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In-situ preparation and properties of hydrophobic high-strong aluminium-based aerogel
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Zhongyi FU1, Liqing ZOU2, Zhong LUO3, Shuyuan ZHAO4, Caixia REN2, Liuying HUANG2, Yuxi YU2
Journal of Materials Engineering | 2026, 54(7) : 280 - 289
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Journal of Materials Engineering | 2026, 54(7): 280-289
• RESEARCH ARTICLE •
In-situ preparation and properties of hydrophobic high-strong aluminium-based aerogel
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Zhongyi FU1, Liqing ZOU2, Zhong LUO3, Shuyuan ZHAO4, Caixia REN2, Liuying HUANG2, Yuxi YU2
Affiliations
  • 1.AECC Hunan Aviation Powerplant Research Institute,Zhuzhou 412002,Hunan,China
  • 2.Fujian Key Laboratory of Advanced Materials,College of Materials,Xiamen University,Xiamen 361005,Fujian,China
  • 3.Ocean Engineering,Naval University of Engineering,Wuhan 430033,China
  • 4.National Key Laboratory of Science and Technology on Advanced Composites in Special Environments,Harbin Institute of Technology,Harbin 150080,China
Published: 2026-07-20 doi: 10.11868/j.issn.1001-4381.2024.000530
Outline
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Al2O3 aerogels has been used as insulating materials in the high-temperature areas due to the excellent high-temperature resistance, especially at the temperatures above 1000 ℃. But the hydrophilicity of Al2O3 aerogels makes it easy to absorb water steam, damaging the skeleton and the thermal insulating performance. In this work, a polyvinyltrimethoxysilane (PVTMS) hydrocarbon chain polymer is synthesized with vinyltrimethoxysilane (VTMS) as the raw material to solve above problems. Then Al-polyvinyltrimethoxysilane aerogel (AlPVSA) is prepared by in-situ polymerization using PVTMS and Al(NO3)3·9H2O as precursors. The polyvinyl chain is introduced into the Al2O3 skeleton, and the transformation from hydrophilicity to hydrophobicity is realized by adjusting the content of organic components, where the maximum contact angle is up to 136.8°. The transformation mechanism is further studied based on the surface energy and roughness. The mechanical properties of AlPVSA are improved by participating in the network-formation of organic components, and the compression modulus is maximized to 3.9 MPa when n(PVTMS/Al)=1. AlPVSA with high content silicon-polyvinyl chain is easy to form mullite phase after being heated at 1200 ℃, which lead to higher linear shrinkage (the maximum is 53.8%) and destruction of microstructure,resulting in thermal stability decrease.

hydrophobicity  /  silica-alumina aerogel  /  organic modification  /  in-situ polymerization
付仲议, 邹丽清, 罗忠, 赵淑媛, 任彩霞, 黄柳英, 余煜玺. 疏水性、高强度铝基气凝胶的原位制备与性能. 材料工程, 2026 , 54 (7) : 280 -289 . DOI: 10.11868/j.issn.1001-4381.2024.000530
Zhongyi FU, Liqing ZOU, Zhong LUO, Shuyuan ZHAO, Caixia REN, Liuying HUANG, Yuxi YU. In-situ preparation and properties of hydrophobic high-strong aluminium-based aerogel[J]. Journal of Materials Engineering, 2026 , 54 (7) : 280 -289 . DOI: 10.11868/j.issn.1001-4381.2024.000530
Year 2026 volume 54 Issue 7
54
24
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Article Info
doi: 10.11868/j.issn.1001-4381.2024.000530
  • Receive Date:2024-07-23
  • Online Date:2026-10-28
  • Published:2026-07-20
Article Data
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History
  • Received:2024-07-23
  • Accepted:2024-09-04
Funding
Affiliations
    1.AECC Hunan Aviation Powerplant Research Institute,Zhuzhou 412002,Hunan,China
    2.Fujian Key Laboratory of Advanced Materials,College of Materials,Xiamen University,Xiamen 361005,Fujian,China
    3.Ocean Engineering,Naval University of Engineering,Wuhan 430033,China
    4.National Key Laboratory of Science and Technology on Advanced Composites in Special Environments,Harbin Institute of Technology,Harbin 150080,China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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