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Influence of thermal ageing on electric strength of epoxy/glass fiber composites
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Jian ZHANG1, Pengfei WANG2, Zhongyuan LI1, Ji LIU2, Heqian LIU1, Hongda YANG1
Insulating Materials | 2025, 58(7) : 121 - 128
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Insulating Materials | 2025, 58(7): 121-128
Insulation Technology
Influence of thermal ageing on electric strength of epoxy/glass fiber composites
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Jian ZHANG1, Pengfei WANG2, Zhongyuan LI1, Ji LIU2, Heqian LIU1, Hongda YANG1
Affiliations
  • 1. Electric Power Research Institute, State Grid Heilongjiang Electric Power Company Limited, Harbin 150030, China
  • 2. Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, China
Published: 2025-07-20 doi: 10.16790/j.cnki.1009-9239.im.2025.07.014
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To investigate the thermal ageing mechanism of dry air core reactor encapsulated insulating materials at the molecular level, this study conducted 336-hour accelerated thermal ageing tests on epoxy/glass fiber composites at 180℃. The evolutionary characteristics of functional groups, molecular chain segment motions, activation energies, and AC electric strength of the epoxy/glass fiber composites after ageing were characterized by infrared spectroscopy, dielectric spectroscopy, and AC electric strength test. The effect of the decrease in activation energy caused by the changes in chemical structure and the evolution of molecular chain segment movement properties during ageing on the AC electric strength was investigated. The results show that a lot of carbonyl groups and small molecular chains dominated by ester and ketone groups generate during the ageing process. These small molecule chains and polar groups greatly increase the free volume and the number of free electrons inside the epoxy matrix, so that the chain segment movement is gradually enhanced and the activation energy is reduced, which ultimately leads to a significant reduction in insulation capacity.

dry air core reactor  /  epoxy/glass fiber composites  /  thermal ageing  /  activate energy
Jian ZHANG, Pengfei WANG, Zhongyuan LI, Ji LIU, Heqian LIU, Hongda YANG. Influence of thermal ageing on electric strength of epoxy/glass fiber composites[J]. Insulating Materials, 2025 , 58 (7) : 121 -128 . DOI: 10.16790/j.cnki.1009-9239.im.2025.07.014
Year 2025 volume 58 Issue 7
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Article Info
doi: 10.16790/j.cnki.1009-9239.im.2025.07.014
  • Receive Date:2024-08-04
  • Online Date:2025-10-29
  • Published:2025-07-20
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  • Received:2024-08-04
  • Revised:2024-10-23
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Affiliations
    1. Electric Power Research Institute, State Grid Heilongjiang Electric Power Company Limited, Harbin 150030, China
    2. Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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