To clarify the effect of composition optimization on the hot corrosion behavior of powder metallurgy superalloys, a new powder metallurgy superalloy (hereinafter referred to as the new alloy) and FGH96 superalloy are selected as research objects. Gas hot corrosion and salt-coated hot corrosion tests are carried out at 700, 750 ℃, and 800 ℃, and the hot corrosion behavior are analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe micro analysis (EPMA). The results show that the gas hot corrosion mechanism for both alloys is accelerated oxidation, while the salt-coated hot corrosion mechanism involves the synergistic effect of oxidation and sulfidation. Compared with the FGH96 alloy, the new alloy exhibits superior hot corrosion resistance, particularly at 800 ℃. This phenomenon is mainly attributed to the increasing contents of Co and Al element in the new alloy. The high Co and Al contents promote the rapid formation of continuous and dense Cr2O3 and Al2O3 scales on the alloy surface. Moreover, the high Co content suppresses the internal oxidation of Al and reduces the inward diffusion of sulfur through the third-element effect, resulting in a complete and continuous Al2O3 scale. This effectively protects the alloy substrate and reduces the oxidation and sulfidation rates of the alloy.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |