This study utilizes mushroom stalks as a biological template and melamine as a precursor for carbon nitride to synthesize g-C3N4/C,via thermal polymerization method. Copper sulfate pentahydrate (CuSO4·5H2O),ammonium molybdate tetrahydrate ((NH4)6Mo7O24·4H2O),and thiourea (CH4N2S) are selected as the sources for Cu,Mo,and S,respectively. A two-step hydrothermal process is employed to prepare CuS/MoS2 composites with different mass ratios. Then CuS/MoS2 is anchored on the surface of g-C3N4/C to obtain CuS/MoS2-g-C3N4/C composite electrode materials. The composite electrode materials are characterized by their phase structure,microstructure,pore structure,and capacitance performance. The results indicate that the CuS/MoS2-g-C3N4/C composite electrode materials exhibit high purity,good crystallinity,good phase contact interface, and abundant porous structure. In electrochemical performance testing,the CuS/MoS2 composite material with a mass ratio of MoS2 to CuS at 1∶2 demonstrates optimal electrochemical performance,achieving a specific capacitance of 230 F·g-1 at a current density of 1 A·g-1. When the mass ratio of CuS/MoS2 to g-C3N4/C is 1∶1,the CuS/MoS2-g-C3N4/C composite material exhibits the best electrochemical performance,with a specific capacitance of 434.7 F·g-1. Moreover,after 1000 cycles,the capacitance retention rate is 89.2%,showing good stability.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |