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Application of metakaolin based polymer in the treatment of low level radioactive waste liquid
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CHENG Jianfeng1, 2, ZHANG Qi1, 2, ZONG Zihua1, 2, DONG Yanhui3, CAO Shengfei1, 2, PENG Liyuan1, 2
World Nuclear Geoscience | 2025, 42(1) : 123 - 133
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World Nuclear Geoscience | 2025, 42(1): 123-133
RESEARCH ARTICALS
Application of metakaolin based polymer in the treatment of low level radioactive waste liquid
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CHENG Jianfeng1, 2, ZHANG Qi1, 2, ZONG Zihua1, 2, DONG Yanhui3, CAO Shengfei1, 2, PENG Liyuan1, 2
Affiliations
  • 1 Beijing Research Institute of Uranium Geology, Beijing 100029,China
  • 2 CAEA Innovation Center for Geological Disposal of High-Level Radioactive Waste,Beijing 100029,China
  • 3 Key Laboratory of Shale Gas and Geoengineering,Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
Published: 2025-02-08 doi: 10.3969/j.issn.1672-0636.2025.01.010
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The development of nuclear energy is inseparable from the treatment and disposal of radioactive waste. Geopolymer is a promising radioactive waste solidification material. In this study,metakaolin was used as the substrate to prepare metakaolin polymer, which was used to solidify Cs and real radioactive waste. The properties of metakaolin geopolymer were investigated by characterization and leaching experiments. Characterization experiments show that metakaolin geopolymer with three-dimensional network structure has high compressive strength, which can meet the strength requirements of radioactive waste solidified body. At the same time, the solidification of Cs in metakaolin polymer is uniform. However, the incorporation of Cs will hinder the growth of silicon and aluminum network skeleton and reduce the gel structure of the system,resulting in the increase of porosity and the decrease of compressive strength of geopolymer cured body. The leaching experiments of Cs and real waste water in deionized water and real groundwater show that metakaolin polymer has excellent Cs retention ability,and has low leaching rate and cumulative leaching fraction,which is better than the value specified in the national standard. In general,metakaolin geopolymer performs well in physical compression resistance and Cs retention,and is a material with great application potential.

metakaolin  /  geopolymer  /  radioactive waste liquid  /  leaching rate  /  cumulative leaching fraction
CHENG Jianfeng, ZHANG Qi, ZONG Zihua, DONG Yanhui, CAO Shengfei, PENG Liyuan. Application of metakaolin based polymer in the treatment of low level radioactive waste liquid[J]. World Nuclear Geoscience, 2025 , 42 (1) : 123 -133 . DOI: 10.3969/j.issn.1672-0636.2025.01.010
  • National Key R&D Program of China(2022YFE0120500)
Year 2025 volume 42 Issue 1
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Article Info
doi: 10.3969/j.issn.1672-0636.2025.01.010
  • Receive Date:2024-12-25
  • Online Date:2025-11-07
  • Published:2025-02-08
Article Data
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History
  • Received:2024-12-25
  • Revised:2025-01-23
Funding
National Key R&D Program of China(2022YFE0120500)
Affiliations
    1 Beijing Research Institute of Uranium Geology, Beijing 100029,China
    2 CAEA Innovation Center for Geological Disposal of High-Level Radioactive Waste,Beijing 100029,China
    3 Key Laboratory of Shale Gas and Geoengineering,Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China

Corresponding:

ZHANG Qi,male,born in 1991,senior engineer,PhD,focusing on the research of multi- physical field coupling theory and numerical simulation of buffer materials for geological disposal of high-level radioactive waste. E-mail:
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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