Article(id=1314907733921456724, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907656704324517, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.01.014, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1756310400000, receivedDateStr=2025-08-28, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428033570, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428033570, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428033570, creator=13701087609, updateTime=1791428033570, updator=13701087609, issue=Issue{id=1314907656704324517, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='1', pageStart='1', pageEnd='206', issueExtLink='null', onlineDate='null', pubDate='1769875200000', pubDateStr='2026-02-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791428015160, creator='13701087609', updateTime=1791430491940, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314918045139690301, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907656704324517, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314918045139690302, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907656704324517, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=85, endPage=90, ext={EN=ArticleExt(id=1314907735221690965, articleId=1314907733921456724, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Collecting Performance and Mechanism of Novel Phosphonic Acid Type Collectors for Zircon and Rutile, columnId=1236276106932842717, journalTitle=Mining and Metallurgical Engineering, columnName=MINERAL PROCESSING, runingTitle=null, highlight=null, articleAbstract=

For solving the difficulty in separation between zircon and rutile, 1-hydroxyethane-1, 1-diphosphonic acid (GS) was independently synthesized, and effects of GS, etedronate sodium (ETD) and amino-trimethylphosphonic acid (ATMP) on flotation of zircon and rutile were also explored. Based on micro-flotation tests, the collecting performance and corresponding mechanism of collectors were analyzed by contact angle measurement, Zeta potential measurement and FTIR spectroscopy. It is found that GS exhibits excellent collection performance and selectivity in separation under neutral conditions, bringing in significant improvement in separation between rutile and zircon. Phosphonic acid group of GS enhances the electronegativity and hydrophobicity by multi-point adsorption, resulting in effective collection. The FTIR analysis has further approved chemical adsorption of phosphonic acid group.

, authors=Liuyi REN^{1, 2, 3}, Sidi LOU¹, Yuebo ZHANG¹, Yuting MA¹, Xinyu ZHANG^{1, 2, 3}, authorsList=Liuyi REN, Sidi LOU, Yuebo ZHANG, Yuting MA, Xinyu ZHANG, authorCompany=null, correspAuthors=Sidi LOU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314907736454816342, articleId=1314907733921456724, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=新型膦酸型捕收剂对锆英石与金红石的捕收性能及机理研究, columnId=1236276107125780707, journalTitle=矿冶工程杂志, columnName=选矿, runingTitle=null, highlight=null, articleAbstract=

针对锆英石与金红石分离难题，自主合成了1-羟基乙烷-1，1-二膦酸（GS），并研究了GS、依替膦酸钠（ETD）、氨基三亚甲基膦酸（ATMP）对锆英石与金红石的浮选效果；通过微浮选试验、接触角测量、Zeta电位测试和红外光谱测试等研究和分析捕收剂对锆英石和金红石的捕收性能及机理。结果表明，GS在中性条件下表现出优异的捕收性能和分离选择性，显著提升了金红石与锆英石的分离效果；GS的磷酸基团通过多点吸附作用增强矿物表面电负性和疏水性实现对矿物的有效捕收，红外光谱分析结果进一步证实了磷酸基团的化学吸附作用。

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任浏祎（1983—），女，河南周口人，博士，教授，博士研究生导师，主要研究方向为复杂微细矿物分选。E-mail: rly1015@whut.edu.cn

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任浏祎（1983—），女，河南周口人，博士，教授，博士研究生导师，主要研究方向为复杂微细矿物分选。E-mail: rly1015@whut.edu.cn

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