Article(id=1314908301754725032, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.04.022, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1771084800000, receivedDateStr=2026-02-15, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428168952, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428168952, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428168952, creator=13701087609, updateTime=1791428168952, updator=13701087609, issue=Issue{id=1314908074188562588, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='4', pageStart='1', pageEnd='266', issueExtLink='null', onlineDate='null', pubDate='1785513600000', pubDateStr='2026-08-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1791428114697, creator='13701087609', updateTime=1791430419337, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314917740654191268, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314917740654191269, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=145, endPage=149, ext={EN=ArticleExt(id=1314908303579247273, articleId=1314908301754725032, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Synthesis of 4-(Chloromethyl) Benzohydroxamic Acid and Its Flotation Performance for Wolframite, columnId=1236276106932842717, journalTitle=Mining and Metallurgical Engineering, columnName=MINERAL PROCESSING, runingTitle=null, highlight=null, articleAbstract=
Conventional hydroxamic acid collectors suffer from weak collecting capacity and high dosage consumption. To address these drawbacks, 4-(chloromethyl) benzohydroxamic acid was synthesized, and its flotation performance for wolframite was systematically investigated. With methyl 4-(chloromethyl) benzoate, hydroxylamine hydrochloride and sodium hydroxide as raw materials, the optimal synthesis conditions were determined as follows:methyl 4-(chloromethyl) benzoate, hydroxylamine hydrochloride and sodium hydroxide in a molar ratio of 1∶1.2∶ 2.35, reaction temperature of 35 ℃, reaction time of 4 h, and pH of 5 at the terminal acidification. Tests on flotation of wolframite indicate that 4-(chloromethyl) benzohydroxamic acid outperforms benzohydroxamic acid in collecting ability. To achieve equivalent flotation indices, the required dosage of the synthesized reagent is lower than that of benzohydroxamic acid.
, authors=Lei HAN
1, 2, 3, Yunbo LUO
1, 2, 3, 4, Ruipeng CHEN
1, 2, 3, Faming ZHANG
1, 2, 3, Zhenxuan XIE
1, authorsList=Lei HAN, Yunbo LUO, Ruipeng CHEN, Faming ZHANG, Zhenxuan XIE, authorCompany=null, correspAuthors=Yunbo LUO, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314908304233558698, articleId=1314908301754725032, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=对氯甲基苯甲羟肟酸的合成及其对黑钨矿的浮选性能, columnId=1236276107125780707, journalTitle=矿冶工程杂志, columnName=选矿, runingTitle=null, highlight=null, articleAbstract=
针对现有羟肟酸类捕收剂捕收能力不足、用量大等问题,合成了对氯甲基苯甲羟肟酸,并考察了其对黑钨矿的浮选性能。以对氯甲基苯甲酸甲酯、盐酸羟胺、氢氧化钠为原料,合成对氯甲基苯甲羟肟酸的适宜条件为:对氯甲基苯甲酸甲酯、盐酸羟胺、氢氧化钠物质的量比1∶1.2∶2.35,反应温度35 ℃,反应时间4 h,酸化终点pH值为5。黑钨矿浮选试验结果表明,对氯甲基苯甲羟肟酸对黑钨矿的浮选性能优于苯甲羟肟酸,在浮选指标相当的情况下,对氯甲基苯甲羟肟酸比苯甲羟肟酸用量更低。
, authors=韩雷
1, 2, 3, 罗云波
1, 2, 3, 4, 陈锐鹏
1, 2, 3, 张发明
1, 2, 3, 谢臻璇
1, authorsList=韩雷, 罗云波, 陈锐鹏, 张发明, 谢臻璇, authorCompany=null, correspAuthors=罗云波, authorNote=
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1.Guangzhou Yueyouyan Mineral Resources Technology Co., Ltd., Guangzhou 510650, Guangdong, China
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1.广州粤有研矿物资源科技有限公司,广东 广州 510650
2.广东省科学院资源利用与稀土开发研究所,广东 广州 510650
3.稀有金属分离与综合利用国家重点实验室,广东 广州 510650, bio={"content":"
韩雷(1987—),男,安徽亳州人,硕士,工程师,主要从事选矿药剂与工艺开发工作。E-mail: 489449170@qq.com
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韩雷(1987—),男,安徽亳州人,硕士,工程师,主要从事选矿药剂与工艺开发工作。E-mail: 489449170@qq.com
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1.Guangzhou Yueyouyan Mineral Resources Technology Co., Ltd., Guangzhou 510650, Guangdong, China
2.Guangdong Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences, Guangzhou 510650, Guangdong, China
3.State Key Laboratory of Rare Metals Separation and Comprehensive Utilization, Guangzhou 510650, Guangdong, China
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1, 2, 3, 4, address=
1.广州粤有研矿物资源科技有限公司,广东 广州 510650
2.广东省科学院资源利用与稀土开发研究所,广东 广州 510650
3.稀有金属分离与综合利用国家重点实验室,广东 广州 510650
4.郑州大学 化工学院,河南 郑州 450001, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1314908305059836588, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1314908301754725032, xref=1., ext=[AuthorCompanyExt(id=1314908305068225197, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1314908301754725032, companyId=1314908305059836588, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
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1, 2, 3, address=
1.Guangzhou Yueyouyan Mineral Resources Technology Co., Ltd., Guangzhou 510650, Guangdong, China
2.Guangdong Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences, Guangzhou 510650, Guangdong, China
3.State Key Laboratory of Rare Metals Separation and Comprehensive Utilization, Guangzhou 510650, Guangdong, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1314908310613095118, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1314908301754725032, authorId=1314908310181081801, language=CN, stringName=陈锐鹏, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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2.广东省科学院资源利用与稀土开发研究所,广东 广州 510650
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1, 2, 3, address=
1.Guangzhou Yueyouyan Mineral Resources Technology Co., Ltd., Guangzhou 510650, Guangdong, China
2.Guangdong Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences, Guangzhou 510650, Guangdong, China
3.State Key Laboratory of Rare Metals Separation and Comprehensive Utilization, Guangzhou 510650, Guangdong, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1314908313016431319, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1314908301754725032, authorId=1314908310944445136, language=CN, stringName=张发明, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
1, 2, 3, address=
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