The preparation of carbon paper used phenolic resin as matrix carbon, and different heat treatment temperatures (1400-2700 ℃) are used to obtain matrix carbon with different structures. At the same time, the effect of matrix carbon content and structure on carbon paper for proton exchange membrane fuel cell is studied. The results show that the matrix carbon in carbon paper is more prone to graphitization transformation than carbon fiber. As the content of the matrix carbon increases, the d002 diffraction peak of the carbon paper becomes sharper. When the heat treatment temperature increases from 2100 ℃ to 2400 ℃, the graphitization of the carbon paper increases by 45.2%, which is the largest increase. With the increase of heat treatment temperature, the carbon papers, with different matrix carbon ratios, show differences in performance trends. When the carbon content of the matrix is 60%(mass fraction, the same below) and 120%, the thickness of the carbon paper gradually decreases with the increase of the graphitization temperature, and the tensile strength of the carbon paper has a slight change; when the carbon content of the matrix is 200% and 350%, with the increase of graphitization temperature, the thickness of carbon paper decreases slightly and then increases, and the tensile strength of carbon paper decreases rapidly. The surface resistivity of carbon paper shows a downward trend with the increase of heat treatment temperature, and its change trend is basically consistent with the change trend of thickness. Therefore, when preparing carbon papers with different properties, it is necessary to consider the synergistic effect of matrix carbon content and structure.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |