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2. CNOOC (Tianjin) Pipeline Engineering Technology Co., LTD., Binhai 300450, China, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1284794307336975100, articleId=1284794307114676987, tenantId=1146029695717560320, journalId=1283840536528293913, language=CN, title=外加载荷下X65钢腐蚀缺陷处氢分布的数值模拟, columnId=null, journalTitle=太阳能学报, columnName=null, runingTitle=null, highlight=null, articleAbstract=利用有限元方法,将固体力学模型和扩散模型相结合,构建应力诱导氢扩散模型,并研究不同塑性应变条件下含腐蚀缺陷的X65钢的应力、等效塑性应变及氢浓度分布。结果表明,塑性应变显著增加了缺陷区域的应力、等效塑性应变以及氢浓度。塑性应变会使试样整体的von Mises应力升高,而静水应力和等效塑性应变的显著升高则主要集中在腐蚀缺陷的中心区域。在无塑性应变时,氢原子的扩散主要受浓度梯度驱动,从高浓度向低浓度区域均匀扩散;而在施加应变后,氢原子则受到静水应力的驱动,向高应变区域聚集。此外,窄且深的缺陷更易导致氢原子的局部积聚,而缺陷的形状对氢浓度分布的影响相对较小。, authors=靳舒涵1, 刘亮2, 孙东旭1, 刘成威1, 于洋1, 徐铭1, authorsList=靳舒涵, 刘亮, 孙东旭, 刘成威, 于洋, 徐铭, authorCompany=1.辽宁石油化工大学石油天然气工程学院,抚顺 113001;
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[14] GORBAN A N, SARGSYAN H P, WAHAB H A.Quasichemical models of multicomponent nonlinear diffusion[J]. Mathematical modelling of natural phenomena, 2011, 6(5): 184-262.
[15] YANG F Q, ZHAN W J, YAN T, et al.Numerical analysis of the coupling between hydrogen diffusion and mechanical behavior near the crack tip of titanium[J]. Mathematical problems in engineering, 2020, 2020(1): 3618589.
[16] WIJMANS J G, BAKER R W.The solution-diffusion model: a review[J]. Journal of membrane science, 1995, 107(1/2): 1-21.
[17] KROM A H M, KOERS R W J, BAKKER A. Hydrogen transport near a blunting crack tip[J]. Journal of the mechanics and physics of solids, 1999, 47(4): 971-992.
[18] HIRTH J P.Effects of hydrogen on the properties of iron and steel[J]. Metallurgical transactions A, 1980, 11(6): 861-890.
[19] MCLELLAN A G.Non-hydrostatic thermodynamics of chemical systems[J]. Proceedings of the royal society of London a mathematical and physical sciences, 1970, 314(1518): 443-455.
[20] XU L Y, CHENG Y F.Corrosion of X100 pipeline steel under plastic strain in a neutral pH bicarbonate solution[J]. Corrosion science, 2012, 64: 145-152.)
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外加载荷下X65钢腐蚀缺陷处氢分布的数值模拟
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太阳能学报 | 2026,47(6): 594-600
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太阳能学报 2026 , 47 (6) : 594 -600
外加载荷下X65钢腐蚀缺陷处氢分布的数值模拟
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靳舒涵1, 刘亮2, 孙东旭1, 刘成威1, 于洋1, 徐铭1
作者信息
    1.辽宁石油化工大学石油天然气工程学院,抚顺 113001;
    2.中海油(天津)管道工程技术有限公司,滨海 300450
NUMERICAL SIMULATION OF HYDROGEN DISTRIBUTION AT CORROSION DEFECT OF X65 STEEL UNDER APPLIED LOAD
  • Jin Shuhan1, Liu Liang2, Sun Dongxu1, Liu Chengwei1, Yu Yang1, Xu Ming1
  • Affiliations
      1. College of Petroleum and Natural Gas Engineering, Liaoning Petroleum and Chemical University, Fushun 113001, China;
      2. CNOOC (Tianjin) Pipeline Engineering Technology Co., LTD., Binhai 300450, China
    doi: 10.19912/j.0254-0096.tynxb.2025-0131
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    利用有限元方法,将固体力学模型和扩散模型相结合,构建应力诱导氢扩散模型,并研究不同塑性应变条件下含腐蚀缺陷的X65钢的应力、等效塑性应变及氢浓度分布。结果表明,塑性应变显著增加了缺陷区域的应力、等效塑性应变以及氢浓度。塑性应变会使试样整体的von Mises应力升高,而静水应力和等效塑性应变的显著升高则主要集中在腐蚀缺陷的中心区域。在无塑性应变时,氢原子的扩散主要受浓度梯度驱动,从高浓度向低浓度区域均匀扩散;而在施加应变后,氢原子则受到静水应力的驱动,向高应变区域聚集。此外,窄且深的缺陷更易导致氢原子的局部积聚,而缺陷的形状对氢浓度分布的影响相对较小。
    氢能  /  氢脆  /  塑性应变  /  数值模拟  /  X65管道钢  /  腐蚀缺陷  /  氢扩散
    This study establishes a three-dimensional stress-induced hydrogen diffusion model by using finite element analysis and simulates the plastic strain at the defects and its influence on the diffusion and aggregation behaviour of hydrogen atoms under large deformation conditions by using the nonlinear hardening function. The results show that the plastic strain significantly increases the local stress, the equivalent plastic strain, and the hydrogen concentration in the corrosion defect region. Plastic strain increases the overall von Mises stress in the specimen, while the significant increase in hydrostatic stress and equivalent plastic strain is mainly concentrated in the central region of the corrosion defect. In the absence of plastic strain, the diffusion of hydrogen atoms is mainly driven by the concentration gradient, and the flow direction is from the region of high concentration to the region of low concentration, which ultimately leads to a steady state of hydrogen atom concentration inside the specimen. However, when plastic strain exists, the diffusion behaviour of hydrogen atoms is driven by the hydrostatic stress gradient, which is manifested by the aggregation of hydrogen atoms towards the stress concentration region (i.e., at the corrosion defect). In addition, narrow and deep corrosion defects are more likely to lead to local accumulation of hydrogen atoms, while the shape of the defect has relatively little effect on the distribution of hydrogen concentration.
    hydrogen energy  /  hydrogen embrittlement  /  plastic strain  /  numerical simulation  /  X65 pipeline steel  /  corrosion defects  /  hydrogen diffusion
    靳舒涵, 刘亮, 孙东旭, 刘成威, 于洋, 徐铭. 外加载荷下X65钢腐蚀缺陷处氢分布的数值模拟. 太阳能学报, 2026 , 47 (6) : 594 -600 . DOI: 10.19912/j.0254-0096.tynxb.2025-0131
    Jin Shuhan, Liu Liang, Sun Dongxu, Liu Chengwei, Yu Yang, Xu Ming. NUMERICAL SIMULATION OF HYDROGEN DISTRIBUTION AT CORROSION DEFECT OF X65 STEEL UNDER APPLIED LOAD[J]. Acta Energiae Solaris Sinica, 2026 , 47 (6) : 594 -600 . DOI: 10.19912/j.0254-0096.tynxb.2025-0131

