Article(id=1314907904046629807, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907832038810534, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.02.022, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1760889600000, receivedDateStr=2025-10-20, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428074131, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428074131, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428074131, creator=13701087609, updateTime=1791428074131, updator=13701087609, issue=Issue{id=1314907832038810534, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='2', pageStart='1', pageEnd='214', issueExtLink='null', onlineDate='null', pubDate='1774972800000', pubDateStr='2026-04-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791428056964, creator='13701087609', updateTime=1791430468655, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314917947500486818, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907832038810534, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314917947500486819, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907832038810534, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=140, endPage=144, ext={EN=ArticleExt(id=1314907904809993136, articleId=1314907904046629807, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Experimental Study on Molybdenum Extraction from Ammonia Leaching Residue of Molybdenum Calcine by Oxidative Alkaline Leaching, columnId=1236276106727321817, journalTitle=Mining and Metallurgical Engineering, columnName=METALLURGY, runingTitle=null, highlight=null, articleAbstract=

With ammonia leaching residue from a molybdenum ore in Henan as raw material, a high-temperature oxidative alkali leaching process was adopted to recover molybdenum therein. With Na2CO3+NaOH+H2O2 as a composite leaching agent at the dosage of 200 L/t, 160 kg/t and 200 kg/t respectively, ammonia leaching residue was leached at 70 ℃, with the solid-to-liquid ratio of 1∶5 and agitation speed of 60 r/min, leading to the leaching rate of molybdenum up to 93.75% and the molybdenum content in the obtained alkali leaching residue reduced to 0.46%. Mechanism analysis reveals that in the composite leaching agent, H2O2 can oxidize low-valent molybdenum (MoOx, where 2≤x<3) and MoS2 into soluble MoO42-, and Na2CO3 can displace molybdenum from insoluble molybdates, while NaOH can maintain a high pH of the solution to inhibit the precipitation of molybdic acid. This composite leaching system can efficiently recover refractory molybdenum from ammonia leaching residue, and also significantly shorten the ammonia leaching process. The approach provides an economically feasible technical route for the utilization of low-grade molybdenum resources.

, authors=Xin LIU, Wanhui FAN, Hanquan ZHANG, Hong YU, Bona DENG, authorsList=Xin LIU, Wanhui FAN, Hanquan ZHANG, Hong YU, Bona DENG, authorCompany=null, correspAuthors=Bona DENG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314907905745322930, articleId=1314907904046629807, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=钼焙砂氨浸渣氧化碱浸提钼试验研究, columnId=1236276107322913000, journalTitle=矿冶工程杂志, columnName=冶金, runingTitle=null, highlight=null, articleAbstract=

以河南某钼矿氨浸渣为原料,采用高温氧化碱浸法对氨浸渣中的钼进行回收。结果表明,以Na2CO3+NaOH+H2O2作为复合浸出剂,浸出剂Na2CO3+NaOH+H2O2用量200 kg/t+160 kg/t+200 L/t、浸出温度70 ℃、固液比1∶5、振荡速度60 r/min条件下,氨浸渣中钼的浸出率达到93.75%,碱浸渣钼品位降至0.46%。机理分析表明,复合浸出剂中H2O2可将低价钼(MoOx,2≤x<3)及MoS2氧化成MoO42-;Na2CO3能够置换出不溶钼酸盐中的钼;NaOH可维持溶液高pH值,抑制钼酸沉淀生成。该复合浸出体系可高效回收氨浸渣中的难溶钼,缩短氨浸渣浸出流程,为低品位钼资源利用提供了经济可行的技术路径。

, authors=刘鑫, 范宛惠, 张汉泉, 余洪, 邓博纳, authorsList=刘鑫, 范宛惠, 张汉泉, 余洪, 邓博纳, authorCompany=null, correspAuthors=邓博纳, authorNote=

刘鑫(2001-),女,山东潍坊人,硕士研究生,主要研究方向为矿物加工。E-mail:

, correspAuthorsNote=
邓博纳(1991-),女,湖北黄冈人,博士,讲师,主要研究方向为大宗固废资源高效利用、共伴生稀散金属提取、矿物材料制备。E-mail:
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刘鑫(2001-),女,山东潍坊人,硕士研究生,主要研究方向为矿物加工。E-mail:

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钼焙砂氨浸渣氧化碱浸提钼试验研究
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刘鑫 , 范宛惠 , 张汉泉 , 余洪 , 邓博纳
矿冶工程杂志 | 冶金 2026,46(2): 140-144
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矿冶工程杂志 |冶金 2026 , 46 (2) : 140 -144
钼焙砂氨浸渣氧化碱浸提钼试验研究
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刘鑫 , 范宛惠, 张汉泉, 余洪, 邓博纳
作者信息
  • 武汉工程大学资源与安全工程学院,湖北 武汉 430205
通讯作者:
邓博纳(1991-),女,湖北黄冈人,博士,讲师,主要研究方向为大宗固废资源高效利用、共伴生稀散金属提取、矿物材料制备。E-mail:
作者简介:

刘鑫(2001-),女,山东潍坊人,硕士研究生,主要研究方向为矿物加工。E-mail:

Experimental Study on Molybdenum Extraction from Ammonia Leaching Residue of Molybdenum Calcine by Oxidative Alkaline Leaching
Xin LIU , Wanhui FAN, Hanquan ZHANG, Hong YU, Bona DENG
Affiliations
  • School of Resource and Safety Engineering, Wuhan Institute of Technology, Wuhan 430205, Hubei, China
doi: 10.3969/j.issn.0253-6099.2026.02.022
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以河南某钼矿氨浸渣为原料,采用高温氧化碱浸法对氨浸渣中的钼进行回收。结果表明,以Na2CO3+NaOH+H2O2作为复合浸出剂,浸出剂Na2CO3+NaOH+H2O2用量200 kg/t+160 kg/t+200 L/t、浸出温度70 ℃、固液比1∶5、振荡速度60 r/min条件下,氨浸渣中钼的浸出率达到93.75%,碱浸渣钼品位降至0.46%。机理分析表明,复合浸出剂中H2O2可将低价钼(MoOx,2≤x<3)及MoS2氧化成MoO42-;Na2CO3能够置换出不溶钼酸盐中的钼;NaOH可维持溶液高pH值,抑制钼酸沉淀生成。该复合浸出体系可高效回收氨浸渣中的难溶钼,缩短氨浸渣浸出流程,为低品位钼资源利用提供了经济可行的技术路径。

辉钼矿  /  钼氨浸渣  /  氧化碱浸  /  工艺优化  /  同步浸出

With ammonia leaching residue from a molybdenum ore in Henan as raw material, a high-temperature oxidative alkali leaching process was adopted to recover molybdenum therein. With Na2CO3+NaOH+H2O2 as a composite leaching agent at the dosage of 200 L/t, 160 kg/t and 200 kg/t respectively, ammonia leaching residue was leached at 70 ℃, with the solid-to-liquid ratio of 1∶5 and agitation speed of 60 r/min, leading to the leaching rate of molybdenum up to 93.75% and the molybdenum content in the obtained alkali leaching residue reduced to 0.46%. Mechanism analysis reveals that in the composite leaching agent, H2O2 can oxidize low-valent molybdenum (MoOx, where 2≤x<3) and MoS2 into soluble MoO42-, and Na2CO3 can displace molybdenum from insoluble molybdates, while NaOH can maintain a high pH of the solution to inhibit the precipitation of molybdic acid. This composite leaching system can efficiently recover refractory molybdenum from ammonia leaching residue, and also significantly shorten the ammonia leaching process. The approach provides an economically feasible technical route for the utilization of low-grade molybdenum resources.

molybdenite  /  ammonia leaching residue of molybdenum  /  oxidative alkali leaching  /  process optimization  /  synchronous leaching
刘鑫, 范宛惠, 张汉泉, 余洪, 邓博纳. 钼焙砂氨浸渣氧化碱浸提钼试验研究. 矿冶工程杂志, 2026 , 46 (2) : 140 -144 . DOI: 10.3969/j.issn.0253-6099.2026.02.022
Xin LIU, Wanhui FAN, Hanquan ZHANG, Hong YU, Bona DENG. Experimental Study on Molybdenum Extraction from Ammonia Leaching Residue of Molybdenum Calcine by Oxidative Alkaline Leaching[J]. Mining and Metallurgical Engineering, 2026 , 46 (2) : 140 -144 . DOI: 10.3969/j.issn.0253-6099.2026.02.022
  • 国家自然科学基金(52234008)
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doi: 10.3969/j.issn.0253-6099.2026.02.022
  • 接收时间:2025-10-20
  • 首发时间:2026-10-08
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  • 收稿日期:2025-10-20
基金
国家自然科学基金(52234008)
作者信息
    武汉工程大学资源与安全工程学院,湖北 武汉 430205

通讯作者:

邓博纳(1991-),女,湖北黄冈人,博士,讲师,主要研究方向为大宗固废资源高效利用、共伴生稀散金属提取、矿物材料制备。E-mail:
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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