PSA/MWCNTs-T composite resins were prepared using solution method by mixing silicon-containing polyarylacetylene (PSA) with MWCNTs and MWCNTs-T, respectively. The thermal conductivity, thermal stability, electric insulation, and bending properties of the PSA/MWCNTs and PSA/MWCNTs-T composites were investigated. The results show that TEOAS was grafted on the surface of MWCNTs successfully, and MWCNTs-T is compatible with PSA matrix. The thermal conductivity of the composites increases with the increase of the mass fraction of MWCNTs and MWCNTs-T. The effect of MWCNTs-T is more obvious, with the mass fraction of 2%, the thermal conductivity of PSA/MWCNTs-T reaches 0.62 W/(m·K), which is 3 times as higher as that of PSA. The introduction of MWCNTs and MWCNTs-T can decrease the thermal stability and bending properties of PSA, the effect of MWCNTs-T is smaller than that of MWCNTs. The glass transition temperature of the PSA/MWCNTs is higher than 500℃, the electrical resistivity of the composite resin decreases linearly with the increase of frequency, while is still higher than 108 Ω·cm at 106 Hz.

silicon-containing polyarylacetylene  /  triethoxyacetylenic silane  /  multiwall carbon nanotube  /  thermal conductivity  /  thermophysical property
Yuqiao WANG, Qiaolong YUAN, Farong HUANG. Preparation and Thermal Conductivity of Carbon Nanotubes Modified Silicon-Containing Polyarylacetylene Resin[J]. Insulating Materials, 2021 , 54 (10) : 33 -40 . DOI: 10.16790/j.cnki.1009-9239.im.2021.10.005
Year 2021 volume 54 Issue 10
PDF
87
35
Cite this Article
BibTeX
Article Info
doi: 10.16790/j.cnki.1009-9239.im.2021.10.005
  • Receive Date:2020-12-24
  • Online Date:2026-03-23
  • Published:2021-10-20
Article Data
Affiliations
History
  • Received:2020-12-24
  • Revised:2021-04-14
Funding
Affiliations
    Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
References
Share
https://castjournals.cast.org.cn/joweb/jycl/EN/10.16790/j.cnki.1009-9239.im.2021.10.005
Share to
QR

Scan QR to access full text

Cite this article
BibTeX
Citations
表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
关闭全屏
  • BibTeX
  • EndNote
  • RefWorks
  • TxT