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Influence of carbon fiber surface oxygen- containing functional groups on interfacial properties of composites
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Siyuan TIAN, Xubo ZHANG, Yihao WANG, Aijun GAO, Lianghua XU
Journal of Materials Engineering | 2025, 53(12) : 122 - 131
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Journal of Materials Engineering | 2025, 53(12): 122-131
• RESEARCH ARTICLE •
Influence of carbon fiber surface oxygen- containing functional groups on interfacial properties of composites
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Siyuan TIAN, Xubo ZHANG, Yihao WANG, Aijun GAO, Lianghua XU
Affiliations
  • Key Laboratory of Carbon Fiber and Functional Polymer (Ministry of Education),Beijing University of Chemical Technology,Beijing 100029,China
Published: 2025-12-20 doi: 10.11868/j.issn.1001-4381.2024.000757
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The interfacial structure of carbon fiber-reinforced polymer (CFRP) is crucial to the performance of composites, which represents a fundamental aspect of composite materials science research. The research on carbon fiber surface treatment is an important part of the research on composite material interfaces. By changing the physicochemical structure of the carbon fiber surface, better interface properties can be imparted to the composites. In this paper, an anodic oxidation surface treatment method based on acidic medium is adopted. Dilute sulfuric acid solutions of different concentrations are used as electrolytes to construct functional groups on the carbon fiber surface at different current densities. The results show that the carbonyl functional group (C̿    O) plays an important role in the interface properties of CFRP. In anodic oxidation treatment, a lower current density is conducive to generating more C̿    O on the surface of carbon fiber. There is an optimal value for the influence of sulfuric acid concentration on C̿    O. Moreover, adjusting the sulfuric acid concentration can achieve more accurate construction of C̿    O on the carbon fiber surface. When the current density is 0.31 mA/cm2 and the sulfuric acid concentration is 0.3%(mass fraction), the C̿    O content on the carbon fiber surface reaches the maximum value of 6.49%, and the interfacial shear strength with epoxy resin also reaches the maximum value of 76.9 MPa. Compared with untreated carbon fibers, it is increased by 111.3%, reflecting a strong correlation. This is because the dispersion interaction between C̿    O and the groups in epoxy resin enhances the bonding ability between carbon fiber and epoxy resin.

carbon fiber  /  anodic oxidation  /  oxygen-containing functional group  /  interfacial performance  /  epoxy resin
田思源, 张旭博, 王亿豪, 高爱君, 徐樑华. 碳纤维表面含氧官能团对复合材料界面性能的影响. 材料工程, 2025 , 53 (12) : 122 -131 . DOI: 10.11868/j.issn.1001-4381.2024.000757
Siyuan TIAN, Xubo ZHANG, Yihao WANG, Aijun GAO, Lianghua XU. Influence of carbon fiber surface oxygen- containing functional groups on interfacial properties of composites[J]. Journal of Materials Engineering, 2025 , 53 (12) : 122 -131 . DOI: 10.11868/j.issn.1001-4381.2024.000757
Year 2025 volume 53 Issue 12
63
30
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Article Info
doi: 10.11868/j.issn.1001-4381.2024.000757
  • Receive Date:2024-11-08
  • Online Date:2026-10-26
  • Published:2025-12-20
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  • Received:2024-11-08
  • Accepted:2025-01-24
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    Key Laboratory of Carbon Fiber and Functional Polymer (Ministry of Education),Beijing University of Chemical Technology,Beijing 100029,China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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