Article(id=1284794267549810965, tenantId=1146029695717560320, journalId=1283840536528293913, issueId=1284794217658560734, articleNumber=null, orderNo=null, doi=10.19912/j.0254-0096.tynxb.2025-0157, pmid=null, cstr=null, oa=null, hot=0, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1737561600000, receivedDateStr=2025-01-23, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1784248423706, onlineDateStr=2026-07-17, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1784248423706, onlineIssueDateStr=2026-07-17, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1784248423706, creator=13701087609, updateTime=1784248423706, updator=13701087609, issue=Issue{id=1284794217658560734, tenantId=1146029695717560320, journalId=1283840536528293913, year='2026', volume='47', issue='6', pageStart='1', pageEnd='814', issueExtLink='null', onlineDate='null', pubDate='1783180800000', pubDateStr='2026-07-05', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1784248411812, creator='13701087609', updateTime=1784252840208, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1284812791785689442, tenantId=1146029695717560320, journalId=1283840536528293913, issueId=1284794217658560734, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1284812791785689443, tenantId=1146029695717560320, journalId=1283840536528293913, issueId=1284794217658560734, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=601, endPage=606, ext={EN=ArticleExt(id=1284794267881160983, articleId=1284794267549810965, tenantId=1146029695717560320, journalId=1283840536528293913, language=EN, title=KINETIC AND THERMODYNAMIC ANALYSIS OF NH4+ AND K+ IN TAILING LIQUID OF ZEOLITE ADSORPTION HYDROGEN PRODUCTION, columnId=null, journalTitle=Acta Energiae Solaris Sinica, columnName=null, runingTitle=null, highlight=null, articleAbstract=In order to achieve the recycling of nutrients in photo-fermentation hydrogen production tailing liquid, the adsorption capacity of zeolite on NH4+ and K+ in photo-fermentation hydrogen production tailing liquid was investigated using natural zeolite as adsorbent and kinetic and thermodynamic analyses were carried out. It is found that the adsorption of zeolite on NH4+ and K+ in photo-fermentation hydrogen production tailing liquid exhibites a tendency of accelerated adsorption, then gradually reaches balance, which is attained at 2 h and 3 h of adsorption, respectively. When adsorption time is 2h and adsorption temperature is 35 ℃, zeolite demonstrates stronger adsorption capacity for NH4+ with an adsorption of 1.82 mg/g. When adsorption time is 3 h and adsorption temperature is 45 ℃, zeolite exhibites its maximum adsorption capacity for K+, reaching 7.11 mg/g. The quasi-secondary kinetic model provides a superior description for the adsorption process. The adsorption process of zeolite on NH4+ and K+ in the tailing liquid of photo-fermentation hydrogen production is non-spontaneous. The adsorption of NH4+ by zeolite is characterised as an exothermic entropy reduction reaction, while the adsorption of K+ is identified as an adsorptive entropy increase reaction., authors=Zhou Xiaokai, Zhang Kai, Jing Yanyan, Zhang Quanguo, Lu Chaoyang, authorsList=Zhou Xiaokai, Zhang Kai, Jing Yanyan, Zhang Quanguo, Lu Chaoyang, authorCompany=Key Laboratory of New Materials and Equipment for Renewable Energy, Ministry of Agriculture and Rural Affairs, Henan Agricultural University, Zhengzhou 450002, China, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1284794267801469206, articleId=1284794267549810965, tenantId=1146029695717560320, journalId=1283840536528293913, language=CN, title=沸石吸附制氢尾液中NH4+和K+的动力学与热力学分析, columnId=null, journalTitle=太阳能学报, columnName=null, runingTitle=null, highlight=null, articleAbstract=为实现光发酵制氢尾液营养物质的回收利用,以天然沸石为吸附材料,采用动力学和热力学分析方法,研究沸石吸附光发酵制氢尾液中NH4+和K+的能力。研究发现,在吸附时间和温度分别为2 h、35 ℃时,沸石对NH4+的吸附能力较强,吸附量为1.82 mg/g;当吸附时间为3 h、温度为45 ℃时,K+在沸石上的吸附最佳,为7.11 mg/g。准二级动力学更适合描述NH4+和K+在沸石上的吸附,且K+在沸石上的吸附是非自发的吸热熵增反应,而NH4+的吸附是非自发的放热熵减反应。, authors=周小楷, 张凯, 荆艳艳, 张全国, 路朝阳, authorsList=周小楷, 张凯, 荆艳艳, 张全国, 路朝阳, authorCompany=河南农业大学农业农村部可再生能源新材料与装备重点实验室,郑州 450002, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=22453jg0Gro6Cwr6Vs8N2A==, pdfFileSize=1388034, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, 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PENG Q C, LIU X H, LUO P Y, et al.Adsorption and desorption characteristics of nitrogen, phosphorus and potassium by biochars from different raw materials[J]. Journal of plant nutrition and fertilizers, 2019, 25(10): 1763-1772. [11] 刘成, 兰童, 陈卫. 水厂生物活性炭失效判定的几个关键问题及建议[J]. 净水技术, 2022, 41(12): 1-8, 158. LIU C, LAN T, CHEN W.Key factors and suggestion on failure judgement for spent BAC in WTP[J]. Water purification technology, 2022, 41(12): 1-8, 158. [12] 臧金秋, 杨传玺, 王小宁, 等. 生物炭吸附水中污染物的性能、机理和环境风险[J]. 工业水处理, 2023, 43(12): 1-13. ZANG J Q, YANG C X, WANG X N, et al.Performance, mechanism and environmental risk on adsorption removal of pollutants in water using biochar[J]. Industrial water treatment, 2023, 43(12): 1-13. [13] WU K, LI Y, LIU T, et al.Evaluation of the adsorption of ammonium-nitrogen and phosphate on a granular composite adsorbent derived from zeolite[J]. Environmental science and pollution research, 2019, 26(17): 17632-17643. [14] 杨延梅, 吕远洋, 陈可, 等. 天然斜发沸石和人粪生物炭吸附回收黄水中氮磷[J]. 工业水处理, 2025, 45(8): 104-112. YANG Y M, LYU Y Y, CHEN K, et al.Adsorption and recovery of nitrogen and phosphorus in yellow water by natural clinoptilolite and human manure biochar[J]. Industrial water treatment, 2025, 45(8): 104-112. [15] ENGLERT A H, RUBIO J.Characterization and environmental application of a Chilean natural zeolite[J]. International journal of mineral processing, 2005, 75(1/2): 21-29. [16] 鲍慧敏. 粉煤灰基沸石吸附废液中氨氮化物与铜离子的试验研究[J]. 矿冶工程, 2024, 44(4): 253-258. BAO H M.Experimental study on adsorption of ammonia nitride and copper ions in wastewater by fly ash-based zeolite[J]. Mining and metallurgical engineering, 2024, 44(4): 253-258. [17] 王建辉, 朱星宇, 李广, 等. 改性天然斜发沸石去除氨氮的工艺[J]. 长春工程学院学报(自然科学版), 2024, 25(3): 96-104. WANG J H, ZHU X Y, LI G, et al.Technology for removing ammonia nitrogen by modified natural clinoptilolite[J]. Journal of Changchun Institute of Technology (natural sciences edition), 2024, 25(3): 96-104. [18] 程国斌, 韩梅, 王刃, 等. NH4+型斜发沸石吸附钾离子[J]. 应用化学, 2005, 22(10): 1092-1095. CHENG G B, HAN M, WANG R, et al.Adsorption of potassium on NH4+-pretreated clinoptilolite[J]. Chinese journal of applied chemistry, 2005, 22(10): 1092-1095. [19] MITROGIANNIS D, PSYCHOGIOU M, MANTHOS G, et al.Phosphorus and potassium recovery from anaerobically digested olive mill wastewater using modified zeolite, fly ash and zeolitic fly ash: a comparative study[J]. Journal of chemical technology & biotechnology, 2022, 97(7): 1860-1873. [20] ZHOU X K, LI F, LI C J, et al.Effect of deep eutectic solvent pretreatment on biohydrogen production from corncob: pretreatment temperature and duration[J]. Bioengineered, 2023, 14(1): 2252218. [21] 胡启立, 何智浩, 张帅, 等. 吸附动力学模型拟合优度的统计评估及模型比较研究[J]. 水处理技术, 2025, 51(3): 23-30. HU Q L, HE Z H, ZHANG S, et al.Statistical evaluation of adsorption kinetic models: goodness of fit and model comparison[J]. Technology of water treatment, 2025, 51(3): 23-30. [22] YANG W L, LU C Y, LIANG B, et al.Removal of Pb(Ⅱ) from aqueous solution and adsorption kinetics of corn stalk biochar[J]. Separations, 2023, 10(8): 140894. [23] WAN C L, DING S, ZHANG C, et al.Simultaneous recovery of nitrogen and phosphorus from sludge fermentation liquid by zeolite adsorption: mechanism and application[J]. Separation and purification technology, 2017, 180: 1-12. [24] 周传庭, 安莹, 羌佳鑫, 等. 盐改性方法对沸石吸附氨氮性能的影响[J]. 净水技术, 2024, 43(9): 80-86. ZHOU C T, AN Y, QIANG J X, et al.Effect of salt modification method on performance of ammonia nitrogen adsorption by zeolite[J]. Water purification technology, 2024, 43(9): 80-86. [25] 刘丽芳, 林子厚, 杨克敏, 等. 改性沸石滤料吸附氨氮性能研究[J]. 给水排水, 2022, 58(S1): 679-686. LIU L F, LIN Z H, YANG K M, et al.Experimental study on adsorption of ammonia nitrogen by modified zeolite filter material[J]. Water & wastewater engineering, 2022, 58(S1): 679-686. [26] 石勤, 黄雪莉. 钡十字沸石吸附K+的热力学模拟及动力学实验[J]. 无机盐工业, 2016, 48(11): 12-16. SHI Q, HUANG X L.Thermodynamic simulation and kinetics experiment of K+ adsorption by merlinoite[J]. Inorganic chemicals industry, 2016, 48(11): 12-16. [27] ZHANG H, YU X J, CHEN L, et al.Study of 63Ni adsorption on NKF-6 zeolite[J]. Journal of environmental radioactivity, 2010, 101(12): 1061-1069. [28] KIM J R, HULING S G, KAN E.Effects of temperature on adsorption and oxidative degradation of bisphenol A in an acid-treated iron-amended granular activated carbon[J]. Chemical engineering journal, 2015, 262: 1260-1267. [29] 邢赜. 沼液营养物的沸石吸附回收与利用[D]. 重庆: 西南大学, 2013. XING Z.Adsorption and its utilization of nutrient from biogas slurry by zeolite[D]. Chongqing: Southwest University, 2013. [30] 李佳. 改性沸石对水中氮磷和菲吸附作用及对底泥中氮磷固定作用研究[D]. 上海: 上海海洋大学, 2014. LI J.Study on adsorption of phosphate, ammonium and phenanthrene from aqueous solution and immobilization of phosphate and ammonium in sediment by modified zeolite[D]. Shanghai: Shanghai Ocean University, 2014.)
