Article(id=1314907192768164129, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907112854089785, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2025.06.021, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1748707200000, receivedDateStr=2025-06-01, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791427904550, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791427904550, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791427904550, creator=13701087609, updateTime=1791427904550, updator=13701087609, issue=Issue{id=1314907112854089785, tenantId=1146029695717560320, journalId=1235980550691926019, year='2025', volume='45', issue='6', pageStart='1', pageEnd='228', issueExtLink='null', onlineDate='null', pubDate='1764518400000', pubDateStr='2025-12-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1791427885497, creator='13701087609', updateTime=1791430521754, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314918170201252492, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907112854089785, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314918170201252493, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314907112854089785, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=119, endPage=123, ext={EN=ArticleExt(id=1314907193598636323, articleId=1314907192768164129, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Enhanced Leaching of Vanadium and Gallium from Red Mud with a Mixture of Acids, columnId=1236276106727321817, journalTitle=Mining and Metallurgical Engineering, columnName=METALLURGY, runingTitle=null, highlight=null, articleAbstract=

A mixture of two acids (H2SO4, HCl) was used to enhance the acid leaching of vanadium (V) and gallium (Ga) from red mud, and the effects of key parameters on the leaching rates of V and Ga were investigated, including volume ratio of two acids, acid concentration, reaction time, leaching temperature and liquid-to-solid ratio. The results show that under the following conditions, including two acids in a volume ratio of 1∶1, acid concentration of 28.89%, liquid-to-solid ratio of 9, reaction time of 60 min and leaching temperature of 120 ℃, the leaching rates of V and Ga can reach 90.65% and 97.30%, respectively. X-ray diffraction (XRD) and thermodynamic analyses indicate that muscovite, hematite and perovskite in red mud are dissolved to some extent during the acid leaching process, and vanadium and gallium exist in different valence states in the leachate. It is concluded that acid leaching can effectively promote dissolution of minerals and release of valuable metals.

, authors=Ting GUO1, Xiaobo ZHU1, Wang LI1, Caifeng YUAN2, Yajun LYU3, authorsList=Ting GUO, Xiaobo ZHU, Wang LI, Caifeng YUAN, Yajun LYU, authorCompany=null, correspAuthors=Xiaobo ZHU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314907194852733220, articleId=1314907192768164129, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=双酸复配强化浸出赤泥中钒和镓, columnId=1236276107322913000, journalTitle=矿冶工程杂志, columnName=冶金, runingTitle=null, highlight=null, articleAbstract=

采用双酸(H2SO4,HCl)复配强化酸浸的方法提取赤泥中的钒、镓,考察了双酸体积配比、酸浓度、反应时间、浸出温度以及液固比对钒、镓浸出率的影响。结果表明,在双酸体积配比1∶1、酸浓度28.89%、液固比9、反应时间60 min、浸出温度120 ℃条件下,钒浸出率为90.65%,镓浸出率为97.30%。X射线衍射分析和热力学分析结果表明,在酸浸过程中,赤泥中的白云母、赤铁矿和钙钛矿均被一定程度溶解;钒和镓分别以钒酸盐和镓离子形式存在于酸浸液中,表明酸浸有效促进了矿物的溶解及有价金属的释放。

, authors=郭婷1, 朱晓波1, 李望1, 袁彩凤2, 吕亚军3, authorsList=郭婷, 朱晓波, 李望, 袁彩凤, 吕亚军, authorCompany=null, correspAuthors=朱晓波, authorNote=

郭婷(1999—),女,甘肃陇南人,硕士研究生,主要从事赤泥有价金属综合回收。E-mail:

, correspAuthorsNote=
朱晓波(1985—),男,辽宁辽阳人,博士,副教授,主要从事化学提取分离与固废资源化利用方面的研究。E-mail:
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郭婷(1999—),女,甘肃陇南人,硕士研究生,主要从事赤泥有价金属综合回收。E-mail:

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郭婷(1999—),女,甘肃陇南人,硕士研究生,主要从事赤泥有价金属综合回收。E-mail:

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双酸复配强化浸出赤泥中钒和镓
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郭婷 1 , 朱晓波 1 , 李望 1 , 袁彩凤 2 , 吕亚军 3
矿冶工程杂志 | 冶金 2025,45(6): 119-123
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矿冶工程杂志 |冶金 2025 , 45 (6) : 119 -123
双酸复配强化浸出赤泥中钒和镓
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郭婷1 , 朱晓波1 , 李望1, 袁彩凤2, 吕亚军3
作者信息
  • 1.河南理工大学化学化工学院,河南 焦作 454000
  • 2.河南省生态环境技术中心,河南 郑州 450000
  • 3.华北水利水电大学建筑学院,河南 郑州 450046
通讯作者:
朱晓波(1985—),男,辽宁辽阳人,博士,副教授,主要从事化学提取分离与固废资源化利用方面的研究。E-mail:
作者简介:

郭婷(1999—),女,甘肃陇南人,硕士研究生,主要从事赤泥有价金属综合回收。E-mail:

Enhanced Leaching of Vanadium and Gallium from Red Mud with a Mixture of Acids
Ting GUO1 , Xiaobo ZHU1 , Wang LI1, Caifeng YUAN2, Yajun LYU3
Affiliations
  • 1.School of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454000, Henan, China
  • 2.Henan Ecological Environment Technology Center, Zhengzhou 450000, Henan, China
  • 3.School of Architecture, North China University of Water Resources and Electric Power, Zhengzhou 450046, Henan, China
doi: 10.3969/j.issn.0253-6099.2025.06.021
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采用双酸(H2SO4,HCl)复配强化酸浸的方法提取赤泥中的钒、镓,考察了双酸体积配比、酸浓度、反应时间、浸出温度以及液固比对钒、镓浸出率的影响。结果表明,在双酸体积配比1∶1、酸浓度28.89%、液固比9、反应时间60 min、浸出温度120 ℃条件下,钒浸出率为90.65%,镓浸出率为97.30%。X射线衍射分析和热力学分析结果表明,在酸浸过程中,赤泥中的白云母、赤铁矿和钙钛矿均被一定程度溶解;钒和镓分别以钒酸盐和镓离子形式存在于酸浸液中,表明酸浸有效促进了矿物的溶解及有价金属的释放。

赤泥  /  钒  /  镓  /  强化浸出  /  双酸复配  /  酸浸

A mixture of two acids (H2SO4, HCl) was used to enhance the acid leaching of vanadium (V) and gallium (Ga) from red mud, and the effects of key parameters on the leaching rates of V and Ga were investigated, including volume ratio of two acids, acid concentration, reaction time, leaching temperature and liquid-to-solid ratio. The results show that under the following conditions, including two acids in a volume ratio of 1∶1, acid concentration of 28.89%, liquid-to-solid ratio of 9, reaction time of 60 min and leaching temperature of 120 ℃, the leaching rates of V and Ga can reach 90.65% and 97.30%, respectively. X-ray diffraction (XRD) and thermodynamic analyses indicate that muscovite, hematite and perovskite in red mud are dissolved to some extent during the acid leaching process, and vanadium and gallium exist in different valence states in the leachate. It is concluded that acid leaching can effectively promote dissolution of minerals and release of valuable metals.

red mud  /  vanadium  /  gallium  /  enhanced leaching  /  mixture of two acids  /  acid leaching
郭婷, 朱晓波, 李望, 袁彩凤, 吕亚军. 双酸复配强化浸出赤泥中钒和镓. 矿冶工程杂志, 2025 , 45 (6) : 119 -123 . DOI: 10.3969/j.issn.0253-6099.2025.06.021
Ting GUO, Xiaobo ZHU, Wang LI, Caifeng YUAN, Yajun LYU. Enhanced Leaching of Vanadium and Gallium from Red Mud with a Mixture of Acids[J]. Mining and Metallurgical Engineering, 2025 , 45 (6) : 119 -123 . DOI: 10.3969/j.issn.0253-6099.2025.06.021
  • 国家自然科学基金(51804103; 51904097)
  • 河南省重点研发计划(231111321800)
  • 河南省科技项目(242102320354)
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doi: 10.3969/j.issn.0253-6099.2025.06.021
  • 接收时间:2025-06-01
  • 首发时间:2026-10-08
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  • 收稿日期:2025-06-01
基金
国家自然科学基金(51804103; 51904097)
河南省重点研发计划(231111321800)
河南省科技项目(242102320354)
作者信息
    1.河南理工大学化学化工学院,河南 焦作 454000
    2.河南省生态环境技术中心,河南 郑州 450000
    3.华北水利水电大学建筑学院,河南 郑州 450046

通讯作者:

朱晓波(1985—),男,辽宁辽阳人,博士,副教授,主要从事化学提取分离与固废资源化利用方面的研究。E-mail:
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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