In order to suppress surface charge accumulation on the insulation in HVDC wall bushings and improve their flashover performance, the epoxy resins used for the supporting insulator and the tube body were surface fluorinated under the same conditions using a fluorine/nitrogen mixture. The results show that fluorine atoms are introduced into the surface layers of two types of epoxy resins by the substitution for hydrogen atoms and the addition to carbon-carbon double bonds, forming C-F bonds. The fluorination is accompanied by chain breaking, which mainly occurs at the crosslinking sites. Due to the difference in epoxy value, two types of epoxy resins show different crosslinking densities. SEM imaging shows that they have different thicknesses of the fluorinated layer and surface morphologies. Surface potential decay and surface conductivity measurements reveal that the fluorination increases surface conductivity of two types of epoxy resins and inhibits their surface charge accumulation to different degrees. Flashover tests show that their DC flashover voltages are significantly increased by the fluorination to almost the same degree.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |