TiO2 nanoparticles surface modified with acetic acid, hexanoic acid, and oleic acid were synthesized via liquid-phase method and used to prepared modified transformer oils. The morphology and surface modification state of the nanoparticles were measured by transmission electron microscope (TEM) and Fourier infrared spectroscopy (FTIR). The positive impulse breakdown voltage and streamer development pattern of the transformer oil before and after modification were tested, and the effect of nanoparticle surface modification on the breakdown performance of transformer oil was studied. The results show that the surface modified nanoparticles greatly improve the positive impulse breakdown voltage of transformer oil, and significantly prolong the breakdown time. Among them, the acetic acid modified nanoparticles have the best modification effect, which increases the impulse breakdown voltage from 84.73 kV of pure oil to 116.42 kV, an increase of 37.4%, and the breakdown time is extended to 1.86 times that of pure oil. The surface modification of nanoparticles greatly increases the shallow trap density in the oil, changes the streamer propagation pattern, significantly inhibits the development speed of streamer, and thus improves the impulse breakdown properties of the transformer oil.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |