In order to find out the effect of adding nano-SiO2 on the relative permittivity and conduction characteristic of ethylene propylene diene monomer (EPDM) insulation, we prepared EPDM composite dielectrics with different mass fractions of nano-SiO2 by melt-blending method. The dispersion of nanoparticles in the EPDM matrix and the bonding properties between nanoparticles and EPDM matrix were analyzed. The relative permittivity and the steady-state current of the EPDM nanocomposite dielectrics at different temperatures and electric fields were measured, and the conductance characteristic were analyzed. The results show that when the mass fraction of nano-SiO2 is 0.5%, the dispersion of nano-SiO2 is the best in EPDM. The steric hindrance, which formed by doping of low content, reduces the mobility of the EPDM molecular segments and its side groups, and the interface effect is obvious in the nanocomposite dielectrics, making the relative permittivity and conductance decrease, the threshold electric field strength of space charge injection enhance, the insulating performance improve significantly. With the increase of the mass fraction, the interface effect between nanoparticles and EPDM matrix is weakened. When the mass fraction of nano-SiO2 is 2.5% or 5.0%, the agglomeration caused by doping makes the relative permittivity and the conductance increase, and the threshold electric field strength of space charge injection decreases. The interface effect caused by the addition of nano-SiO2 is a key factor affecting the properties of EPDM nanocomposite dielectrics.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |