Article(id=1314908081092395828, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907935172551117, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.03.013, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1776614400000, receivedDateStr=2026-04-20, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428116343, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428116343, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428116343, creator=13701087609, updateTime=1791428116343, updator=13701087609, issue=Issue{id=1314907935172551117, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='3', pageStart='1', pageEnd='297', issueExtLink='null', onlineDate='null', pubDate='1780243200000', pubDateStr='2026-06-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791428081553, creator='13701087609', updateTime=1791430444568, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314917846770082179, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907935172551117, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314917846770082180, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907935172551117, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=106, endPage=110, ext={EN=ArticleExt(id=1314908082833031989, articleId=1314908081092395828, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Extraction of Manganese from Manganese Nodules via Coal-Based Reduction-Leaching Process and Analysis of Its Microscopic Mechanism, columnId=1314908041200362409, journalTitle=Mining and Metallurgical Engineering, columnName=SPECIAL TOPIC ON BREAKTHROUGHS IN KEY TECHNOLOGIES AND COORDINATED DEVELOPMENT OF INDUSTRIAL CHAINS FOR DEEP-SEA MINERAL RESOURCE EXPLOITATION, runingTitle=null, highlight=null, articleAbstract=

A process consisting of reduction roasting and sulfuric acid leaching was adopted to extract manganese from manganese nodules, and the microstructure evolution and phase transformation during the processes from raw ore, roasting to sulfuric acid leaching were explored. It is found that the reduction rate of manganese can reach 99.29% after 2 h reduction process at 750 ℃. After 6 h leaching with 0.5 mL/g of sulfuric acid at 60 ℃, the leaching rate of manganese is 90.53%. It is shown that part of manganese replaces iron to form acid-insoluble minerals such as jarosite and manganese-iron olivine, which are difficult to be leached out. This study provides a technical reference for preparing electrolytic manganese with low-grade manganese nodules.

, authors=Minye XIONG1, 2, Zhijian XU3, Yuhan SONG2, Zhenjin CHENG1, 2, Yanmei PENG2, Lian WANG2, Yisheng WANG2, Xueliang XIONG2, 3, authorsList=Minye XIONG, Zhijian XU, Yuhan SONG, Zhenjin CHENG, Yanmei PENG, Lian WANG, Yisheng WANG, Xueliang XIONG, authorCompany=null, correspAuthors=Xueliang XIONG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314908083512509239, articleId=1314908081092395828, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=煤基还原-浸出锰结核提取锰及微观机理分析, columnId=1314908041376523179, journalTitle=矿冶工程杂志, columnName=深海矿产资源开发关键技术突破与产业链协同发展专题, runingTitle=null, highlight=null, articleAbstract=

采用还原焙烧-硫酸浸出工艺从深海锰结核中提取锰,探究了锰结核在焙烧以及硫酸浸出过程中的微观结构变化与物相转变规律。结果表明,还原温度750 ℃、还原时间2 h条件下,锰还原率为99.29%;硫酸用量0.5 mL/g、浸出温度60 ℃、浸出时间6 h条件下,锰浸出率为90.53%;部分锰替代铁形成了不溶于酸的黄钾铁矾类和锰铁橄榄石类矿石,难以浸出。本研究可为低品位锰结核制备电解锰提供技术参考。

, authors=熊旻烨1, 2, 徐志坚3, 宋雨涵2, 成震今1, 2, 彭艳枚2, 王炼2, 王怡圣2, 熊雪良2, 3, authorsList=熊旻烨, 徐志坚, 宋雨涵, 成震今, 彭艳枚, 王炼, 王怡圣, 熊雪良, authorCompany=null, correspAuthors=熊雪良, authorNote=

熊旻烨(1994—),男,江西宜春人,工程师,研究方向为材料制备与检测。E-mail:

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熊雪良(1976—),男,江西丰城人,正高级工程师,研究方向为锰基新材料制备与应用。E-mail:
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煤基还原-浸出锰结核提取锰及微观机理分析
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熊旻烨 1, 2 , 徐志坚 3 , 宋雨涵 2 , 成震今 1, 2 , 彭艳枚 2 , 王炼 2 , 王怡圣 2 , 熊雪良 2, 3
矿冶工程杂志 | 深海矿产资源开发关键技术突破与产业链协同发展专题 2026,46(3): 106-110
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矿冶工程杂志 |深海矿产资源开发关键技术突破与产业链协同发展专题 2026 , 46 (3) : 106 -110
煤基还原-浸出锰结核提取锰及微观机理分析
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熊旻烨(1994—),男,江西宜春人,工程师,研究方向为材料制备与检测。E-mail:

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熊旻烨(1994—),男,江西宜春人,工程师,研究方向为材料制备与检测。E-mail:

