Aerosol-assisted submicron γ-Fe2O3/C spheres as a promising heterogeneous Fenton-like catalyst for soil and groundwater remediation: Transport, adsorption and catalytic ability

Aerosol-assisted submicron γ-Fe₂O₃/C spheres as a promising heterogeneous Fenton-like catalyst for soil and groundwater remediation: Transport, adsorption and catalytic ability

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Jingjing Zhan^a^,^*, Mingfei Li^a, Xiujuan Zhang^b, Yu An^a, Weiqi Sun^a, Aixia Peng^a, Hao Zhou^a

Chinese Chemical Letters | 2020, 31(3) : 715 - 720

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Chinese Chemical Letters | 2020, 31(3): 715-720

• Communication •

Aerosol-assisted submicron γ-Fe₂O₃/C spheres as a promising heterogeneous Fenton-like catalyst for soil and groundwater remediation: Transport, adsorption and catalytic ability

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Jingjing Zhan^a^,^*, Mingfei Li^a, Xiujuan Zhang^b, Yu An^a, Weiqi Sun^a, Aixia Peng^a, Hao Zhou^a

Affiliations

^a School of Food and Environment, Dalian University of Technology, Panjin 124221, China

^b School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin 124221, China

Published: 2020-03-15 doi: 10.1016/j.cclet.2019.09.001

Outline

Abstract

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This research reports a novel heterogeneous Fenton-like catalyst which could freely move through the model sediments and easily seize the pollutants in addition to efficiently catalyze H₂O₂, well suitable for soil and groundwater remediation. Herein, submicron γ-Fe₂O₃/C spheres were synthesized through a facile one-step aerosol-based process. In a series of column tests, these spheres exhibit better transport ability due to their optimal size, conforming to the prediction by the Tufenkji-Elimelech filtration theory. Meanwhile, γ-Fe₂O₃/C spheres could act as a strong adsorbent for organic pollutants owing to the presence of carbon, thereby providing a driving force to gather contaminants into their vicinity and facilitating the reaction. In addition, immobilization of γ-Fe₂O₃ nanoparticles into carbon spheres protects iron oxides from aggregation, and thus retains the number of active sites for catalytic decomposition of H₂O₂. Hence, the system containing the as-prepared γ-Fe₂O₃/C spheres and H₂O₂ shows the high removal efficiency and degradation efficiency in the remediation of recalcitrant organic contaminants such as methylene blue and sulfamethoxazole.

Key words

Heterogeneous Fenton / Groundwater remediation / Aerosol-assisted materials / Transport / Adsorption

Cite this Article

Jingjing Zhan, Mingfei Li, Xiujuan Zhang, Yu An, Weiqi Sun, Aixia Peng, Hao Zhou. Aerosol-assisted submicron γ-Fe₂O₃/C spheres as a promising heterogeneous Fenton-like catalyst for soil and groundwater remediation: Transport, adsorption and catalytic ability[J]. Chinese Chemical Letters, 2020 , 31 (3) : 715 -720 . DOI: 10.1016/j.cclet.2019.09.001

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With the rapid growth of population, environmental pollution has become increasingly serious in the world [1]. Among a variety of pollutants, recalcitrant organic contaminants such as dyes and antibiotics are of special concern because they are difficult to degrade by means of common physical and chemical methods [2, 3]. For this reason, advanced oxidation processes such as Fenton reaction have been widely applied to remediate refractory organic pollutants from water and soils [4, 5].

However, classic Fenton is only effective under very acidic conditions, which inevitably cause soil acidification and massive amounts of iron sludge [6, 7]. To overcome these drawbacks, heterogeneous catalysts were recently employed to replace homogeneous catalyst Fe²⁺, and the corresponding process is called Fenton-like or modified Fenton [8]. Previous studies have shown that iron oxide nanoparticles including magnetite (Fe₃O₄)[9-11], goethite (α-FeOOH) [12], hematite (α-Fe₂O₃)[13] and maghemite (γ-Fe₂O₃)[14, 15] were often used as heterogeneous Fenton-like catalysts. Furthermore, supported heterogeneous catalysts were developed to avoid the aggregation of nano-scaled catalysts [16, 17], and common supports include zeolite [18, 19], carbon xerogels [20], carbon nanotube [21], alginate beads [22], Nafion membrane [23], cationic exchange resin [24], and so on.

Most of current studies related to heterogeneous Fenton-like reactions have just been focused on the application of water treatment, while there is no information on the investigation of heterogeneous Fenton-like catalysts for the purpose of subsurface remediation. Although naturally existing iron minerals may catalyze H₂O₂ in some area, extremely low efficiency and complex soil heterogeneity make it necessary to supplement the extra heterogeneous catalysts in the practical application [25]. Indeed, the most desirable application of heterogeneous Fenton-like reactions for subsurface remediation is the in-situ injection of chemical oxidants including H₂O₂ and catalysts into the soil [26]. In this regard, mobility of catalysts in subsurface is becoming of great importance as removal efficiency is determined by the contact among organic pollutants, catalysts and H₂O₂. However, it was reported that current supports are generally larger than 2 μm, which are not movable under typical subsurface conditions according to classical filtration theory and the corresponding Tufenkji–Elimelech model [27-29]. Therefore, common supported heterogeneous catalysts in micron size range are not suitable for the in-situ Fenton-like treatment of contaminated soil due to their inappropriate size and the resultant poor mobility in the subsurface, although they offered excellent performance for water purification.

The objective of this paper was to present a heterogeneous Fenton-like catalyst which could be applied in subsurface remediation. In this study, submicron γ-Fe₂O₃/C spheres were synthesized through a facile one-step aerosol-based process, followed by the evaluation of their transport properties, pollutants adsorption and H₂O₂-activating ability. Our results revealed that as-prepared composites may hold the following advantages for future applications: (1) the optimum size in the range of 100 nm – 1 μm guarantees that the composites effectively transport through sediments and easily reach the contamination zone, beneficial for in-situ subsurface remediation; (2) immobilization of γ-Fe₂O₃ into carbon spheres cause less prone to aggregation and negligible iron leaching, and thus maintaining high H₂O₂-activating ability; (3) carbon serves as a strong adsorbent in addition to a support and therefore helps to uptake the pollutants from soil, facilitating the contact of catalysts–pollutants and enhancing the removal efficiency. To the best of our knowledge, this is the first report of a heterogeneous Fenton-like catalyst with good mobility intended for use in soil and groundwater remediation,

We synthesized submicron γ-Fe₂O₃/C spheres using a self-built aerosol setup as depicted in Fig. 1. The procedure is similar to our earlier work [30-32], but a commercial nebulizer (402AI, Jiangsu Yuyue Medical Equipment & Supply Co., Ltd.) instead of the costly atomizer nozzle was firstly used, paving the way for the future scale-up. Typically, 6 g of sucrose and 5 g of FeSO₄7H₂O were firstly dissolved in 40 mL deionized water. Then, the precursor solution was ultrasonically nebulized to droplets and pass through a heating zone driven by the carrier gas (N₂). The temperature was held at 900 ℃ in the heating zone. The produced black particles were collected by two consecutive water bubblers. Subsequently, the obtained particles were washed by deionized water for several times to remove purities and dried at 60 ℃ before use. In the process, each aerosol droplets containing sucrose and iron sulfate went through the high temperature zone, where sucrose dehydration (Eq. 1) and iron sulfate decomposition (Eq. 2) took place, resulting in the formation of γ-Fe₂O₃/C spheres.

(1)

(2)

The morphology and microstructure of the particles was characterized by SEM, TEM, XRD and the N₂ adsorption. The characterization method and equipment are depicted in Supporting information. As shown in Fig. 2a, the SEM image indicates the obtained materials are spherical with variable size ranging from 100 nm to 1 μm, which is the typical feature of materials synthesized through aerosol-based process [33-36]. Furthermore, the TEM image (Fig. 2b) illustrates an even distribution of iron oxides without aggregation throughout the carbon matrix. All diffraction peaks in the XRD pattern (Fig. 2c) are well matched with the correspondence planes of γ-Fe₂O₃ according to JCPDS No. 39- 1346. In addition, the N₂ adsorption isotherm of γ-Fe₂O₃/C is shown in Fig. 2d, which reveals that the surface area was 231.0 m²/ g, calculated by the Brunauer–Emmet–Teller (BET) method. The pore volume was 0.364 cm³/g based on Barret–Joyner–Halenda (BJH) model. In fact, the porosity of supports is desired in the application, which may ensure the convenient entry of H₂O₂ to contact the surface of the interior iron oxides.

Classic filtration theory assumes that three mechanisms including diffusion, interception and sedimentation account for the trajectory of colloidal particles through porous media such as soil. Furthermore, the Tufenkji-Elimelech equation calculated the theoretical single contact efficiency (η₀) to predict the collision probability of migrating particles with the collector. Apparently, the lower contact efficiency implies the better transportability on the premise of the same attachment efficiency. Intuitively, the smaller particles could transport more effectively through the sand. However, we have correlated the collector efficiency with particle size, where a concave curve (Fig. 3a) displays the optimal size for γ-Fe₂O₃/C and bare Fe₂O₃ particles to freely move through porous media is in the submicron scale (300 nm – 1 μm is the best) under conditions closed to most sediment systems. The details of η₀ calculation has been shown in Supporting information.

The mobility of submicron γ-Fe₂O₃/C spheres in the subsurface was evaluated by a series of sand-packed column experiments, which were designed to simulate the injection of heterogeneous catalysts into water-saturated porous media. The column tests were based on a common 50 mL glass burette. In the experiment, the column was firstly packed with dry sand, which was in the size range of 300–700 μm. During the packing, intermittent vibration was adopted to ensure uniform packing and the packed volume was maintained at 20 mL. A small cotton plug was placed at the bottom of each column to prevent the loss of the sand. Then, the column was saturated with water prior to the injection of the materials containing suspension. The porosity of the column was determined as 0.42 following the previously reported method [29] and accordingly the pore volume (PV) was 8.4 mL. After 3 PVs of bulk suspension with desired concentration (either γ-Fe₂O₃/C or bare γ-Fe₂O₃) was fed, each column was flushed with 9 PVs of water at a flow rate of 18 mL/min (superficial velocity of 20 cm/min, controlled by a peristaltic pump). Effluent samples were collected every 1 PV. Each sample was digested by adding 3 mol/L HCl solution and the total iron concentration was measured with 1, 10–phenanthroline spectrophotometric method [37].

Fig. 3b shows visual comparison between submicron γ-Fe₂O₃/C spheres and commercial available bare γ-Fe₂O₃ nanoparticles (50– 1000 nm). The concentrations of the influent suspensions were both at 3 g/L. In the case of bare γ-Fe₂O₃ nanoparticles, only clear solution passed through the columns and most of the particles were trapped at the entrance end of the column. This indicates that bare γ-Fe₂O₃ nanoparticles had poor transportability because they form aggregates rapidly and thus are easily intercepted by the porous media. In contrast, submicron γ-Fe₂O₃/C spheres were able to travel through the column and elute efficiently, confirmed by the visibly black particles collected in the conical flask. Fig. 3c shows breakthrough curves of submicron γ-Fe₂O₃/C spheres with varied concentrations, which are plotted as the relative concentration of solid materials in the effluent (C/C₀) versus PVs. At 1 g/mL, almost 67.2% of particles were eluted from the sand column after flush with 12 PVs under the specified conditions. Meanwhile, the relative effluent concentration slightly decreased to 63.3% for 3 g/mL, and 42.0% for 9 g/mL.

All heterogeneous Fenton-like experiments were conducted at room temperature and the initial pH of the solution was adjusted by H₂SO₄ (0.1 mol/L) or NaOH (0.1 mol/L). In the experiment, 10 mg of submicron γ-Fe₂O₃/C spheres was firstly added into a 10 mL of methylene blue (MB)-contaminated aqueous solutions, followed by the addition of desired amount of H₂O₂. The mixture was then stirred during the reaction. At predetermined time, the experiment was terminated by the magnetic separation of γ-Fe₂O₃/C spheres from the solution. The residual MB in the supernatant was directly analyzed by an UV×vis spectrometer (5200PC, China) at wavelength of 665 nm. To determine the amount of the adsorbed MB, solid catalysts were washed by 10 mL of ethanol for three times to completely extract MB. Subsequently, the amount of degraded MB was calculated by subtracting the total of the residual and the adsorbed MB from the initial MB. In the experiments, MB was chosen as the primary probe molecule because it was a typical recalcitrant pollutant widely used in previously reported Fentonlike reactions. In addition, the remediation of sulfamethoxazole (SMX) was simply investigated as a complement, considering that it is one of frequently detected pollutants in soil and groundwater. Their structures are shown in Fig. S1 (Supporting information).

Fig. 4a shows photographs of untreated and treated MBcontaminated solutions, which visually reflect the effectiveness of the system γ-Fe₂O₃/C+H₂O₂ on the treatment of MB over a period of 4 h. A noticeable discoloration in only 10 min illustrates that most of MB has been quickly removed from the aqueous phase. However, when catalysts γ-Fe₂O₃/C spheres were magnetically separated and rinsed by ethanol, blue extractions were observed again which means that MB was initially adsorbed on the γ-Fe₂O₃/C spheres rather than oxidation. Hence, preliminary vial tests indicate that there are three possible routes for MB during the removal process including degradation due to the Fenton-like reaction, adsorption by heterogeneous catalysts and as the residual remaining in aqueous phase.

Fig. 4b presents the kinetics of MB removal and degradation in the presence of γ-Fe₂O₃/C spheres and H₂O₂, where the difference between removal and degradation is that the latter only counts the decrease of solution MB concentration arisen from Fentonlike oxidation, but the contribution from adsorption was excluded. As a control, the system combining bare γ-Fe₂O₃ nanoparticles and H₂O₂ was also studied. The removal curve of the γ-Fe₂O₃/C + H₂O₂ system (the solid black line: M_l/M₀) exhibits an immediate sharp drop to 20.7% of its initial concentration followed by a much slower decrease. Obviously, this is mainly the result of MB partitioning from the aqueous phase to the solid surface through strong adsorption. To accurately determine the reactivity, the degradation curve of the γ-Fe₂O₃/C + H₂O₂ system (the dash red line: (M_l+M_s)/ M₀) was presented which only counted the decrease of solution MB concentration arisen from Fenton-like oxidation, but the contribution from adsorption was excluded. From this dash line, it could been seen that 4.9%, 21.2% and 100% of MB were degraded in 5 min, 1 h and 4 h, respectively. In contrast, the removal curve and the degradation curve for the control experiment are the same because the amount of MB adsorbed on bare γ-Fe₂O₃ was negligible. Clearly, there is no pronounced decrease in MB concentration and only 28.3% of the pollutant was removed from the solution in 4 h, showing a much slower removal and degradation rate.

The adsorption ability of the γ-Fe₂O₃/C spheres was further investigated by the time-dependent adsorption capacity under different initial MB concentrations. Herein, 10 mg of γ-Fe₂O₃/C spheres and 10 mL of MB solution at 10–50 mg/L were used in the absence of H₂O₂. As shown in Fig. 4c, in each case the adsorptive capacity rises dramatically in the first few minutes, followed by the gradual increase till equilibrium.

Meanwhile, we found the adsorption fits Langmuir model where the maximum adsorption amount q_m arrives 42.166 mg/g and K_L is 2.723 L/mg. Furthermore, we compared the adsorption capability of the γ-Fe₂O₃/C spheres with the materials reported in the literature. Under the same condition with the initial concentration of MB at 40 mg/L, the uptake amounts of MB are 6.8, 6.0, and 8.0 mg/g for α-Fe₂O₃@GO, Fe₃O₄-carbon and γ-Fe₂O₃-Fecarbon, lower than 28.8 mg/g for aerosol-assisted γ-Fe₂O₃/C spheres. In addition, similar phenomena were observed for SMX as shown in the Supporting information, where Figs. S2 and S3 (Supporting information) demonstrated removal and adsorption kinetics, respectively.

To understand whether heterogeneous γ-Fe₂O₃/C spheres or dissolved iron ions from maghemite account for the decomposition of H₂O₂, the dissolved iron concentration was measured in the experiment. As shown in Fig. 4d, the leached iron concentration was detected at 0.028 mg/L after 6 h when 1 g/L of γ-Fe₂O₃/C spheres were used at pH 7, far below the acceptable limit of 2 mg/L according to the EU discharge standard [38]. Furthermore, the degradation efficiency at the same level of dissolved iron (~0.028 mg/L) was tested to be 4.7% in 4 h, negligible compared to the use of γ-Fe₂O₃/C spheres. Meanwhile, the supernatant obtained after 6 h was reused with the addition of H₂O₂ for another catalytic test, and no significant removal phenomenon was observed in absence of the γ-Fe₂O₃/C. Hence, it is concluded that soluble iron only existed in insufficient concentration to catalyzed hydrogen peroxide decomposition. Accordingly, the mechanism in this study is the Fe^Ⅲ–initiated decomposition of H₂O₂ under the circumneutral conditions, involving a series of chain reactions as previously described [39].

Hence, in our understanding, the significant enhancement in the degradation rate for the γ-Fe₂O₃/C + H₂O₂ system might be attributed to two reasons. Firstly, the distribution of nano-scaled γ-Fe₂O₃ catalysts onto carbon spheres prevented the aggregation, and thus retained the number of active sites for reaction. Secondly, the strong adsorption brought about a driving force for organic pollutants from the bulk solution to the vicinity of γ-Fe₂O₃/C spheres which leads to eventual oxidization. The adsorptivereaction system proposed here is well-suited for organic pollutants remediation in soil and groundwater as it also provides a strong sequestration from the natural organic matters such as humic acid in addition to Fenton-like oxidation.

Moreover, the effects from experimental parameters were investigated and the results are shown in Fig. 5. It is well known that pH value has a remarkable effect on the Fenton-like reaction, therefore the elimination of MB by the γ-Fe₂O₃/C + H₂O₂ system was investigated at four different pH values of 3.0, 5.0, 7.0 and 9.0. As seen in Fig. 5a, the MB removal efficiency was nearly unaffected by initial pH (solid lines), while the degradation efficiency decreased with an increase in the initial pH (dash lines). It should be noted that the catalytic activity of the system is enough to degrade organic pollutants at pH 7.0, and the system is still active under the alkaline condition although the degradation efficiency is lowered to 45.8% in 4 h. The wide range of the working pH is very attractive for the practical application considering the soil diversity. The higher degradation activity at the acidic condition may be related to the released Fe³⁺ ions in aqueous solution. On the contrary, the formation of ^·OH on the surface of catalyst was gradually restricted with pH increasing to 9, which resulted in a slow degradation rate of MB.

The effects of the initial H₂O₂ concentration on the removal and degradation of MB were studied under the condition of [MB]₀ = 30 mg/L, [catalyst] = 1 g/L and pH 7. Similarly, there is no change on the removal efficiency because adsorption was not affected by the amount of H₂O₂. However, the degradation efficiency was obviously improved as the H₂O₂ concentrations increased from 0.05 mol/L to 0.2 mol/L. The reason is that the degradation efficiency is directly related to the amount of OH generated by the catalytic decomposition of H₂O₂, leading to much MB decomposition with the high concentration of H₂O₂. The catalyst is still active at low H₂O₂ concentration, which has a great potential for an application in soil-treatment, where a moderate amount of H₂O₂ is required for economic and technical reasons. Conversely, a slight decrease was appeared when the concentration was further increased to 0.4 mol/L (Fig. 5b). The phenomenon could be explained by the scavenging effect of OH by H₂O₂ according to the following equations [40]:

(10)

(11)

Fig. 5c illustrates the effect that various concentration of MB had on the removal and degradation performance. With the increase of initial MB concentration from 20 mg/L to 50 mg/L, the instant drop of the removal efficiency decreased from 90.0% to 33.7% accordingly. Meanwhile, the degradation efficiency of MB in 4 h dropped from 100% to 62.3%. The reusability of the γ-Fe₂O₃/C was finally evaluated by recycling reactions for the degradation of MB under identical experimental conditions. At the end of one experiment, the material was magnetically separated from the solution and subsequently washed with ethanol and dried in a vacuum oven at 60 ℃ overnight before the next test. As shown in Fig. 5d, the catalyst retained a good activity after 5 cycles, despite a slight decrease in MB removal efficiency from 99% to 89% in 4 h. The result indicates that the obtained heterogeneous catalyst could still be effective when reinjection of H₂O₂ into the soil is needed.

To summary, the submicron γ-Fe₂O₃/C spheres developed in this work have exhibited the ability to be an effective heterogeneous Fenton-like catalyst for soil and groundwater remediation. Differing from the treatment of industrial wastewater, the most desirable characteristic of heterogeneous Fenton-like catalysts for subsurface remediation is to possess a good mobility in subsurface, as removal efficiency is determined by the contact among organic pollutants, catalysts and H₂O₂. The concept behind our technology involves the direct injection of γ-Fe₂O₃/C spheres and H₂O₂ into contaminated groundwater-saturated sediments. As soon as the γ-Fe₂O₃/C spheres enter into the contaminated area, the carbon component could act as an adsorbent for organic pollutants, thereby providing a driving force to capture the adsorbed contaminants from the soil to the vicinity of iron oxides for further reactions. Consequently Fenton-like reactions catalyzed by γ-Fe₂O₃ lead to eventual degradation of organic pollutants. Hence, the system containing this novel heterogeneous catalyst and H₂O₂ is able to sequester and degrade organic pollutants simultaneously in addition to move through the subsurface readily. However, we consider this work is just the first step which is necessary in determining the potential for practical applications. Several studies such as the effects of the organic matters in the soil, the competitive adsorption of cations and anions, the long term fate and transport of these materials are still in progress.

Acknowledgments

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This work was supported by the National Natural Science Foundation of China (NSFC, Nos. 21876022, 31400840), the Fundamental Research Funds for the Central Universities (No.DUT16ZD226) and PetroChina Innovation Foundation (No. 2017D- 5007-0609).

Appendix A. Supplementary data

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Supplementary material related to this article can be found, in the online version, at doi:https://doi.org/10.1016/j.cclet.2019.09.001.

References

Less

[1]

R.P. Schwarzenbach, B.I. Escher, K. Fenner, et al., Science 313 (2006) 1072-1077.

[2]

S. Rong, Y. Sun, Z. Zhao, Chin. Chem. Lett. 25 (2014) 187-192.

[3]

Y. Zhang, S. Hu, H. Zhang, et al., Sci. Total Environ. 607-608 (2017) 1348-1356.

[4]

B. Ranc, P. Faure, V. Croze, M.O. Simonnot, J. Hazard. Mater. 312 (2016) 280-297.

[5]

J. Shi, Z. Ai, L. Zhang, Water Res. 59 (2014) 145-153.

[6]

Y. Wang, H. Zhao, M. Li, J. Fan, G. Zhao, Appl. Catal. B -Environ. 147 (2014) 534-545.

[7]

H. Fida, G. Zhang, S. Guo, A. Naeem, J. Colloid Interface Sci. 490 (2017) 859-868.

[8]

W. Luo, L. Zhu, N. Wang, et al., Environ. Sci. Technol. 44 (2010) 1786-1791.

[9]

F. Chen, S. Xie, X. Huang, X. Qiu, J. Hazard. Mater. 322 (2017) 152-162.

[10]

M. Munoz, Z.M. de Pedro, J.A. Casas, J.J. Rodriguez, Appl. Catal. B -Environ. 176-177 (2015) 249-265.

[11]

K. Chen, G. Wang, W. Li, et al., Chin. Chem. Lett. 25 (2014) 1455-1460.

[12]

X. Qian, M. Ren, Y. Zhu, et al., Environ. Sci. Technol. 51 (2017) 3993-4000.

[13]

Y. Zhao, F. Pan, H. Li, et al., J. Mater. Chem. A 1 (2013) 7242.

[14]

N. Ferroudj, J. Nzimoto, A. Davidson, et al., Appl. Catal. B -Environ. 136-137 (2013) 9-18.

[15]

T. Chen, Y. Xiong, Y. Qin, et al., RSC Adv. 7 (2017) 336-343.

[16]

S. Zhang, X. Zhao, H. Niu, et al., J. Hazard. Mater. 167 (2009) 560-566.

[17]

R.S. Ribeiro, A.M.T. Silva, J.L. Figueiredo, J.L. Faria, H.T. Gomes, Appl. Catal. B -Environ 187 (2016) 428-460.

[18]

S. Navalon, M. Alvaro, H. Garcia, Appl. Catal. B -Environ. 99 (2010) 1-26.

[19]

X. Yang, X. Cheng, A.A. Elzatahry, et al., Chin. Chem. Lett. 30 (2019) 324-330.

[20]

R.S. Ribeiro, Z. Frontistis, D. Mantzavinos, et al., Appl. Catal. B -Environ. 199 (2016) 170-186.

[21]

V. Cleveland, J. Bingham, E. Kan, Sep. Purif. Technol. 133 (2014) 388-395.

[22]

O. Iglesias, J. Gómez, M. Pazos, M.Á. Sanromán, Appl. Catal. B -Environ. 144 (2014) 416-424.

[23]

J. Kiwi, N. Denisov, Y. Gak, et al., Langmuir 18 (2002) 9054-9066.

[24]

J. Feng, X. Hu, P. Yue, Chem. Eng. J. 100 (2004) 159-165.

[25]

A.L. Pham, F.M. Doyle, D.L. Sedlak, Water Res. 46 (2012) 6454-6462.

[26]

C.L. Yap, S. Gan, H.K. Ng, Chemosphere 83 (2011) 1414-1430.

[27]

K. Yao, M.T. Habibian, C.R. O'Melia, Environ. Sci. Technol. 11 (1971) 1105-1112.

[28]

N. Tufenkji, M. Elimelech, Environ. Sci. Technol. 38 (2004) 529-536.

[29]

J. Zhan, T. Zheng, G. Piringer, et al., Environ. Sci. Technol. 42 (2008) 8871-8876.

[30]

H. Qu, X. Zhang, J. Zhan, et al., ACS Sustain. Chem. Eng. 6 (2018) 7380-7389.

[31]

J. He, Y. Long, Y. Wang, C. Wei, J. Zhan, ACS Appl. Mater. Interfaces 8 (2016) 16699-16707.

[32]

J. Zhan, I. Kolesnichenko, B. Sunkara, et al., Environ. Sci. Technol. 45 (2011) 1949-1954.

[33]

Y.F. Lu, H.Y. Fan, A. Stump, et al., Nature 398 (1999) 223-226.

[34]

L. Ai, J. He, Y. Wang, C. Wei, J. Zhan, RSC Adv. 6 (2016) 56108-56115.

[35]

J. Zhan, B. Sunkara, J. Tang, et al., Ind. Eng. Chem. Res. 50 (2011) 13021-13029.

[36]

Y. Long, M. Li, H. Qu, et al., RSC Adv. 6 (2016) 103910-103918.

[37]

T. Xu, R. Zhu, G. Zhu, et al., Appl. Catal. B -Environ. 212 (2017) 50-58.

[38]

J.H. Ramirez, F.J. Maldonado-Hodar, A.F. Perez-Cadenas, et al., Appl. Catal. B -Environ. 75 (2007) 312-323.

[39]

X. Hu, B. Liu, Y. Deng, et al., Appl. Catal. B-Environ 107 (2011) 274-283.

[40]

X. Xue, K. Hanna, M. Abdelmoula, N. Deng, Appl. Catal. B -Environ. 89 (2009) 432-440.

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Year 2020 volume 31 Issue 3

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doi: 10.1016/j.cclet.2019.09.001

Receive Date：2019-07-23
Online Date：2026-01-31
Published：2020-03-15

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Received：2019-07-23
Revised：2019-08-22
Accepted：2019-09-02

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^a School of Food and Environment, Dalian University of Technology, Panjin 124221, China

^b School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin 124221, China

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表12种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

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Fig. 1 Aerosol-assisted experimental apparatus.

Fig. 2 (a) SEM, (b) TEM, (c) XRD and (d) Nitrogen adsorption-desorption isotherm of submicron γ-Fe₂O₃/C spheres. The inset is the size distribution of the spheres.

Fig. 3 (a) Collector efficiency dependency on the particle size as predicted by the Tufenkji-Elimelech filtration model. The two curves represent the theory forγ-Fe₂O₃/C and g-Fe₂O₃. (b) Elution characteristics of submicronγ-Fe₂O₃/C spheres (left) and pristineγ-Fe₂O₃ (right); (c) Elution profiles of submicronγ-Fe₂O₃/C spheres with different initial concentrations. M/M₀: the fraction of particles that are eluted.

Fig. 4 (a) Photographs of supernatants and extractions of MB-contaminated solutions treated by the systemγ-Fe₂O₃/C+H₂O₂ at different times. (b) MB removal and degradation rates for submicronγ-Fe₂O₃/C spheres and pristineγ-Fe₂O₃ in the presence of H₂O₂. M_l: the amount of MB remaining in the solution, M_s: the amount of MB adsorbed on the catalyst, M₀: the amount of the original MB in the solution. (c) Adsorption capacity for MB onγ-Fe₂O₃/C and (d) iron leaching during the reaction. Experimental conditions: T = 25 ℃, pH 7, [H₂O₂]₀ = 0.2 μmol/L, [MB]₀ = 30 mg/L, [catalyst] = 1 g/L.

Fig. 5 Effects of (a) the initial pH, (b) the concentration of added H₂O₂ and (c) the initial concentration of MB on the removal and degradation of MB. (d) The reusability of the g-Fe₂O₃/C. Experimental conditions (except the parameter under investigation): T = 25 ℃, pH 7, [H₂O₂]₀ = 0.2 mol/L, [MB]₀ = 30 mg/L, [catalyst] = 1 g/L. Solid line is for M/M₀, and dash line is for (M_l+M_s)/M₀.

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