沸石吸附制氢尾液中NH4+和K+的动力学与热力学分析
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太阳能学报
| 2026,47(6): 601-606
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太阳能学报
2026
, 47
(6) :
601
-606
沸石吸附制氢尾液中NH4+和K+的动力学与热力学分析
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周小楷, 张凯, 荆艳艳, 张全国, 路朝阳
作者信息
河南农业大学农业农村部可再生能源新材料与装备重点实验室,郑州 450002
KINETIC AND THERMODYNAMIC ANALYSIS OF NH4+ AND K+ IN TAILING LIQUID OF ZEOLITE ADSORPTION HYDROGEN PRODUCTION
Zhou Xiaokai, Zhang Kai, Jing Yanyan, Zhang Quanguo, Lu Chaoyang
Affiliations
Key Laboratory of New Materials and Equipment for Renewable Energy, Ministry of Agriculture and Rural Affairs, Henan Agricultural University, Zhengzhou 450002, China
In order to achieve the recycling of nutrients in photo-fermentation hydrogen production tailing liquid, the adsorption capacity of zeolite on NH4+ and K+ in photo-fermentation hydrogen production tailing liquid was investigated using natural zeolite as adsorbent and kinetic and thermodynamic analyses were carried out. It is found that the adsorption of zeolite on NH4+ and K+ in photo-fermentation hydrogen production tailing liquid exhibites a tendency of accelerated adsorption, then gradually reaches balance, which is attained at 2 h and 3 h of adsorption, respectively. When adsorption time is 2h and adsorption temperature is 35 ℃, zeolite demonstrates stronger adsorption capacity for NH4+ with an adsorption of 1.82 mg/g. When adsorption time is 3 h and adsorption temperature is 45 ℃, zeolite exhibites its maximum adsorption capacity for K+, reaching 7.11 mg/g. The quasi-secondary kinetic model provides a superior description for the adsorption process. The adsorption process of zeolite on NH4+ and K+ in the tailing liquid of photo-fermentation hydrogen production is non-spontaneous. The adsorption of NH4+ by zeolite is characterised as an exothermic entropy reduction reaction, while the adsorption of K+ is identified as an adsorptive entropy increase reaction.
Zhou Xiaokai, Zhang Kai, Jing Yanyan, Zhang Quanguo, Lu Chaoyang.
KINETIC AND THERMODYNAMIC ANALYSIS OF NH4+ AND K+ IN TAILING LIQUID OF ZEOLITE ADSORPTION HYDROGEN PRODUCTION[J].
Acta Energiae Solaris Sinica,
2026
, 47
(6)
: 601
-606
.
DOI: 10.19912/j.0254-0096.tynxb.2025-0157
基金
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国家重点研发计划（2018YFE0206600）
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Environmental science and pollution research, 2019, 26(17): 17632-17643. [14] 杨延梅, 吕远洋, 陈可, 等. 天然斜发沸石和人粪生物炭吸附回收黄水中氮磷[J]. 工业水处理, 2025, 45(8): 104-112. YANG Y M, LYU Y Y, CHEN K, et al.Adsorption and recovery of nitrogen and phosphorus in yellow water by natural clinoptilolite and human manure biochar[J]. Industrial water treatment, 2025, 45(8): 104-112. [15] ENGLERT A H, RUBIO J.Characterization and environmental application of a Chilean natural zeolite[J]. International journal of mineral processing, 2005, 75(1/2): 21-29. [16] 鲍慧敏. 粉煤灰基沸石吸附废液中氨氮化物与铜离子的试验研究[J]. 矿冶工程, 2024, 44(4): 253-258. BAO H M.Experimental study on adsorption of ammonia nitride and copper ions in wastewater by fly ash-based zeolite[J]. Mining and metallurgical engineering, 2024, 44(4): 253-258. [17] 王建辉, 朱星宇, 李广, 等. 改性天然斜发沸石去除氨氮的工艺[J]. 