To meet the growing demand for high thermal conductive and electrically insulating composites, a silver nanoparticles (AgNPs) modified nonwoven fabric (AgNPs@NWF) was prepared by polydopamine (PDA) modification and in situ reduction process using PET nonwoven fabric (NWF) as a template. The continuous boron nitride nanosheets (BNNS) thermal conductive network (BNNS@NWF) and AgNPs/BNNS synergistic thermal conductive network (AgNPs/BNNS@NWF) were constructed by adsorbing BNNS on the surfaces of NWF and AgNPs@NWF through the dispersion and interfacial bonding of nanocellulose through a cyclic impregnation adsorption and layer-by-layer assembly process. BNNS-AgNPs/BNNS-BNNS sandwich-structured thermal conductive composite films were prepared by hot pressing process with BNNS@NWF as the surface layer and AgNPs/BNNS@NWF as the intermediate layer, and their microstructure, thermal conductivity, insulating properties, mechanical properties, and actual thermal management performance is characterized and tested. The results show that a synergistic three-dimensional thermal conductive network of AgNPs/BNNS was constructed in the composite films, at the same time the insulating properties are ensured. When the mass fraction of BNNS and AgNPs is 34.8% and 3.3%, the in-plane thermal conductivity of the composite films reaches 7.56 W/(m·K), the volume resistivity reaches 3.54×1013 Ω·cm, and the mechanical properties is good. The actual application test show that the composite films have good thermal management performance.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |