Defect engineering using Ti-doped calcium niobate nanosheets in polymer-based dielectrics for high temperature capacitance

Defect engineering using Ti-doped calcium niobate nanosheets in polymer-based dielectrics for high temperature capacitance

PDF

Dongyang Chen^a, Xiaoxu Liu^a, Haonan Chen^a, Yaru Wang^a, Jing Li^a, Jiaming Sun^a, Xiaofeng Wang^b, Qiong Liu^c

Chinese Chemical Letters | 2026, 37(9) : 111436

Less

Chinese Chemical Letters | 2026, 37(9): 111436

• Communication •

Defect engineering using Ti-doped calcium niobate nanosheets in polymer-based dielectrics for high temperature capacitance

Full

Dongyang Chen^a, Xiaoxu Liu^a, Haonan Chen^a, Yaru Wang^a, Jing Li^a, Jiaming Sun^a, Xiaofeng Wang^b, Qiong Liu^c

Affiliations

^aSchool of Materials Science and Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, China

^bSchool of Mechanical and Electrical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China

^cXi'an Herong New Energy Technology Co., Ltd., Xi'an 710021, China

About Author:

CRediT authorship contribution statement

Dongyang Chen: Writing – review & editing, Writing – original draft, Visualization, Validation, Software, Resources, Methodology, Investigation, Data curation, Conceptualization.

Xiaoxu Liu: Writing – review & editing, Supervision, Project administration, Investigation, Funding acquisition, Conceptualization.

Haonan Chen: Methodology, Investigation.

Yaru Wang: Methodology.

Jing Li: Visualization, Investigation.

Jiaming Sun: Methodology, Investigation.

Xiaofeng Wang: Writing – review & editing, Methodology, Investigation.

Qiong Liu: Writing – review & editing.

Published: 2026-09-15 doi: 10.1016/j.cclet.2025.111436

Outline

Abstract

Less

Although the incorporation of fillers has improved the high temperature (150–200 ℃) capacitance of polymer composite dielectrics, effective strategies for designing filler-matrix interface structures remains a formidable challenge. Herein, defect-rich nanosheets (Ca₂Nb_2.75Ti_0.25O₁₀, CT) were coated with a zeolite imidazolate frameworks-8 (ZIF-8, Zn(C₄H₅N₂)₂) layer (mCT). The mCT was integrated into polyetherimide (PEI) to create the polymer-based dielectrics. The defects on the surface of the negative CT nanosheets exhibited strong anchoring effects on the Zn²⁺ in ZIF-8, enhancing the filler-coating layer interface. Additionally, X-ray absorption fine structure analysis and density functional theory confirmed that the porous ZIF-8 coating layer forms strong coordination bonds with the PEI molecular chains, thereby an increased band gap (3.3 eV) of PEI/mCT compared to PEI (3.0 eV). It demonstrated exceptional performance at high temperatures, achieving ultra-high energy storage densities of 5.25 and 4.47 J/cm³ with efficiency > 90% at 150 and 200 ℃, which are higher than PEI (0.4 and 0.4 J/cm³). This work offers a new approach and reference for designing high-temperature polymer composite dielectrics for energy storage applications.

Key words

Defect engineering / Titanium-doped calcium niobate nanosheets / Inorganic-organic interface / Polymer dielectrics / High temperature capacitance

Cite this Article

Dongyang Chen, Xiaoxu Liu, Haonan Chen, Yaru Wang, Jing Li, Jiaming Sun, Xiaofeng Wang, Qiong Liu. Defect engineering using Ti-doped calcium niobate nanosheets in polymer-based dielectrics for high temperature capacitance[J]. Chinese Chemical Letters, 2026 , 37 (9) : 111436 - . DOI: 10.1016/j.cclet.2025.111436

Full Text

Less

Polymer capacitors are known for their high-power density, voltage resistance, and exceptional reliability, advancing modern power electronic systems [1–7]. There is a growing demand for polymer capacitors capable of operating at extreme temperatures (150–200 ℃) in applications such as hybrid electric vehicles, oil and gas exploration, and wind generators [8–12]. However, commercially available biaxially oriented polypropylene (BOPP) struggles at high temperatures [13], leading to the development of high glass transition temperature polymers like Kapton (PI), ULTEM (PEI) and ISARYL (FPE) for high-temperature dielectric capacitors [14]. These polymers often exhibit exponentially increasing conduction currents with temperature and electric field, reducing discharge energy density (U_e) and limiting their industrial application as dielectrics [15,16]. Research has led to strategies to suppress high-temperature conductivity and enhance energy storage properties of polymer-based dielectrics [17,18]. For example, cross-linked c-BCB with BNNs nanosheets shows a tenfold reduction in conductivity and impressive energy storage (1.6 J/cm³ at 200 ℃, η > 90%) [19]. Physical cross-linking in PI-based polymers achieves 4.0 J/cm³ with η > 90% at 200 ℃ [20]. Additionally, wide bandgap nanofillers like Si₃N₄, BNNs, Al₂O₃, and SiO₂ [21–24] have been used to create barriers at the electrode-polymer dielectric interface, improving capacitive performance by suppressing charge injection. Inorganic nanofillers with high thermal stability, such as BNNs, HfO₂, Al₂O₃ [25], and SiO₂ [26], alter the energy levels of polymer dielectrics, improving performance by inducing charge traps and capturing hot carriers [27–30]. Most methods focus on the filler-polymer structure, but the inorganic-organic interface significantly impacts insulation and capacitive performance [17,18,31]. Our previous research has shown that hierarchical nanofillers (CNO@Al₂O₃) [32] and organic-metal hybrid interfaces (MOHI) enhance polymer capacitor energy storage performance [33]. Interface structure design is thus a promising strategy for developing advanced polymer dielectrics.

In this work, we present a novel strategy for enhancing high-temperature energy storage in polymer dielectrics by incorporating defect-engineered Ca₂Nb_2.75Ti_0.25O₁₀ (CT) nanosheets. The defect sites facilitate the tight growth of ZIF-8, which introduces low-coordinated Zn²⁺ capable of forming coordination bonds with the polymer. This interaction effectively suppresses carbonyl relaxation. As a result, the composite dielectric achieves a remarkable discharged energy density of 4.47 J/cm³ at 200 ℃ with an efficiency exceeding 90%, even at a low filler loading 0.5 wt%. This work provides a new strategy for designing polymer dielectrics with outstanding high temperature capacitance.

The mechanism diagram of the coordination between metal ions and organic compounds induced by Ti-doped calcium niobate (Ca₂Nb_2.75Ti_0.25O₁₀, CT) nanosheets is shown in Fig. 1a. The CT nanosheets were prepared via solid-phase reaction. As shown in Fig. S1a (Supporting information), the X-ray diffraction (XRD) pattern of pre-CT exhibits weak (001), (002) and (003) diffraction peaks compared to Ti-undoped nanosheets reported previously [33], indicating altered interlayer spacing and reduced ordering (Fig. S1b in Supporting information). The transmission electron microscopy (TEM) in Fig. S2 (Supporting information) reveales the typical 2D stacked morphology of CT, while element mapping (Fig. 1b) confirms Ti incorporation. Subsequently, ZIF-8 (zeolitic imidazolate framework-8) was coated onto CT to produce the modified nanosheets (mCT).

TEM image of mCT (Fig. 1c) shows the granular morphology of ZIF-8, confirming the successful coating of ZIF-8 on the CT. The electron density fluctuations in nanosheets were examined using small angle X-ray scattering (SAXS). As shown in Fig. 1d, the positive deviation at the CT Porod curve tail indicates that CT exhibits electron density fluctuations or non-uniform regions attributed to defects caused by Ti doping [34]. The negative deviation at the mCT Porod curve tail suggests the presence of dispersed transition layer. This transition layer arises from the physical and chemical interactions between CT and ZIF-8. In Fig. 1e, the XRD pattern of mCT exhibits a notable decrease intensity of ZIF-8. The Fourier transform infrared spectroscopy (FT-IR) results show the presence of ZIF-8 in mCT (Fig. 1f). Additionally, the Nb-OH absorption peak exhibits bule shift from 775 cm^-1 to 779 cm^-1, and the Nb-O absorption peak shows red shift from 941 cm^-1 to 930 cm^-1 [32]. These shifts are attributed to the consumption of -OH groups during the interactions of Nb-O-Zn or Ti-O-Zn between ZIF-8 and CT. The X-ray photoelectron spectroscopy (XPS) analysis of nanosheets is shown in Fig. 1f, Figs. S3 and S4 (Supporting information). The additional peak of mCT (Fig. 1g) appeared at 532.0 eV can be ascribed to the interactions between ZIF-8 and CT, which hinders the electron transition of O elements in mCT. The strong interactions are also evidenced in the substantial peak area proportion (28.9%). The X-ray absorption fine structure (XAFS) measurements provided coordination information of Zn²⁺ in the mCT. As shown in Fig. 1h, the K-Edge of mCT displays a higher white line (WL) peak energy intensity (1.35) compared to Zn foil (1.05) and ZnO (1.16), and the K-Edge of mCT lies between Zn foil and ZnO. These results indicate that Zn in ZIF-8 possesses unoccupied orbitals, which serve as available sites for coordination bonding with PEI [35]. Extended X-ray absorption fine structure (EXAFS) analysis of mCT (Fig. 1i) confirmed the coordination environments involving Zn-N, Zn-O and Zn-Zn coordination. Detailed coordination parameters are provided in Table S1 (Supporting information). The Wavelet Transform (WT) plot of mCT in Fig. 1j provides evidence of Zn-N, Zn-O and Zn-Zn coordination in K-space.

Polymer dielectrics containing mCT were synthesized via in situ polymerization and designated as x mCT (PEI/x wt% mCT, x = 0, 0.2, 0.5 and 1.0). As shown in Fig. S5 (Supporting information) and Fig. 2a, PEI shows no gel after soaking in NMP 24 h, whereas 0.5 mCT exhibits optimal gel content (88%). Scanning electron microscopy of the x mCT (Fig. S6 in Supporting information) demonstrated that those with low filler loading are dense. Polymer dielectrics containing mCT also exhibit low surface energy. Figs. S7 and S8 (Supporting information) exhibit the increased water contact angle and a low root-mean-square value of 0.5 mCT, which are advantageous for the metallization of polymer dielectrics [36]. The chemical interaction between mCT and PEI is further supported by the C═O-Zn coordination peak (Figs. 2b and c). Two factors facilitate the formation of C═O-Zn coordination bonds: First, the presence of Zn²⁺ with unoccupied orbitals in mCT, as confirmed in Fig. 1h; Second, the oxygen atoms in the C═O groups of PEI possess lone pair electrons. To directly investigate the interaction between ZIF-8 and PEI, TEM was employed to observe the micro-regions of 0.5 mCT. As shown in Fig. 2d, no ZIF-8 particles were observed, and no nanoscale defects or free volume were detected at the CT-PEI interface region, which is consistent with the SEM results (Fig. S6). These results confirmed that the porous structure of ZIF-8 disrupted in the solvent and imidization (300 ℃) process, thereby preventing defects between CT an PEI. The schematic diagram illustrating the resulting coordination interactions (Fig. 2e). As depicted in Fig. 2f and Fig. S9 (Supporting information), x mCT and PEI demonstrate similar glass transition temperature (T_g, 223.2–224.6 ℃) and average inter-chain distance (5.36 Å).

Fig. S10 (Supporting information) shows the optical image and infrared spectrum of PEAA/0.5 mCT (where PEAA refers to polyether amide acid), providing evidence of coordination interactions occurring during the polycondensation process. As shown in Fig. 3a, the C═O peaks of PEAA and PEAA/0.5 mCT appears at 1719 cm^-1 and 1713–1723 cm^-1, which can be ascribed to C═O coordination between C═O and Zn²⁺. Additionally, PEAA/0.5 mCT exhibits a shoulder peak at 1196 cm^-1 attributed to the lone pair electrons of C—O-C. Subsequently, the consistent C—N characteristic peaks were identified in Fig. S11 (Supporting information), confirming the complete imidization of x mCT. The SAXS scattering patterns and Porod curves of x mCT are depicted in Fig. S11 (Supporting information) and Fig. 3b. All samples exhibit positive deviation at the Porod curve tails, indicating the absence of sharp interface within x mCT. The ln(q)-ln(I(q)) plot (Fig. 3c) shows that the D_m increases with mCT content, reaching a maximun of 3.04 for 0.5 mCT. This increased structural compactness is consistent with the wider bandgaps observed in UV–vis analysis (Fig. S13 in Supporting information), where PEI has a bandgap of 3.36 eV and 0.5 mCT reaches 3.48 eV. The coordination interaction between Zn and PEI in 0.5 mCT was analyzed using XAFS. Compared to the mCT, 0.5 mCT shows a lower WL energy position (labeled A and B in Fig. 3d) and a higher WL intensity (1.49 vs. 1.35), indicating a change in the electronic transition mode of the Zn element in mCT and 0.5 mCT. EXAFS analysis (Fig. 3e) reveals a reduced main peak intensity and slight peak broadening in 0.5 mCT, attributable to C═O-Zn coordination. The WT plot for 0.5 mCT (Fig. 3f) displays two lobes: a main lobe and a minor lobe are visible (Fig. 3f). The first one, localized in the △R = (1.0–2.2) Å and △k = (0–12) Å^-1 range. The second minor lobe collects the contributions coming from the Zn in ZIF-8 and the dimethylimidazole (2-MiM). Detailed coordination parameters for 0.5 mCT are provided in Table S1.

Fig. 4a shows the dielectric constant (ε_r) and loss (tanδ) of x mCT films measured at room temperature. The ε_r continuously increases with the content of mCT rising, for example, from 3.10 for the PEI to 3.73 for 1.0 mCT. Meanwhile, the tanδ of all polymer dielectrics remain below 0.015 across a frequency ranging of 10²–10⁶ Hz. Fig. S14 shows that the ε_r of all polymer dielectrics changes little from room temperature to 200 ℃. As shown in Fig. S15 (Supporting information) and Fig. 4b, the introduction of the mCT leads to a significant reduction in the current density at high electric field and wide temperature range (25–200 ℃), e.g., from 7.2 × 10^–7 A/cm² for PEI to 1.0 × 10^–7 A/cm² for 0.5 mCT at 100 MV/m and 200 ℃. The decrease of current density reduces the conduction loss when polymer dielectrics work at different temperatures, giving increase to an enhancement in the electrical breakdown strength (E_b) at different temperature. As shown in Fig. S16 (Supporting information) and Fig. 4c, the E_b of all films showed a decreasing trend with increasing temperature.

At 200 ℃, the incorporation of the optimal loading ratio of mCT (0.5 wt%) increased the E_b to 594 MV/m compared to 399 MV/m for the PEI. More notably, 0.5 mCT exhibited a higher β value (18.26 for 0.5 mCT vs. 9.86 for PEI), indicating enhanced electric field resistance and dielectric reliability of the polymer dielectric under harsh conditions due to the introduction of mCT. The energy storage performance of polymer dielectrics at various temperatures (25, 150 and 200 ℃) was obtained by electric displacement-electric field (D-E) loops (Figs. S17-S19 in Supporting information and Fig. 4d). The U_e of x mCT at different temperatures (25, 150 and 200 ℃) are presented in Fig. S20 (Supporting information) and Fig. 4e, in which the high temperature energy storage performance of x mCT are improved compared to PEI. At 200 ℃, the U_e with η > 90% reached 4.47 J/cm³ for 0.5 mCT which is an improvement of 728% over that of PEI (0.54 J/cm³). We prepared a large 0.5 mCT film of 12 × 18 cm² area (insert of Fig. 4f), and measured the breakdown and U_e at 600 MV/m and 200 ℃ at different regions. The results show high consistency across the different regions (573–640 MV/m and 4.32–4.71 J/cm³). Cyclic charging-discharging tests at 150 and 200 ℃ were performed to examine the stability of 0.5 mCT. As shown in Fig. 4g, 0.5 mCT exhibits stable energy storage performance over 10⁴ cycles under up to 150 and 200 ℃ at 300 MV/m. Furthermore, the U_e and η of 0.5 mCT polymer dielectric film were measured with different electrode diameters at 200 ℃ (Fig. 4h). It is found that the size of the electrodes has a negligible effect on the capacitive performance. Fig. 4i summarizes the U_e with η ≥ 90% at 200 ℃ and the electric field of 0.5 mCT and other advanced works. It is impressive that both the discharged energy density ~4.47 J/cm³ and electric field ~594 MV/m for the 0.5 mCT outperform all the reported dielectric polymers and polymer nanocomposites [33,37–46].

In order to investigate the effect of interface bonding on molecular orbitals of polymer dielectrics. Density functional theory (DFT) was employed to analyze the interactions between ZIF-8 and PEI and HOMO-LUMO gap of 0.5 mCT. As shown in Fig. 5a, Zn in the Zn/(2-MiM)₄ (ZIF-8 unit) exhibits neutrality when coordinated tetrahedrally with 4 ligands. However, when ZIF-8 grows on the surface of CT, spatial hindrance effects can lead to lower coordination numbers and unoccupied orbitals of ZIF-8.

In the PEI molecular chain, the oxygen atoms of C═O groups (shown in red) possess lone pair electrons. The coordination bonds in Zn/(2-MiM)₃-PEI result from unoccupied orbitals of Zn and C═O lone pairs. The electrostatic potential of Zn/(2-MiM)₃-PEI is also depicted. Fig. 5b analyzes the HOMO and LUMO for Zn/(2-MiM)₄, PEI, and Zn/(2-MiM)₃-PEI, showing a HOMO-LUMO gap of 2.985 eV for PEI, which increases to 3.306 eV in Zn/(2-MiM)₃-PEI. This electrostatic distribution confirms the electron-donating role of C═O and the coordination structure between Zn and C═O, with the Zn/(2-MiM)₃-PEI composite showing a larger HOMO-LUMO gap, indicating that 0.5 mCT exhibits an improved insulating properties.

In summary, we propose a strategy of incorporating defects to significantly enhance the high-temperature capacitance of polymer-based dielectrics. The optimal polymer dielectric achieved an ultra-high U_e of 4.47 J/cm³ with η > 90% at 200 ℃. Notably, the introduction of surface defects in nanosheets resulted in a more robust integration between the transitional MOF layer and nanosheets, as validated by XAFS. The DFT calculation indicate that MOF provides unoccupied orbitals to facilitate the formation of coordination bonds with C═O groups in the PEI chains, thereby increasing the HOMO-LUMO gap of 0.5 mCT. This study presents an innovative and effective method for enhancing the capacitance of polymer-based dielectrics in harsh conditions.

References

Less

H. Li, Y. Zhou, Y. Liu, et al., Chem. Soc. Rev. 50 (2021) 6369–6400.

G. Wang, Z. Lu, Y. Li, et al., Chem. Rev. 121 (2021) 6124–6172.

Z. Shang, X. An, S. Nie, et al., J. Bioresour. Bioprod. 8 (2023) 292–305.

Y. Liu, K. Xiang, W. Zhou, et al., Small 20 (2024) 2308741.

S. Zeng, G. Duan, R. Yu, et al., Prog. Mater. Sci. 147 (2025) 101356.

X.Y. Wen, W. Li, H. Chen, et al., Rare Met. 44 (2025) 3881–3892.

H. Zhang, X. Liu, et al., Chin. Chem. Lett. 37 (2026) 110790.

T. Guo, L.B. Tang, W.N. Deng, et al., Rare Met. 44 (2025) 4631–4641.

S. Jiang, J. Fang, H. Liu, et al., Chem. Eng. J. 502 (2024) 157745.

H. Jin, T. Zhang, Z. Tian, et al., J. For. Eng. 9 (2024) 103–109.

X.J. Liu, M.S. Zheng, G. Chen, et al., Energy Environ. Sci. 15 (2022) 56–81.

H. Li, Y. Zhou, Y. Liu, et al., Chem. Soc. Rev. 50 (2021) 6369–6400.

X. Wu, Y. Liu, X. Lin, et al., Surf. Interfaces 28 (2022) 101686.

T. Zhang, Q. Chi, High temperature dielectric materials for electrical energy storage, in: B. Du (Ed.), Polymer Insulation Applied For HVDC Transmission, Springer, 2020, pp. 653–674.

V. Adamec, J.H. Calderwood, J. Phys. D. Appl. Phys. 8 (1975) 551–560.

J. Ho, T.R. Jow, IEEE Trans. Dielectr. Electr. Insul. 19 (2012) 990–995.

Y. Zhu, P. Jiang, Z. Zhang, et al., Chin. Chem. Lett. 28 (2017) 2027–2035.

R. Chen, X. Liu, N. Zhang, et al., Chin. Chem. Lett. 35 (2024) 109194.

Q. Li, L. Chen, M.R. Gadinski, et al., Nature 523 (2015) 576–579.

M. Yang, L. Zhou, X. Li, et al., Adv. Mater. 35 (2023) 2302392.

X. Zhou, Q. Chen, Q.M. Zhang, et al., IEEE Trans. Dielectr. Electr. Insul. 18 (2011) 463–470.

A. Azizi, M.R. Gadinski, Q. Li, et al., Adv. Mater. 29 (2017) 1701864.

J. Dong, R. Hu, X. Xu, et al., Adv. Funct. Mater. 31 (2021) 2102644.

Y. Zhou, Q. Li, B. Dang, et al., Adv. Mater. 30 (2018) 1805672.

D. Ai, H. Li, Y. Zhou, et al., Adv. Energy Mater. 10 (2020) 1903881.

B. Sun, P. Hu, X. Ji, et al., Small 18 (2022) 2202421.

L.Z. Chen, D.D. Huang, Chin. Chem. Lett. 25 (2014) 279–282.

C. Yuan, Y. Zhou, Y. Zhu, et al., Nat. Commun. 11 (2020) 3919.

Y. Zhou, Y. Zhu, W. Xu, et al., Adv. Energy Mater. 13 (2023) 2203961.

B. Zhang, X. ming Chen, Z. Pan, et al., Adv. Funct. Mater. 33 (2022) 2210050.

S. Wang, Z. Luo, J. Liang, et al., ACS Nano 16 (2022) 13612–13656.

J. Li, X. Liu, Y. Feng, et al., Energy Storage Mater. 54 (2023) 605–614.

X. Liu, D. Chen, J. Li, et al., Adv. Mater. 36 (2024) 2402239.

X. Xia, J. Yin, B. Su, et al., Compos. Part B: Eng. 120 (2017) 92–96.

S.E. Neumann, J. Kwon, C. Gropp, et al., Science 383 (2024) 1337–1343.

H. Li, B.S. Chang, H. Kim, et al., Joule 7 (2023) 95–111.

Q. Zhang, X. Chen, B. Zhang, et al., Matter 4 (2021) 2448–2459.

H. Li, D. Ai, L. Ren, et al., Adv. Mater. 31 (2019) 1900875.

Y. Niu, J. Dong, Y. He, et al., Nano Energy 97 (2022) 107215.

J. Song, H. Qin, S. Qin, et al., Mater. Horizon. 10 (2023) 2139–2148.

A.A. Deshmukh, C. Wu, O. Yassin, et al., Energy Environ. Sci. 15 (2022) 1307–1314.

W. Ren, M. Yang, L. Zhou, et al., Adv. Mater. 34 (2022) 2207421.

C. Yuan, Y. Zhou, Y. Zhu, et al., Nat. Commun. 11 (2020) 3919.

J. Dong, L. Li, P. Qiu, et al., Adv. Mater. 35 (2023) 2211487.

M. Yang, L. Zhou, X. Li, et al., Adv. Mater. 35 (2023) 2302392.

M. Yang, Y. Zhao, Z. Wang, et al., Energy Environ. Sci. 17 (2024) 1592–1602.

Appendix

Less

Year 2026 volume 37 Issue 9

PDF

Cite this Article

BibTeX

Article Info

doi: 10.1016/j.cclet.2025.111436

Receive Date：2025-04-27
Online Date：2026-10-27
Published：2026-09-15

Article Data

Affiliations

History

Received：2025-04-27
Revised：2025-06-09
Accepted：2025-06-10

Affiliations

^bSchool of Mechanical and Electrical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China

^cXi'an Herong New Energy Technology Co., Ltd., Xi'an 710021, China

Corresponding:

E-mail addresses: xiaoxuliu@sust.edu.cn (X. Liu)

ansteelmaker@163.com (X. Wang)

References

Share

https://castjournals.cast.org.cn/joweb/ccl/EN/10.1016/j.cclet.2025.111436

Share to

Scan QR to access full text

Cite this article

BibTeX

Citations

表12种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

关闭全屏

BibTeX
EndNote
RefWorks
TxT

Fig.1 Morphological and structural characterization of CT, ZIF-8 and mCT: (a) Schematic diagram of interface layer growth induced by defect engineering. (b) Dark field image and elemental mapping. (c) TEM image. (d) The Porod curves. (e) XRD pattern. (f) FT-IR spectrum. (g) XPS O 1s core-level spectrum. (h) Normalized K-edge XANES absorption spectra of Zn element. (i) K-edge FT-EXAFS in R space. (j) Wavelet transformation analysis.

Fig.2 (a) Gel content in x mCT. XPS of x mCT. (b) C 1s and (c) O 1s core-level spectrum. (d) TEM image and FFT image of 0.5 mCT. (e) Schematic diagram of the interactions between PEI and mCT. (f) DSC curves of x mCT.

Fig.3 (a) Spectral comparison of PEAA and PEAA/0.5 mCT and spatially resolved infrared mapping of PEAA/0.5 mCT. The data is the average value of different region, PEAA is polyether amide acid. (b) Porod curves and (c) ln(q)-ln(I(q)) plots derived from SAXS (Small Angle X-ray Scattering) of x mCT. (d) Normalized K-edge XANES absorption spectra of Zn element. (e) K-edge FT-EXAFS in R space. (f) Wavelet transformation analysis of 0.5 mCT.

Fig.4 (a) Frequency dependence of dielectric constant (ε_r) and tanδ at 25 ℃ of x mCT. (b) The current density of x mCT at 200 ℃. (c) Weibull distribution of measured E_b for x mCT at 25, 150 and 200 ℃. (d) D-E loops of x mCT. (e) Discharge energy density of x mCT. (f) Energy storage performance of different regions in large-scale 0.5 mCT. The insets are the photographs of 0.5 mCT. (g) Cyclic performance of 0.5 mCT at 150 and 200 ℃ under 300 MV/m. (h) Energy storage performance with different electrode diameter at 200 ℃. (i) Comparison of discharged energy density (η > 90%) of this work and other reports at 200 ℃.

Fig.5 (a) Electrostatic potential distribution of Zn-(2-MiM)₄ (ZIF-8 unit), PEI and Zn/(2-MiM)₃-PEI (C═O coordination between mCT and PEI). (b) Lowest unoccupied molecular orbital (LUMO) and highest occupied molecular orbital (HOMO) of Different unit.

Articles: Latest Articles; Most Read; Collections

Updates: Events; News; Multimedia

About: About Us

Contact

No. 86 Xueyuan South Road, Haidian District, Beijing

100081

010-62662699(Operation and Technical Support)

qkjq@cast.org.cn

Copyright © 2025 China Association for Science and Technology. All rights reserved. For all open access content, the relevant licensing terms apply.
Sponsored by the Office of the Leading Group for Cybersecurity and Informatization of CAST, and supported by Science and Technology Review Publishing House