长春工程学院学报(自然科学版), 2024, 25(3): 96-104. WANG J H, ZHU X Y, LI G, et al.Technology for removing ammonia nitrogen by modified natural clinoptilolite[J]. Journal of Changchun Institute of Technology (natural sciences edition), 2024, 25(3): 96-104. [18] 程国斌, 韩梅, 王刃, 等. NH4+型斜发沸石吸附钾离子[J]. 应用化学, 2005, 22(10): 1092-1095. CHENG G B, HAN M, WANG R, et al.Adsorption of potassium on NH4+-pretreated clinoptilolite[J]. Chinese journal of applied chemistry, 2005, 22(10): 1092-1095. [19] MITROGIANNIS D, PSYCHOGIOU M, MANTHOS G, et al.Phosphorus and potassium recovery from anaerobically digested olive mill wastewater using modified zeolite, fly ash and zeolitic fly ash: a comparative study[J]. Journal of chemical technology & biotechnology, 2022, 97(7): 1860-1873. [20] ZHOU X K, LI F, LI C J, et al.Effect of deep eutectic solvent pretreatment on biohydrogen production from corncob: pretreatment temperature and duration[J]. Bioengineered, 2023, 14(1): 2252218. [21] 胡启立, 何智浩, 张帅, 等. 吸附动力学模型拟合优度的统计评估及模型比较研究[J]. 水处理技术, 2025, 51(3): 23-30. HU Q L, HE Z H, ZHANG S, et al.Statistical evaluation of adsorption kinetic models: goodness of fit and model comparison[J]. Technology of water treatment, 2025, 51(3): 23-30. [22] YANG W L, LU C Y, LIANG B, et al.Removal of Pb(Ⅱ) from aqueous solution and adsorption kinetics of corn stalk biochar[J]. Separations, 2023, 10(8): 140894. [23] WAN C L, DING S, ZHANG C, et al.Simultaneous recovery of nitrogen and phosphorus from sludge fermentation liquid by zeolite adsorption: mechanism and application[J]. Separation and purification technology, 2017, 180: 1-12. [24] 周传庭, 安莹, 羌佳鑫, 等. 盐改性方法对沸石吸附氨氮性能的影响[J]. 净水技术, 2024, 43(9): 80-86. ZHOU C T, AN Y, QIANG J X, et al.Effect of salt modification method on performance of ammonia nitrogen adsorption by zeolite[J]. Water purification technology, 2024, 43(9): 80-86. [25] 刘丽芳, 林子厚, 杨克敏, 等. 改性沸石滤料吸附氨氮性能研究[J]. 给水排水, 2022, 58(S1): 679-686. LIU L F, LIN Z H, YANG K M, et al.Experimental study on adsorption of ammonia nitrogen by modified zeolite filter material[J]. Water & wastewater engineering, 2022, 58(S1): 679-686. [26] 石勤, 黄雪莉. 钡十字沸石吸附K+的热力学模拟及动力学实验[J]. 无机盐工业, 2016, 48(11): 12-16. SHI Q, HUANG X L.Thermodynamic simulation and kinetics experiment of K+ adsorption by merlinoite[J]. Inorganic chemicals industry, 2016, 48(11): 12-16. [27] ZHANG H, YU X J, CHEN L, et al.Study of 63Ni adsorption on NKF-6 zeolite[J]. Journal of environmental radioactivity, 2010, 101(12): 1061-1069. [28] KIM J R, HULING S G, KAN E.Effects of temperature on adsorption and oxidative degradation of bisphenol A in an acid-treated iron-amended granular activated carbon[J]. Chemical engineering journal, 2015, 262: 1260-1267. [29] 邢赜. 沼液营养物的沸石吸附回收与利用[D]. 重庆: 西南大学, 2013. XING Z.Adsorption and its utilization of nutrient from biogas slurry by zeolite[D]. Chongqing: Southwest University, 2013. [30] 李佳. 改性沸石对水中氮磷和菲吸附作用及对底泥中氮磷固定作用研究[D]. 上海: 上海海洋大学, 2014. LI J.Study on adsorption of phosphate, ammonium and phenanthrene from aqueous solution and immobilization of phosphate and ammonium in sediment by modified zeolite[D]. Shanghai: Shanghai Ocean University, 2014.
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