A barium titanate/polyvinylidene fluoride (BT/PVDF) composites was prepared by solution blending method, and the effect of size distribution and content of BT particles on the dielectric properties, electric strength, energy storage properties, and thermal stability of the composites were investigated. The results show that compared with single particle size BT, the synergistic effect of double particle size BT filler makes the composites have more excellent comprehensive properties, and the synergistic effect is the most remarkable when the mass ratio of BT with double size is equal to 1. With the increase of filler content, the dielectric constant and thermal stability of the composites increase, and the dielectric loss factor of the composites maintains at the relative low level. When the mass fraction of BT is 60%, and the mass ratio of BT with double size is 5∶5, the dielectric constant of BT/PVDF composites reaches 46.5 at 100 Hz, which is 5 times bigger than that of pure PVDF; the energy storage density and polarization are 0.18 J/cm3 and 0.011 9 C/m2, respectively, which are 176% and 310% higher than those of pure PVDF; the decomposition temperature corresponding to 5% of weight loss reaches 478.4℃, which is 1.3℃ and 30.3℃ higher than that of PVDF composites filled with S-BT and L-BT, respectively.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |