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Analysis on pyrolysis kinetics of epoxy resin impregnated paper
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Yuanxiang ZHOU1, 2, Bo ZHONG1, Yuhang LI2, Zheng BAI2, Xin HUANG2, Jianning CHEN2, Guimin JIANG1
Insulating Materials | 2025, 58(4) : 117 - 125
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Insulating Materials | 2025, 58(4): 117-125
Test and Analysis
Analysis on pyrolysis kinetics of epoxy resin impregnated paper
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Yuanxiang ZHOU1, 2, Bo ZHONG1, Yuhang LI2, Zheng BAI2, Xin HUANG2, Jianning CHEN2, Guimin JIANG1
Affiliations
  • 1 The Wind Solar Storage Division of State Key Laboratory of Control and Simulation of Power System and Generation Equipment, School of Electrical Engineering, Xinjiang University, Urumqi 830047, China
  • 2 State Key Laboratory of Control and Simulation of Power Systems and Generation Equipment, Department of Electrical Engineering, Tsinghua University, Beijing 100084, China
Published: 2025-04-20 doi: 10.16790/j.cnki.1009-9239.im.2025.04.015
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As a key device in ultra-high voltage and extra-high-voltage transmission projects, the deflagrate accidents of bushings seriously threaten the safe and stable operation of the power system. Adhesive impregnated paper bushing is an alternative to oil-impregnated paper bushings with deflagration risks, while there is relatively little research on the thermodynamic behavior of its core insulating material of epoxy resin impregnated paper during arc faults and the risk of bushing deflagration. In this paper, the thermogravimetric experiments and differential scanning calorimetry analysis at different heating rates were conducted on epoxy resin impregnated paper, and its thermal decomposition process was analyzed. Flynn-Wall-Ozawa (FWO) method and Coast-Redfern (CR) method were used to obtain the pyrolysis kinetic models of epoxy resin impregnated paper at high temperature in an oxygen-free environment. The results show that the thermal decomposition process of epoxy resin impregnated paper in adhesive impregnated paper bushing can be divided into three stages: epoxy melting, endothermic reactions, and decomposition gasification, and the first two stages conform to three-dimensional diffusion model, random nucleation and subsequent growth model, respectively. After an arc breakdown fault occurs in bushing cores, the thermal decomposition mass loss of epoxy resin impregnated paper is as high as 90% under the effect of high temperature. The high temperatures and gas expansion produce high amplitude internal stress inside the core, which leads to core cracking and even explosion.

dry-type bushing  /  epoxy resin impregnated paper  /  pyrolysis process  /  pyrolysis kinetics
Yuanxiang ZHOU, Bo ZHONG, Yuhang LI, Zheng BAI, Xin HUANG, Jianning CHEN, Guimin JIANG. Analysis on pyrolysis kinetics of epoxy resin impregnated paper[J]. Insulating Materials, 2025 , 58 (4) : 117 -125 . DOI: 10.16790/j.cnki.1009-9239.im.2025.04.015
Year 2025 volume 58 Issue 4
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doi: 10.16790/j.cnki.1009-9239.im.2025.04.015
  • Receive Date:2024-05-03
  • Online Date:2025-11-07
  • Published:2025-04-20
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  • Received:2024-05-03
  • Revised:2024-06-24
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Affiliations
    1 The Wind Solar Storage Division of State Key Laboratory of Control and Simulation of Power System and Generation Equipment, School of Electrical Engineering, Xinjiang University, Urumqi 830047, China
    2 State Key Laboratory of Control and Simulation of Power Systems and Generation Equipment, Department of Electrical Engineering, Tsinghua University, Beijing 100084, China
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https://castjournals.cast.org.cn/joweb/jycl/EN/10.16790/j.cnki.1009-9239.im.2025.04.015
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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