      国家自然科学基金青年基金项目(52404058); 辽宁省博士科研启动基金(2023-BS-187); 辽宁省教育厅基本科研项目(LJKMZ20220734)

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    [13] KUMNICK A J, JOHNSON H H.Deep trapping states for hydrogen in deformed iron[J]. Acta metallurgica, 1980, 28(1): 33-39.
    [14] GORBAN A N, SARGSYAN H P, WAHAB H A.Quasichemical models of multicomponent nonlinear diffusion[J]. Mathematical modelling of natural phenomena, 2011, 6(5): 184-262.
    [15] YANG F Q, ZHAN W J, YAN T, et al.Numerical analysis of the coupling between hydrogen diffusion and mechanical behavior near the crack tip of titanium[J]. Mathematical problems in engineering, 2020, 2020(1): 3618589.
    [16] WIJMANS J G, BAKER R W.The solution-diffusion model: a review[J]. Journal of membrane science, 1995, 107(1/2): 1-21.
    [17] KROM A H M, KOERS R W J, BAKKER A. Hydrogen transport near a blunting crack tip[J]. Journal of the mechanics and physics of solids, 1999, 47(4): 971-992.
    [18] HIRTH J P.Effects of hydrogen on the properties of iron and steel[J]. Metallurgical transactions A, 1980, 11(6): 861-890.
    [19] MCLELLAN A G.Non-hydrostatic thermodynamics of chemical systems[J]. Proceedings of the royal society of London a mathematical and physical sciences, 1970, 314(1518): 443-455.
    [20] XU L Y, CHENG Y F.Corrosion of X100 pipeline steel under plastic strain in a neutral pH bicarbonate solution[J]. Corrosion science, 2012, 64: 145-152.
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    doi: 10.19912/j.0254-0096.tynxb.2025-0131
    • 接收时间:2025-01-20
    • 首发时间:2026-07-17
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    2种不同金属材料的力学参数

    Family
    属数
    Number of
    genus
    种数
    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
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