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Performance validation of a Daly detector for thermal ionization mass spectrometry
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Luyi QIAO, Dongfa GUO, Boping LI, Guifang LIU, Bo XIANG, Ziyu WEI, Shuting TANG, Jing TAN, Ze ZHANG, Ruoming WANG, Li LI, Shouzhi DONG, Lei WU, Guangchuan DAI, Mengqing LI
World Nuclear Geoscience | 2025, 42(2) : 423 - 435
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World Nuclear Geoscience | 2025, 42(2): 423-435
RESEARCH ARTICALS
Performance validation of a Daly detector for thermal ionization mass spectrometry
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Luyi QIAO, Dongfa GUO, Boping LI, Guifang LIU, Bo XIANG, Ziyu WEI, Shuting TANG, Jing TAN, Ze ZHANG, Ruoming WANG, Li LI, Shouzhi DONG, Lei WU, Guangchuan DAI, Mengqing LI
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Published: 2025-04-08 doi: 10.3969/j.issn.1672-0636.2025.02.016
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To meet the requirements of thermoionization mass spectrometry (TIMS) for the determination of low-abundance isotopes,it is necessary to configure a secondary electron multiplier (SEM) or Daly detector ion counting detector on the TIMS. Compared to SEM,Daly offers high gain,low noise, good linearity,long service life, and the photomultiplier tube is located outside the instrument’s vacuum system and easy to replace,making it more cost-effective. The authors developed Daly detector consists of a detection chamber,an ion conversion pole,a plastic scintillator,a fast-response photomultiplier tube,a preamplifier,a single-photon counter,a power supply,and the measurement and control software. The response gating of the Daly detector can be adjusted between 0.1~2 V,the photomultiplier tube has a high voltage of 800~900 V,the ion counting background is less than 0.1 cps,and the highest count rate is 40 Mcps. In this paper,the performance of the Daly detector was verified by uranium isotope composition determination, and the results showed that the intra-test precision of Daly for the CRM0002 isotope abundance of 235U/238U was 0.073 %,and the intra-test precision of the isotope abundance of UTB500 was 0.139 %,0.056 % and 0.214 % respectively for 234U /238U,235U /238U and 236U /238U,which met the requirements of ASTM C1625—19.

thermal ionization mass spectrometer  /  Daly detector  /  preamplifier  /  FPGA
Luyi QIAO, Dongfa GUO, Boping LI, Guifang LIU, Bo XIANG, Ziyu WEI, Shuting TANG, Jing TAN, Ze ZHANG, Ruoming WANG, Li LI, Shouzhi DONG, Lei WU, Guangchuan DAI, Mengqing LI. Performance validation of a Daly detector for thermal ionization mass spectrometry[J]. World Nuclear Geoscience, 2025 , 42 (2) : 423 -435 . DOI: 10.3969/j.issn.1672-0636.2025.02.016
  • Nuclear Technology Research and Development Projects,China Atomic Energy Authority(测H2402)
Year 2025 volume 42 Issue 2
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Article Info
doi: 10.3969/j.issn.1672-0636.2025.02.016
  • Receive Date:2025-03-19
  • Online Date:2025-10-29
  • Published:2025-04-08
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History
  • Received:2025-03-19
  • Revised:2025-03-25
Funding
Nuclear Technology Research and Development Projects,China Atomic Energy Authority(测H2402)
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Corresponding:

GUO Dongfa,male,born in 1965,senior engineer,doctoral supervisor,focusing on nuclear geological analysis and nuclear mass spectrometry research and application. E-mail:
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
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占总种数比例
Percentage of
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种数
Number of
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Percentage of total
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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