Bi-directional DC-DC convertersare usually used in vehicle charging pile application circuits, which have problems such as slow system dynamic response and poor output voltage stability due to load perturbations. On the basis, acapacitor-inductor-inductor-capacitor (CLLC) resonant DC-DC converter is taken as a research object, and a control method for the CLLC resonant converter based on sliding mode active disturbance rejectionis proposed. A model-assisted linear state observer is used to improve the estimation accuracy of perturbation, so as to control the stable operation of the system. Sliding mode control is used to design a linear state error feedback control law to improve the dynamic performance and rapidity of the system. Simulations and experimental verification show that the proposed control strategy can effectively improve the dynamic response of the bi-directional DC-DC converter and enhance the output voltage stability.