Article(id=1314908112755192422, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907935172551117, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.03.031, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1764518400000, receivedDateStr=2025-12-01, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428123892, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428123892, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428123892, creator=13701087609, updateTime=1791428123892, updator=13701087609, issue=Issue{id=1314907935172551117, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='3', pageStart='1', pageEnd='297', issueExtLink='null', onlineDate='null', pubDate='1780243200000', pubDateStr='2026-06-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791428081553, creator='13701087609', updateTime=1791430444568, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314917846770082179, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907935172551117, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314917846770082180, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907935172551117, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=210, endPage=213, ext={EN=ArticleExt(id=1314908114260947559, articleId=1314908112755192422, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Tartaric Acid Leaching of Spent Lithium Iron Phosphate Batteries, columnId=1236276106727321817, journalTitle=Mining and Metallurgical Engineering, columnName=METALLURGY, runingTitle=null, highlight=null, articleAbstract=

With cathode powder of spent lithium iron phosphate batteries as raw materials, selective lithium leaching was conducted in a tartaric acid - hydrogen peroxide system. The results indicate that stirring speed and liquid-solid ratio bring slight impact to the leaching rates of lithium and iron, while mass concentration of tartaric acid, leaching temperature and leaching time present remarkable influences. And hydrogen peroxide concentration mainly governs the iron leaching rate. Under the following optimal conditions, including mass concentration of tartaric acid of 150 g/L, stirring speed of 500 r/min, liquid-solid ratio of 6, leaching duration of 3 h, hydrogen peroxide concentration of 3 mol/L and leaching temperature of 70 ℃, the leaching rates of lithium and iron are 98.7% and 4.5% respectively. After the processes of evaporation, concentration and purification, the lithium leachate is subjected to carbonate lithium precipitation, yielding a lithium carbonate product with favorable crystallinity.

, authors=Zhanxin WU, Wubin LI, Yong LI, Zhitong HU, Fajie QIN, authorsList=Zhanxin WU, Wubin LI, Yong LI, Zhitong HU, Fajie QIN, authorCompany=null, correspAuthors=Wubin LI, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314908114604880488, articleId=1314908112755192422, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=废旧磷酸铁锂电池酒石酸浸出研究, columnId=1236276107322913000, journalTitle=矿冶工程杂志, columnName=冶金, runingTitle=null, highlight=null, articleAbstract=

以废旧磷酸铁锂电池正极粉末为原料,采用酒石酸+过氧化氢体系开展锂的选择性浸出研究。结果表明,搅拌速率与液固比对Li、Fe浸出率影响较小,酒石酸质量浓度、浸出温度、浸出时间对Li、Fe浸出率影响显著,过氧化氢浓度主要影响Fe浸出率。确定的优化工艺条件为:酒石酸质量浓度150 g/L、搅拌速率500 r/min、液固比6、浸出时间3 h、过氧化氢浓度3 mol/L、浸出温度70 ℃,该条件下Li、Fe浸出率分别为98.7%、4.5%。锂浸出液经蒸发浓缩、净化处理后,采用碳酸盐沉锂工艺可制得结晶度较好的碳酸锂产品。

, authors=吴占新, 李武斌, 李勇, 胡志同, 覃发玠, authorsList=吴占新, 李武斌, 李勇, 胡志同, 覃发玠, authorCompany=null, correspAuthors=李武斌, authorNote=

吴占新(1997—),男,内蒙古赤峰人,硕士,工程师,主要研究方向为锰冶金及电极材料研发。E-mail:

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李武斌(1984—),男,内蒙古卓资人,硕士,正高级工程师,主要研究方向为湿法冶金。E-mail:
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吴占新(1997—),男,内蒙古赤峰人,硕士,工程师,主要研究方向为锰冶金及电极材料研发。E-mail:

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吴占新(1997—),男,内蒙古赤峰人,硕士,工程师,主要研究方向为锰冶金及电极材料研发。E-mail:

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废旧磷酸铁锂电池酒石酸浸出研究
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吴占新 , 李武斌 , 李勇 , 胡志同 , 覃发玠
矿冶工程杂志 | 冶金 2026,46(3): 210-213
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矿冶工程杂志 |冶金 2026 , 46 (3) : 210 -213
废旧磷酸铁锂电池酒石酸浸出研究
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吴占新(1997—),男,内蒙古赤峰人,硕士,工程师,主要研究方向为锰冶金及电极材料研发。E-mail:

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country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=Guizhou New Materials Research and Development Base, Guiyang 550014, Guizhou, China), AuthorCompanyExt(id=1314908114835567212, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1314908112755192422, companyId=1314908114818789994, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=贵州省新材料研究开发基地,贵州 贵阳 550014)])])]
吴占新 , 李武斌 , 李勇, 胡志同, 覃发玠
作者信息
  • 贵州省新材料研究开发基地,贵州 贵阳 550014
通讯作者:
李武斌(1984—),男,内蒙古卓资人,硕士,正高级工程师,主要研究方向为湿法冶金。E-mail:
作者简介:

吴占新(1997—),男,内蒙古赤峰人,硕士,工程师,主要研究方向为锰冶金及电极材料研发。E-mail:

Tartaric Acid Leaching of Spent Lithium Iron Phosphate Batteries
Zhanxin WU , Wubin LI , Yong LI, Zhitong HU, Fajie QIN
Affiliations
  • Guizhou New Materials Research and Development Base, Guiyang 550014, Guizhou, China
doi: 10.3969/j.issn.0253-6099.2026.03.031
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以废旧磷酸铁锂电池正极粉末为原料,采用酒石酸+过氧化氢体系开展锂的选择性浸出研究。结果表明,搅拌速率与液固比对Li、Fe浸出率影响较小,酒石酸质量浓度、浸出温度、浸出时间对Li、Fe浸出率影响显著,过氧化氢浓度主要影响Fe浸出率。确定的优化工艺条件为:酒石酸质量浓度150 g/L、搅拌速率500 r/min、液固比6、浸出时间3 h、过氧化氢浓度3 mol/L、浸出温度70 ℃,该条件下Li、Fe浸出率分别为98.7%、4.5%。锂浸出液经蒸发浓缩、净化处理后,采用碳酸盐沉锂工艺可制得结晶度较好的碳酸锂产品。

废旧电池  /  电池回收  /  浸出  /  酒石酸  /  碳酸锂  /  锂  /  磷酸铁锂  /  正极材料

With cathode powder of spent lithium iron phosphate batteries as raw materials, selective lithium leaching was conducted in a tartaric acid - hydrogen peroxide system. The results indicate that stirring speed and liquid-solid ratio bring slight impact to the leaching rates of lithium and iron, while mass concentration of tartaric acid, leaching temperature and leaching time present remarkable influences. And hydrogen peroxide concentration mainly governs the iron leaching rate. Under the following optimal conditions, including mass concentration of tartaric acid of 150 g/L, stirring speed of 500 r/min, liquid-solid ratio of 6, leaching duration of 3 h, hydrogen peroxide concentration of 3 mol/L and leaching temperature of 70 ℃, the leaching rates of lithium and iron are 98.7% and 4.5% respectively. After the processes of evaporation, concentration and purification, the lithium leachate is subjected to carbonate lithium precipitation, yielding a lithium carbonate product with favorable crystallinity.

spent battery  /  battery recycling  /  leaching  /  tartaric acid  /  lithium carbonate  /  lithium  /  lithium iron phosphate  /  cathode material
吴占新, 李武斌, 李勇, 胡志同, 覃发玠. 废旧磷酸铁锂电池酒石酸浸出研究. 矿冶工程杂志, 2026 , 46 (3) : 210 -213 . DOI: 10.3969/j.issn.0253-6099.2026.03.031
Zhanxin WU, Wubin LI, Yong LI, Zhitong HU, Fajie QIN. Tartaric Acid Leaching of Spent Lithium Iron Phosphate Batteries[J]. Mining and Metallurgical Engineering, 2026 , 46 (3) : 210 -213 . DOI: 10.3969/j.issn.0253-6099.2026.03.031
  • 贵州科学院青年科学基金项目(黔科院J字〔2024〕5号)
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doi: 10.3969/j.issn.0253-6099.2026.03.031
  • 接收时间:2025-12-01
  • 首发时间:2026-10-08
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  • 收稿日期:2025-12-01
基金
贵州科学院青年科学基金项目(黔科院J字〔2024〕5号)
作者信息
    贵州省新材料研究开发基地,贵州 贵阳 550014

通讯作者:

李武斌(1984—),男,内蒙古卓资人,硕士,正高级工程师,主要研究方向为湿法冶金。E-mail:
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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