Aiming at the refining and regeneration issues of retired transformer insulating oil, we used catalytic hydrogenation to decolorize retired transformer oil. Based on this, polyethylene glycol modified chitosan adsorption process was used to remove corrosive sulfur and heavy metal copper ions, and achieve the regeneration of retired transformer oil. The results show that when the catalytic hydrogenation temperature is 220℃, the reaction pressure is 4 MPa, and the volume ratio of hydrogen to oil is 300∶1, the retired transformer oil can achieve decolorization. The self-made modified chitosan-polyethylene glycol composite adsorbent material (CS-PEG) can quickly remove the corrosive sulfur and metal copper ions from oil samples. After being treated by this process, the retired transformer oil becomes transparent, its acid value decreases to 0.003 mg(KOH)/g, the breakdown voltage reaches 45 kV, and the dielectric loss factor drops below 0.001. This process has good potential for application.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |