In recent years,tungsten oxide(WO3)nanomaterials have garnered significant attention in the field of gas sensors. However,their practical applications are limited by drawbacks such as high operating temperatures and low sensitivity. A series of MoS2/WO3 nanocomposites were synthesized via a hydrothermal method. Gas-sensing tests for nitrogen dioxide(NO2)demonstrated that these composites exhibit excellent sensing performance over a working temperature range of 20-180℃ and an NO2 concentration range of 1ppm-100ppm. Notably,the MoS2/WO3 composite with a 2% MoS2 doping ratio achieved a remarkable response value of 1123.19 toward 20ppm NO2 at 140℃—seven times that of pure WO3 at its optimal working temperature(80℃). Characterization and mechanistic studies revealed that the combination of MoS2 and WO3 forms a p-n heterojunction,inducing a charge depletion layer at the interface. Additionally,the band bending effect reduces the energy barrier for gasmolecule adsorption,thereby enhancing both the gas adsorption capacity and surface reaction activity of the composite. This study provides a novel material design strategy and technical approach for developing high-performance,low-temperature NO2 gas sensors.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |