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Advanced thermal control technology based on solid-state phase transformation of Ti-Ni-based alloys and its application in thermal management of chips
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Zeyi LI1, 2, Zhuangweici SUN1, 2, Shuxin LIU3, Xueyi HUO1, 2, Guanqi LI1, 2, Zhengrui LI1, 2, Changshuo ZHANG1, 2, Peipei LI3, Mingye ZHENG3, Kaichao ZHANG2, Chao LYU2, Jun WENG3, Huilong HOU1, 2
Journal of Materials Engineering | 2026, 54(7) : 62 - 70
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Journal of Materials Engineering | 2026, 54(7): 62-70
• HIGH-PERFORMANCE SHAPE MEMORY MATERIALS COLUMN •
Advanced thermal control technology based on solid-state phase transformation of Ti-Ni-based alloys and its application in thermal management of chips
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Zeyi LI1, 2, Zhuangweici SUN1, 2, Shuxin LIU3, Xueyi HUO1, 2, Guanqi LI1, 2, Zhengrui LI1, 2, Changshuo ZHANG1, 2, Peipei LI3, Mingye ZHENG3, Kaichao ZHANG2, Chao LYU2, Jun WENG3, Huilong HOU1, 2
Affiliations
  • 1.Tianmushan Laboratory,Beihang University,Hangzhou 311115,China
  • 2.School of Materials Science and Engineering,Beihang University,Beijing 100191,China
  • 3.Beijing Institute of Radio Measurement,Beijing 100854,China
Published: 2026-07-20 doi: 10.11868/j.issn.1001-4381.2025.000300
Outline
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Aiming at the contradiction between the high heat flux density heat dissipation requirement and the confined space of chips in the thin electronic devices, this work proposes a solid-state phase transformation thermal control technology based on the structure transformation of the alloys to meet the efficient heat dissipation requirement of chips in confined space. By comparing the thermal response characteristics of sensible thermal energy storage materials and solid-state phase transformation alloys, the effects of the type, the thickness of thermal energy storage materials and the heating power on the temperature rise behavior of the chip are systematically studied. The experiment results show that the Ti-Ni-based solid-state phase transformation alloys with martensite ↔ austenite structure transformation exhibit significant thermal energy storage advantages benefiting from the synergistic effect of structural sensible heat consumption and latent heat absorption of phase transformation. The thermal energy storage capacity per unit volume of the investigative Ti-Ni-based solid-state phase transformation alloys is 285.4 J·cm-3, which is 3.9 times and 2.8 times that of the 6061 aluminum alloys and H62 copper alloys, respectively. The test results of the chip in the working conditions show that the application of Ti-Ni-based solid-state phase transformation alloys can reduce the heating rate of the chip by up to 82%, and the time when the temperature of the chip reaches critical temperature is extended by up to 96% and 73% respectively compared with the architectural systems of aluminum-6061 alloys and copper-H62 alloys. The parametric analysis results indicate that the measured time (tc) when the temperature of the chip reaches critical temperature using the Ti-Ni-based solid-state phase transformation alloys has a quadratic functional relationship (tc∝h2) with the thickness (h) of the thermal energy storage alloy layers, and shows an exponential attenuation law (tc∝p-1.4) with the heating power (p). The solid-state phase transformation alloys are able to absorb sensible heat through intrinsic specific heat capacity and extend the duration of the slowly rising temperature of the chip through latent heat effect. Both of the two abilities form a dual-mode intelligent thermal control response mechanism of “sensible heat absorption-latent heat buffering” during the heating process. This work confirms that solid-state phase transformation alloys can achieve effective thermal buffering in millimeter-level narrow space, providing a new solution for compact thermal management of miniaturized electronic devices.

solid-state phase transformation  /  Ti-Ni-Cu alloys  /  thin electronic device  /  chip  /  thermal management
李泽怡, 孙庄炜慈, 刘舒昕, 霍雪艺, 李冠奇, 李政睿, 张昌硕, 李培培, 郑明晔, 张凯超, 吕超, 翁俊, 侯慧龙. 基于钛镍基合金固态相变的先进温控技术及其在芯片热管理中的应用. 材料工程, 2026 , 54 (7) : 62 -70 . DOI: 10.11868/j.issn.1001-4381.2025.000300
Zeyi LI, Zhuangweici SUN, Shuxin LIU, Xueyi HUO, Guanqi LI, Zhengrui LI, Changshuo ZHANG, Peipei LI, Mingye ZHENG, Kaichao ZHANG, Chao LYU, Jun WENG, Huilong HOU. Advanced thermal control technology based on solid-state phase transformation of Ti-Ni-based alloys and its application in thermal management of chips[J]. Journal of Materials Engineering, 2026 , 54 (7) : 62 -70 . DOI: 10.11868/j.issn.1001-4381.2025.000300
Year 2026 volume 54 Issue 7
68
32
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Article Info
doi: 10.11868/j.issn.1001-4381.2025.000300
  • Receive Date:2025-05-22
  • Online Date:2026-10-28
  • Published:2026-07-20
Article Data
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History
  • Received:2025-05-22
  • Accepted:2025-06-19
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Affiliations
    1.Tianmushan Laboratory,Beihang University,Hangzhou 311115,China
    2.School of Materials Science and Engineering,Beihang University,Beijing 100191,China
    3.Beijing Institute of Radio Measurement,Beijing 100854,China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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