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Phase Field Method for Simulation of Fracture of Silicon Anode in Lithium-ion Batteries
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Ke ZHANG1, Jing LIU2, Ranran FANG1, Wei WANG1
Journal of Power Supply | 2025, 23(7) : 266 - 273
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Journal of Power Supply | 2025, 23(7): 266-273
• Battery and Energy Storage •
Phase Field Method for Simulation of Fracture of Silicon Anode in Lithium-ion Batteries
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Ke ZHANG1, Jing LIU2, Ranran FANG1, Wei WANG1
Affiliations
  • 1.School of Intelligent Manufacturing and Control Engineering, Shandong Institute of Petroleum and Chemical Technology, Dongying 257061, China
  • 2.School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
Published: 2025-11-30 doi: 10.13234/j.issn.2095-2805.2025.7.266
Outline
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In the phase field fracture method, the crack is represented by defining an order parameter, and the governing equation describing the crack development is obtained by using the minimum energy variational principle for the system. In this paper, the framework of phase field theory was established through the derivation of governing equations, including the establishment of phase field fracture damage evolution equation and boundary conditions based on the energy principle. Tensile and shear simulations were carried out on a plate with a notch, and the fracture path and support reaction were in good agreement with the results reported in the literature. The crack propagation of lithium-ion batteries with different diameters of silicon anode during charging was simulated using the phase field method. Results show that the large-diameter (400 nm) silicon particles quickly exhibit crack during charging due to the large tensile stress on their surfaces, and the crack propagates inwards. The fracture energy release rate has a great influence on the crack propagation, and a small energy release rate results in more crack initiation points and a high crack density. In comparison, internal fracture appears in small-diameter (100 nm) silicon particles during charging, and the fracture time is earlier than that of large-sized silicon particles.

Phase field method  /  lithium-ion battery  /  silicon nanoparticle  /  fracture
张可, 刘靖, 房冉冉, 王维. 锂离子电池硅负极断裂的相场法模拟. 电源学报, 2025 , 23 (7) : 266 -273 . DOI: 10.13234/j.issn.2095-2805.2025.7.266
Ke ZHANG, Jing LIU, Ranran FANG, Wei WANG. Phase Field Method for Simulation of Fracture of Silicon Anode in Lithium-ion Batteries[J]. Journal of Power Supply, 2025 , 23 (7) : 266 -273 . DOI: 10.13234/j.issn.2095-2805.2025.7.266
  • Science Development Foundation of Dongying(DJ20211014)
Year 2025 volume 23 Issue 7
37
5
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Article Info
doi: 10.13234/j.issn.2095-2805.2025.7.266
  • Receive Date:2022-10-11
  • Online Date:2026-10-26
  • Published:2025-11-30
Article Data
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History
  • Received:2022-10-11
  • Revised:2023-02-27
  • Accepted:2023-03-07
Funding
Science Development Foundation of Dongying(DJ20211014)
Affiliations
    1.School of Intelligent Manufacturing and Control Engineering, Shandong Institute of Petroleum and Chemical Technology, Dongying 257061, China
    2.School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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