In order to study the performance changes of irradiation crosslinking low-smoke halogen-free flame-retardant insulation layer and sheath layer for photovoltaic cables before and after getting moistened, the insulation layer and sheath layer of photovoltaic cable with various water-immersion time were conducted mechanical properties, thermal extensibility, dynamic thermomechanical analysis (DMA), Fourier transform infrared spectroscopy (FTIR), and volume resistivity tests. The results show that the long-term water-immersion causes hydrolysis of molecular chains in the material, and the entanglement of molecular chains weakens, which lead to decrease of tensile properties of samples. After water-immersion, the initial storage modulus of the insulation layer and sheath layer samples decreases, the adhesion force between filler particles and matrix resin decreases, and the mechanical loss peak of the insulation layer presents double peaks characteristic. With the increase of moistening degree, the EVA in the polyolefin matrix swells, and the free volume increases. Some flame retardant fillers are separate from the binding of matrix and become impurity ions, making the carrier concentration and mobility increase, which leads to continuous decrease of volume resistivity.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |