C6F12O has good environmental protection characteristics and insulation properties, and has good application prospects in medium and low voltage gas-insulated equipment. In order to explore the influence of micro-water inside the gas-insulated equipment on the insulation performance and decomposition characteristics of C6F12O/CO2 gas mixture, a gas power frequency breakdown test platform was set up, and the breakdown voltage of 4%C6F12O/96%CO2 gas mixture under 0.14 MPa pressure within the range of 0-1 000 μL/L micro-water concentration was studied.The influence of different micro-water concentration on the power frequency breakdown characteristics of gas mixture was analyzed. The types and concentrations of the decomposition products of C6F12O/CO2 gas mixture were analyzed quantitatively and qualitatively by gas chromatography-mass spectrometry (GC-MS) after breakdown, and the influence laws of micro-water concentration on the concentration of breakdown decomposition products and effective gas production rate were obtained. The results show that micro-water will reduce the power frequency breakdown voltage of C6F12O/CO2 gas mixture. The main breakdown decomposition products of C6F12O/CO2 gas mixture are CF4, C2F6, C3F6, C3F8, C3F7H, CF2O, C4F10, C5F12, and CF3H, among them, the concentration and effective gas production rate of CF4, C2F6, and C3F7H are positively correlated with the micro-water concentration, and the concentration of CF4, C2F6, C3F6, C3F8, and C3F7H are positively correlated with the breakdown times. Considering the insulation performance and decomposition characteristics, it is recommended to strictly control the concentration of micro-water inside the C6F12O/CO2 gas mixtures equipment during engineering application, and increase the test frequency of micro-water in the equipment.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |