The directionally solidified superalloy DZ125 is widely used as turbine blades in aero-engines. This work investigates the influence of phosphorus(P)on the microstructure, mechanical properties and crack susceptibility of DZ125 alloy. The results indicate that P primarily segregates at grain boundaries in DZ125 alloy and has little effect on γ′ phases, γ+γ′ eutectic and carbides in the alloy. When P content reaches 0.008% (mass fraction, the same below) P-rich phases form in the interdendritic regions during casting, which subsequently dissolve back into the matrix during heat treatment.When the P content is no more than 0.0039%, P shows no obvious effects on the room-temperature tensile properties or the stress rupture life at 980℃/235 MPa. However, it has a significant impact on the stress rupture life at 760℃/805 MPa: the alloy with 0.0039% P exhibits a 37% decrease in stress rupture life at 760℃/805 MPa compared to the alloy with 0.0013% P, due to the segregation of P at grain boundaries weakens the grain boundaries. When the P content reaches 0.011%, the intergranular cracks appear in the DZ125 alloy hollow turbine blades during directionally solidified process. The main reason for the increase of crack susceptibility is excessive enrichment of P at grain boundaries and precipitation of P-rich phases nearby grain boundaries, which leads to grain boundary weakening and crack initiation.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |