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Effect of micro-water on insulation properties and decomposition characteristics of C6F12O/CO2 gas mixture
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Shuangshuang TIAN1, Yimeng CHEN1, Xiaoping JIN1, Yingxiang WANG2, Chenying LI3, Jiahao WANG1, Hui CHEN1
Insulating Materials | 2025, 58(2) : 16 - 24
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Insulating Materials | 2025, 58(2): 16-24
Special Issue on Eco-friendly Insulating Gas
Effect of micro-water on insulation properties and decomposition characteristics of C6F12O/CO2 gas mixture
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Shuangshuang TIAN1, Yimeng CHEN1, Xiaoping JIN1, Yingxiang WANG2, Chenying LI3, Jiahao WANG1, Hui CHEN1
Affiliations
  • 1Hubei Engineering Research Center for Safety Monitoring of New Energy and Power Grid Equipment, Hubei University of Technology, Wuhan 430068, China
  • 2Economic and Technical Research Institute of State Grid Hubei Electric Power Co., Ltd., Wuhan 430077, China
  • 3Electric Power Research Institute, State Grid Jiangsu Electric Power Co., Ltd., Nanjing 211103, China
Published: 2025-02-20 doi: 10.16790/j.cnki.1009-9239.im.2025.02.003
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C6F12O has good environmental protection characteristics and insulation properties, and has good application prospects in medium and low voltage gas-insulated equipment. In order to explore the influence of micro-water inside the gas-insulated equipment on the insulation performance and decomposition characteristics of C6F12O/CO2 gas mixture, a gas power frequency breakdown test platform was set up, and the breakdown voltage of 4%C6F12O/96%CO2 gas mixture under 0.14 MPa pressure within the range of 0-1 000 μL/L micro-water concentration was studied.The influence of different micro-water concentration on the power frequency breakdown characteristics of gas mixture was analyzed. The types and concentrations of the decomposition products of C6F12O/CO2 gas mixture were analyzed quantitatively and qualitatively by gas chromatography-mass spectrometry (GC-MS) after breakdown, and the influence laws of micro-water concentration on the concentration of breakdown decomposition products and effective gas production rate were obtained. The results show that micro-water will reduce the power frequency breakdown voltage of C6F12O/CO2 gas mixture. The main breakdown decomposition products of C6F12O/CO2 gas mixture are CF4, C2F6, C3F6, C3F8, C3F7H, CF2O, C4F10, C5F12, and CF3H, among them, the concentration and effective gas production rate of CF4, C2F6, and C3F7H are positively correlated with the micro-water concentration, and the concentration of CF4, C2F6, C3F6, C3F8, and C3F7H are positively correlated with the breakdown times. Considering the insulation performance and decomposition characteristics, it is recommended to strictly control the concentration of micro-water inside the C6F12O/CO2 gas mixtures equipment during engineering application, and increase the test frequency of micro-water in the equipment.

C6F12O/CO2 gas mixtures  /  micro-water  /  insulation properties  /  decomposition characteristics
Shuangshuang TIAN, Yimeng CHEN, Xiaoping JIN, Yingxiang WANG, Chenying LI, Jiahao WANG, Hui CHEN. Effect of micro-water on insulation properties and decomposition characteristics of C6F12O/CO2 gas mixture[J]. Insulating Materials, 2025 , 58 (2) : 16 -24 . DOI: 10.16790/j.cnki.1009-9239.im.2025.02.003
Year 2025 volume 58 Issue 2
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Article Info
doi: 10.16790/j.cnki.1009-9239.im.2025.02.003
  • Receive Date:2024-03-24
  • Online Date:2025-11-06
  • Published:2025-02-20
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History
  • Received:2024-03-24
  • Revised:2024-04-24
Funding
Affiliations
    1Hubei Engineering Research Center for Safety Monitoring of New Energy and Power Grid Equipment, Hubei University of Technology, Wuhan 430068, China
    2Economic and Technical Research Institute of State Grid Hubei Electric Power Co., Ltd., Wuhan 430077, China
    3Electric Power Research Institute, State Grid Jiangsu Electric Power Co., Ltd., Nanjing 211103, China
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https://castjournals.cast.org.cn/joweb/jycl/EN/10.16790/j.cnki.1009-9239.im.2025.02.003
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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