Article(id=1314908209442292330, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.04.034, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1769702400000, receivedDateStr=2026-01-30, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428146944, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428146944, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428146944, creator=13701087609, updateTime=1791428146944, updator=13701087609, issue=Issue{id=1314908074188562588, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='4', pageStart='1', pageEnd='266', issueExtLink='null', onlineDate='null', pubDate='1785513600000', pubDateStr='2026-08-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1791428114697, creator='13701087609', updateTime=1791430419337, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314917740654191268, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314917740654191269, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=222, endPage=225, ext={EN=ArticleExt(id=1314908209878499947, articleId=1314908209442292330, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Influence of Element Stoichiometry and Sintering Temperature on Lithium-Ion Conductivity of Sulfide Solid Electrolyte Li6-xPS5-xCl1+x, columnId=1236276108207902848, journalTitle=Mining and Metallurgical Engineering, columnName=MATERIALS, runingTitle=null, highlight=null, articleAbstract=

Sulfide solid electrolyte Li6-xPS5-xCl1+x samples were prepared under varied combinations of element stoichiometry and sintering temperature. Performance characterizations were conducted to investigate the effects of processing parameters on ionic conductivity. The results reveal that the optimal parameter combination corresponds to the electrolyte with the chemical formula Li5.35 PS4.35 Cl1.65, being sintered at 500 ℃. This electrolyte delivers a lithium-ion conductivity of 11.05 mS/cm after cold pressing at 26 ℃. For electrolytes with identical stoichiometry, the lithium-ion conductivity of electrolyte increases first and then decreases as sintering temperature rises. Under the optimal sintering temperature, the lithium-ion conductivity of electrolyte exhibits an upward trend followed by a downward trend with the increase of halogen stoichiometric coefficient (1+x).

, authors=Jiaqiang ZHANG, Zexiao MAO, Hong LIAO, Gang LEI, Bowei JU, authorsList=Jiaqiang ZHANG, Zexiao MAO, Hong LIAO, Gang LEI, Bowei JU, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314908210306318956, articleId=1314908209442292330, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=元素配比与烧结温度对硫化物固态电解质Li6-xPS5-xCl1+x锂离子电导率的影响, columnId=1236276110049202322, journalTitle=矿冶工程杂志, columnName=材料, runingTitle=null, highlight=null, articleAbstract=

使用不同元素配比与烧结温度组合,得到不同参数组合下的硫化物固态电解质Li6-xPS5-xCl1+x样品,并对其进行性能表征,厘清工艺参数对电导率的影响规律。结果表明,最佳的工艺参数组合为:电解质化学式Li5.35PS4.35Cl1.65、烧结温度500 ℃,该电解质在26 ℃下冷压,锂离子电导率达到11.05 mS/cm。同一化学式电解质的锂离子电导率随着烧结温度升高先升高后降低;最佳烧结温度条件下电解质的锂离子电导率随着卤素原子配比1+x增大先升高后降低。

, authors=张嘉强, 毛泽潇, 廖红, 雷刚, 鞠博伟, authorsList=张嘉强, 毛泽潇, 廖红, 雷刚, 鞠博伟, authorCompany=null, correspAuthors=null, authorNote=

张嘉强(1998—),男,广东广州人,硕士,主要研究方向为固态电解质材料。E-mail:

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张嘉强(1998—),男,广东广州人,硕士,主要研究方向为固态电解质材料。E-mail:

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元素配比与烧结温度对硫化物固态电解质Li6-xPS5-xCl1+x锂离子电导率的影响
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张嘉强 , 毛泽潇 , 廖红 , 雷刚 , 鞠博伟
矿冶工程杂志 | 材料 2026,46(4): 222-225
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矿冶工程杂志 |材料 2026 , 46 (4) : 222 -225
元素配比与烧结温度对硫化物固态电解质Li6-xPS5-xCl1+x锂离子电导率的影响
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张嘉强 , 毛泽潇, 廖红, 雷刚, 鞠博伟
作者信息
  • 长沙矿冶研究院有限责任公司,湖南 长沙 410012
作者简介:

张嘉强(1998—),男,广东广州人,硕士,主要研究方向为固态电解质材料。E-mail:

Influence of Element Stoichiometry and Sintering Temperature on Lithium-Ion Conductivity of Sulfide Solid Electrolyte Li6-xPS5-xCl1+x
Jiaqiang ZHANG , Zexiao MAO, Hong LIAO, Gang LEI, Bowei JU
Affiliations
  • Changsha Research Institute of Mining and Metallurgy Co., Ltd., Changsha 410012, Hunan, China
doi: 10.3969/j.issn.0253-6099.2026.04.034
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使用不同元素配比与烧结温度组合,得到不同参数组合下的硫化物固态电解质Li6-xPS5-xCl1+x样品,并对其进行性能表征,厘清工艺参数对电导率的影响规律。结果表明,最佳的工艺参数组合为:电解质化学式Li5.35PS4.35Cl1.65、烧结温度500 ℃,该电解质在26 ℃下冷压,锂离子电导率达到11.05 mS/cm。同一化学式电解质的锂离子电导率随着烧结温度升高先升高后降低;最佳烧结温度条件下电解质的锂离子电导率随着卤素原子配比1+x增大先升高后降低。

全固态电池  /  Li6-xPS5-xCl1+x  /  硫化物固态电解质  /  离子电导率  /  烧结温度  /  元素配比

Sulfide solid electrolyte Li6-xPS5-xCl1+x samples were prepared under varied combinations of element stoichiometry and sintering temperature. Performance characterizations were conducted to investigate the effects of processing parameters on ionic conductivity. The results reveal that the optimal parameter combination corresponds to the electrolyte with the chemical formula Li5.35 PS4.35 Cl1.65, being sintered at 500 ℃. This electrolyte delivers a lithium-ion conductivity of 11.05 mS/cm after cold pressing at 26 ℃. For electrolytes with identical stoichiometry, the lithium-ion conductivity of electrolyte increases first and then decreases as sintering temperature rises. Under the optimal sintering temperature, the lithium-ion conductivity of electrolyte exhibits an upward trend followed by a downward trend with the increase of halogen stoichiometric coefficient (1+x).

all-solid-state battery  /  Li6-xPS5-xCl1+x  /  sulfide solid electrolyte  /  ionic conductivity  /  sintering temperature  /  element stoichiometry
张嘉强, 毛泽潇, 廖红, 雷刚, 鞠博伟. 元素配比与烧结温度对硫化物固态电解质Li6-xPS5-xCl1+x锂离子电导率的影响. 矿冶工程杂志, 2026 , 46 (4) : 222 -225 . DOI: 10.3969/j.issn.0253-6099.2026.04.034
Jiaqiang ZHANG, Zexiao MAO, Hong LIAO, Gang LEI, Bowei JU. Influence of Element Stoichiometry and Sintering Temperature on Lithium-Ion Conductivity of Sulfide Solid Electrolyte Li6-xPS5-xCl1+x[J]. Mining and Metallurgical Engineering, 2026 , 46 (4) : 222 -225 . DOI: 10.3969/j.issn.0253-6099.2026.04.034
  • 中国五矿集团科创基金项目(24-C6CL001)
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doi: 10.3969/j.issn.0253-6099.2026.04.034
  • 接收时间:2026-01-30
  • 首发时间:2026-10-08
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  • 收稿日期:2026-01-30
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中国五矿集团科创基金项目(24-C6CL001)
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    长沙矿冶研究院有限责任公司,湖南 长沙 410012
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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