A high toughness composite epoxy resin system was prepared with bisphenol A epoxy resin as matrix, G2019 epoxy resin as the modified resin and hexanediol diglycidyl ether as diluent. The high-performance epoxy resin-based glass fiber reinforced composites for wind turbine blades were fabricated via the pultrusion process, and their mechanical and electrical properties were studied. The results show that the obtained composite epoxy resin system can be used as a high toughness epoxy resin matrix. When the content of G2019 epoxy resin is 30 phr, the impact strength of the epoxy resin composite system casting reaches 25.1 kJ/m², which is 151.5% higher than that of the pure bisphenol A epoxy resin, and the AC and DC electric strength reaches 48 kV/cm and 65 kV/cm, respectively. The pultruded epoxy resin-based glass fiber reinforced composites show outstanding comprehensive mechanical and electrical performances, which can meet the application requirements of wind power fields.