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3.Guizhou Kingrui New Materials Co., Ltd., Tongren 554300, Guizhou, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1314908088709251948, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1314908081092395828, authorId=1314908088537285480, language=CN, stringName=熊雪良, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, 3, address=2.长沙矿冶研究院有限责任公司,湖南 长沙 410012
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熊旻烨1, 2 , 徐志坚3, 宋雨涵2, 成震今1, 2, 彭艳枚2, 王炼2, 王怡圣2, 熊雪良2, 3
作者信息
  • 1.长沙矿冶院检测技术有限责任公司,湖南 长沙 410012
  • 2.长沙矿冶研究院有限责任公司,湖南 长沙 410012
  • 3.贵州金瑞新材料有限责任公司,贵州 铜仁 554300
通讯作者:
熊雪良(1976—),男,江西丰城人,正高级工程师,研究方向为锰基新材料制备与应用。E-mail:
作者简介:

熊旻烨(1994—),男,江西宜春人,工程师,研究方向为材料制备与检测。E-mail:

Extraction of Manganese from Manganese Nodules via Coal-Based Reduction-Leaching Process and Analysis of Its Microscopic Mechanism
Minye XIONG1, 2 , Zhijian XU3, Yuhan SONG2, Zhenjin CHENG1, 2, Yanmei PENG2, Lian WANG2, Yisheng WANG2, Xueliang XIONG2, 3
Affiliations
  • 1.Testing Technology Company of Changsha Research Institute of Mining and Metallurgy Co., Ltd., Changsha 410012, Hunan, China
  • 2.Changsha Research Institute of Mining and Metallurgy Co., Ltd., Changsha 410012, Hunan, China
  • 3.Guizhou Kingrui New Materials Co., Ltd., Tongren 554300, Guizhou, China
doi: 10.3969/j.issn.0253-6099.2026.03.013
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采用还原焙烧-硫酸浸出工艺从深海锰结核中提取锰,探究了锰结核在焙烧以及硫酸浸出过程中的微观结构变化与物相转变规律。结果表明,还原温度750 ℃、还原时间2 h条件下,锰还原率为99.29%;硫酸用量0.5 mL/g、浸出温度60 ℃、浸出时间6 h条件下,锰浸出率为90.53%;部分锰替代铁形成了不溶于酸的黄钾铁矾类和锰铁橄榄石类矿石,难以浸出。本研究可为低品位锰结核制备电解锰提供技术参考。

锰结核  /  煤基还原  /  还原焙烧  /  黄钾铁矾  /  浸出  /  锰

A process consisting of reduction roasting and sulfuric acid leaching was adopted to extract manganese from manganese nodules, and the microstructure evolution and phase transformation during the processes from raw ore, roasting to sulfuric acid leaching were explored. It is found that the reduction rate of manganese can reach 99.29% after 2 h reduction process at 750 ℃. After 6 h leaching with 0.5 mL/g of sulfuric acid at 60 ℃, the leaching rate of manganese is 90.53%. It is shown that part of manganese replaces iron to form acid-insoluble minerals such as jarosite and manganese-iron olivine, which are difficult to be leached out. This study provides a technical reference for preparing electrolytic manganese with low-grade manganese nodules.

manganese nodule  /  coal-based reduction  /  reduction roasting  /  jarosite  /  leaching  /  manganese
熊旻烨, 徐志坚, 宋雨涵, 成震今, 彭艳枚, 王炼, 王怡圣, 熊雪良. 煤基还原-浸出锰结核提取锰及微观机理分析. 矿冶工程杂志, 2026 , 46 (3) : 106 -110 . DOI: 10.3969/j.issn.0253-6099.2026.03.013
Minye XIONG, Zhijian XU, Yuhan SONG, Zhenjin CHENG, Yanmei PENG, Lian WANG, Yisheng WANG, Xueliang XIONG. Extraction of Manganese from Manganese Nodules via Coal-Based Reduction-Leaching Process and Analysis of Its Microscopic Mechanism[J]. Mining and Metallurgical Engineering, 2026 , 46 (3) : 106 -110 . DOI: 10.3969/j.issn.0253-6099.2026.03.013
  • 国家重点研发计划项目(2022YFC3901203)
  • 黔科合平台(JSZX[2025]019)
  • 黔科合成果([2025]重大108)
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2026年第46卷第3期
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doi: 10.3969/j.issn.0253-6099.2026.03.013
  • 接收时间:2026-04-20
  • 首发时间:2026-10-08
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  • 收稿日期:2026-04-20
基金
国家重点研发计划项目(2022YFC3901203)
黔科合平台(JSZX[2025]019)
黔科合成果([2025]重大108)
作者信息
    1.长沙矿冶院检测技术有限责任公司,湖南 长沙 410012
    2.长沙矿冶研究院有限责任公司,湖南 长沙 410012
    3.贵州金瑞新材料有限责任公司,贵州 铜仁 554300

通讯作者:

熊雪良(1976—),男,江西丰城人,正高级工程师,研究方向为锰基新材料制备与应用。E-mail:
参考文献
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https://castjournals.cast.org.cn/joweb/kygczz/CN/10.3969/j.issn.0253-6099.2026.03.013
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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