In this paper, a novel semi-interpenetrating network material PVP/p(HEMA-co-BA) was synthesized by free radical polymerization of 2-hydroxyethyl methacrylate (HEMA), butylacrylate (BA), polyvinyl pyrrolidone (PVP), and host-guest interaction complex which was synthesized by recognition and free radical copolymerization using cyclodextrin modified aluminium oxide nanoparticles (CD-Al2O3NPS) as host molecules and acrylate containing adamantane as guest molecules. The microstructure and properties of PVP/p(HEMA-co-BA) were characterized and tested. The results show that the material has self-repairing property by the interaction of host and guest materials. And the introduction of two reversible non-covalent interactions host-guest interaction and hydrogen bond gives the material excellent shape memory function. With the shape memory and self-repair capability, the material can repair by itself and recover the original property when the distance between the two sections of the crack is large. In addition, PVP/p(HEMA-co-BA) has good thermal stability and can be used at 200℃ in high temperature environment.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |