Taking urea and hexagonal boron nitride as raw materials, we prepared an amino modified boron nitride nanosheets (BNNS) by ball milling method, and then prepared a BNNS/epoxy composite by mixing the BNNS before and after modification with epoxy resin. The effect of amino modified BNNS on the surface insulating properties of epoxy resin was studied. The results show that the amino group is grafted on the surface of BNNS successfully by ball milling method, which improves the dispersion of fillers in epoxy composites. When the mass fraction of the modified BNNS is 0.5%, the flashover voltage of the BNNS/epoxy composite increases by 26.9% compared with the pure epoxy resin. In addition, the amino modification reduces the trap energy level on material surface and accelerates the space charge dissipation rate. The dielectric constant and dielectric loss factor of the composites filled with amino modified BNNS increase slightly. The flashover voltage of the composites can be improved by balancing the effects of space charge dissipation and polarization relaxation.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |