The problem of nanoparticle agglomeration in wire enamel can be solved by modification and gradual dispersion of nanoparticles. Five modifiers, emulsifier OP-10, silane coupling agent AP1231, silane coupling agent A112, γ-propyl trimethoxysilane (KH560), and N-[3-(trimethoxysilyl) propyl] ethylenediamine (KH-792), were used to modify the surface of nano silica particles. The effects of modifier type, modifier dosage, modification temperature and time on the modification effect of nano-SiO2 particles were explored. The effects of nano-SiO2 particles before and after modification on the performance of corona resistant wire enamel were compared by corona resistance test, and the dispersion of nano-SiO2 particles before and after modification was observed by transmission electron microscopy (TEM). The results indicate that the nanoparticles modified by KH-560 have the best dispersion in wire enamel, and the best process conditions are as follows: the dosage of KH-560 is 1.5wt%, the modification temperature is 90℃, and the modification time is 4 h. The wire enamel with high stability and higher than 50 h of corona resistance time can be obtained by gradually dispersing modified nanoparticles into the wire enamel, and the appropriate addition amount of nanoparticles is 13.5wt%.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |