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Effect of Multiple Synergistic Flame Retardant on Properties of EVA/LDPE Composites
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Zili LIU1, Chenying WU1, Xiqin LIU1, Dongbo WEI1, Jinfang BAO2, Jun ZHU2, Xinxiang CHEN3
Insulating Materials | 2022, 55(4) : 48 - 55
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Insulating Materials | 2022, 55(4): 48-55
Material Research
Effect of Multiple Synergistic Flame Retardant on Properties of EVA/LDPE Composites
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Zili LIU1, Chenying WU1, Xiqin LIU1, Dongbo WEI1, Jinfang BAO2, Jun ZHU2, Xinxiang CHEN3
Affiliations
  • 1College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
  • 2Changshu Zhonglian Photoelectric New Material Co., Ltd., Changshu 215542, China
  • 3Zhongli Group, Changshu 215542, China
Published: 2022-04-20 doi: 10.16790/j.cnki.1009-9239.im.2022.04.007
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On the basis of filling magnesium hydroxide sulfate hydrates(MHSH)whisker and aluminium trihydrate (ATH) blends, EVA/LDPE composites were prepared by adding borax, zinc borate (ZnB) and microencapsulated red phosphorus (MRP), respectively. The effects of multiple synergistic flame retardant containing MHSH whisker on the flame retardancy, mechanical and electrical properties of EVA/LDPE composites were analyzed by thermogravimetric analyzer, cone calorimeter, limiting oxygen index (LOI) meter, scanning electron microscope (SEM), energy dispersive spectrometer (EDS), universal tensile machine, AC medium strength tester, and high resistance meter. The results show that the initial decomposition temperature Td, the peak temperature of weight loss rate Tp2 and Tp3, and the residual rate at 800℃ of EVA/LDPE composites are significantly increased by adding MRP. Compared with the samples adding borax and zinc borate, the samples adding MRP show the best flame retardancy, the peak value of heat release rate curve and total heat release value decreases to 219.86 kW/m2 and 19.38 MJ/m2, respectively; and the time to ignition (TTI) and LOI increases to 59 s and 28.4%, respectively; during the combustion process, the carbon layer of the sample is continuous and compact, without melting and dropping. The mechanism of MRP cooperating with MHSH whisker and ATH to improve the flame retardancy of EVA/LDPE composite is due to the synergistic effect of gas phase flame retarding and condensed phase flame retarding. The addition of MRP reduces the elongation at break of the composites, but they still have good electrical insulation properties.

EVA/LDPE composites  /  synergistic flame retardant  /  flame retardancy
Zili LIU, Chenying WU, Xiqin LIU, Dongbo WEI, Jinfang BAO, Jun ZHU, Xinxiang CHEN. Effect of Multiple Synergistic Flame Retardant on Properties of EVA/LDPE Composites[J]. Insulating Materials, 2022 , 55 (4) : 48 -55 . DOI: 10.16790/j.cnki.1009-9239.im.2022.04.007
Year 2022 volume 55 Issue 4
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Article Info
doi: 10.16790/j.cnki.1009-9239.im.2022.04.007
  • Receive Date:2021-06-04
  • Online Date:2025-12-22
  • Published:2022-04-20
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  • Received:2021-06-04
  • Revised:2021-07-26
Affiliations
    1College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
    2Changshu Zhonglian Photoelectric New Material Co., Ltd., Changshu 215542, China
    3Zhongli Group, Changshu 215542, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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