The development of nuclear energy is inseparable from the treatment and disposal of radioactive waste. Geopolymer is a promising radioactive waste solidification material. In this study,metakaolin was used as the substrate to prepare metakaolin polymer, which was used to solidify Cs and real radioactive waste. The properties of metakaolin geopolymer were investigated by characterization and leaching experiments. Characterization experiments show that metakaolin geopolymer with three-dimensional network structure has high compressive strength, which can meet the strength requirements of radioactive waste solidified body. At the same time, the solidification of Cs in metakaolin polymer is uniform. However, the incorporation of Cs will hinder the growth of silicon and aluminum network skeleton and reduce the gel structure of the system,resulting in the increase of porosity and the decrease of compressive strength of geopolymer cured body. The leaching experiments of Cs and real waste water in deionized water and real groundwater show that metakaolin polymer has excellent Cs retention ability,and has low leaching rate and cumulative leaching fraction,which is better than the value specified in the national standard. In general,metakaolin geopolymer performs well in physical compression resistance and Cs retention,and is a material with great application potential.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |