Organic-inorganic composite dielectrics are often difficult to have both high dielectric constant and high electric strength. In this paper, a sandwich structured composite film was prepared by using aramid nanofibers (ANF) as high-temperature resistant matrix, boron nitride nanosheets (BNNS) as electrical breakdown enhancer, and barium titanate particles (BT) as dielectric modifier through step-by-step vacuum filtration and hot-pressing method, and the effects of sandwich structure and different modifier content on the microstructure and dielectric properties of the composite films were studied. The results show that the sandwich structured composite films have high flexibility and excellent high-temperature stability. The addition of BT decreases the electric strength of single layer and sandwich structured composite films, while the addition of BNNS increases the electric strength of the composite films. The individual addition of BT or BNNS can increase the dielectric constant of composite films at low frequency, while the simultaneous addition of BT and BNNS can increase the dielectric constant in wide frequency domain. Therefore, a composite film with balanced dielectric properties and electric strength can be obtained by adjusting the sandwich structure and modifier content in each layer. When taking the ANF/BNNS film with 10% mass fraction of BNNS as the outer layer and the ANF/BT film with 10% mass fraction of BT as the core layer, the dielectric constant, dielectric loss factor, and electric strength of the prepared composite film is 1.41 (1 kHz), 0.013 (1 kHz), and 13.3 kV/mm, respectively.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |