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Insulating materials are more prone to early failure under pulsed voltage, which seriously threatens the stability of power electronic devices and equipment. In order to explore the microscopic mechanism of insulation failure under pulsed voltage, the effect of space charge density in polyimide on the charge-excited molecular vibration at the pulse edge was explored in this paper, and the molecular vibration mechanism at the pulse voltage edge was expounded from the perspective of frequency domain. The results show that there is a large amount of heteropolar space charges accumulated inside the polyimide sample under DC voltage, which leads to the reversal of polarity of the molecular vibration waveform. In the frequency spectrum of pulse voltage rising edge, the voltage component in the frequency band of 5×106-1×107 Hz plays a major role in the molecular vibration. The charge-excited molecular vibration will expand the insulation defects and eventually lead to insulation failure.
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| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |
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