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In order to obtain the optimal concentration of bone glue as a commonly used additive for lead electrolysis and also understand the influence of its colloidal impurities on lead electrolysis, the effects of the concentration of bone glue in the electrolyte, the standing time of bone glue solution and the liquid-solid ratio for purification with activated carbon on lead electrolysis were investigated by evaluating the turbidity of the solution, current efficiency, power consumption and the morphology of precipitated lead. It is found that the optimal concentration of bone glue in lead electrolyte is 0.8 g/L, and colloidal impurities can be removed by resting the bone glue solution for 72 hours or by purifying it with activated carbon in a ratio of 1 000∶1. After purification, lead electrolyte has its current efficiency up to 99.19%. The power consumption of electrolysis declines to 51.79 kW·h/t, and the obtained precipitated lead has a flat and smooth surface.

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为了明确铅电解常用添加剂骨胶的最佳浓度以及胶体杂质对铅电解的影响,从溶液浑浊度、电流效率、电耗及析出铅形貌等方面对电解液进行评估,研究了电解液骨胶浓度、骨胶溶液静置时长以及活性炭净化处理液固比对铅电解的影响。结果表明,适宜的骨胶浓度为0.8 g/L;将铅电解配制所用骨胶溶液静置72 h或经1 000∶1活性炭净化均能去除胶体杂质,净化后铅电解液的电流效率高达99.19%,电耗降至51.79 kW·h/t,获得的析出铅表面平整光滑。

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钟勇(1970—),男,江西上犹人,硕士,教授级高级工程师,主要从事有色金属冶炼技术研发和管理。

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钟勇(1970—),男,江西上犹人,硕士,教授级高级工程师,主要从事有色金属冶炼技术研发和管理。

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钟勇(1970—),男,江西上犹人,硕士,教授级高级工程师,主要从事有色金属冶炼技术研发和管理。

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骨胶对铅电解阴极行为的影响研究
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钟勇 1 , 高和欣 2 , 王文军 2 , 袁铁锤 2 , 邹亮 2 , 蔺士琦 2 , 方浩煜 2 , 颜巧玲 2
矿冶工程杂志 | 冶金 2023,43(6): 139-143
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矿冶工程杂志 | 冶金 2023, 43(6): 139-143
骨胶对铅电解阴极行为的影响研究
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钟勇1, 高和欣2, 王文军2, 袁铁锤2, 邹亮2, 蔺士琦2, 方浩煜2, 颜巧玲2
作者信息
  • 1.深圳市中金岭南有色金属股份有限公司韶关冶炼厂,广东 韶关 512000
  • 2.中南大学,湖南 长沙 410083
  • 钟勇(1970—),男,江西上犹人,硕士,教授级高级工程师,主要从事有色金属冶炼技术研发和管理。

Influence of Bone Glue on Cathodic Behavior of Lead Electrolysis
Yong ZHONG1, Hexin GAO2, Wenjun WANG2, Tiechui YUAN2, Liang ZOU2, Shiqi LIN2, Haoyu FANG2, Qiaoling YAN2
Affiliations
  • 1.Shaoguan Smelter, Shenzhen Zhongjin Lingnan Nonfemet Co Ltd, Shaoguan 512000, Guangdong, China
  • 2.Central South University, Changsha 410083, Hunan, China
出版时间: 2023-12-01 doi: 10.3969/j.issn.0253-6099.2023.06.030
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为了明确铅电解常用添加剂骨胶的最佳浓度以及胶体杂质对铅电解的影响,从溶液浑浊度、电流效率、电耗及析出铅形貌等方面对电解液进行评估,研究了电解液骨胶浓度、骨胶溶液静置时长以及活性炭净化处理液固比对铅电解的影响。结果表明,适宜的骨胶浓度为0.8 g/L;将铅电解配制所用骨胶溶液静置72 h或经1 000∶1活性炭净化均能去除胶体杂质,净化后铅电解液的电流效率高达99.19%,电耗降至51.79 kW·h/t,获得的析出铅表面平整光滑。

铅电解  /  添加剂  /  骨胶除杂  /  电流效率  /  电耗

In order to obtain the optimal concentration of bone glue as a commonly used additive for lead electrolysis and also understand the influence of its colloidal impurities on lead electrolysis, the effects of the concentration of bone glue in the electrolyte, the standing time of bone glue solution and the liquid-solid ratio for purification with activated carbon on lead electrolysis were investigated by evaluating the turbidity of the solution, current efficiency, power consumption and the morphology of precipitated lead. It is found that the optimal concentration of bone glue in lead electrolyte is 0.8 g/L, and colloidal impurities can be removed by resting the bone glue solution for 72 hours or by purifying it with activated carbon in a ratio of 1 000∶1. After purification, lead electrolyte has its current efficiency up to 99.19%. The power consumption of electrolysis declines to 51.79 kW·h/t, and the obtained precipitated lead has a flat and smooth surface.

lead electrolysis  /  additives  /  removal of impurity in bone glue  /  current efficiency  /  power consumption
钟勇, 高和欣, 王文军, 袁铁锤, 邹亮, 蔺士琦, 方浩煜, 颜巧玲. 骨胶对铅电解阴极行为的影响研究. 矿冶工程杂志, 2023 , 43 (6) : 139 -143 . DOI: 10.3969/j.issn.0253-6099.2023.06.030
Yong ZHONG, Hexin GAO, Wenjun WANG, Tiechui YUAN, Liang ZOU, Shiqi LIN, Haoyu FANG, Qiaoling YAN. Influence of Bone Glue on Cathodic Behavior of Lead Electrolysis[J]. Mining and Metallurgical Engineering, 2023 , 43 (6) : 139 -143 . DOI: 10.3969/j.issn.0253-6099.2023.06.030
2023年第43卷第6期
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doi: 10.3969/j.issn.0253-6099.2023.06.030
  • 接收时间:2023-06-23
  • 首发时间:2026-03-05
  • 出版时间:2023-12-01
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  • 收稿日期:2023-06-23
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    1.深圳市中金岭南有色金属股份有限公司韶关冶炼厂,广东 韶关 512000
    2.中南大学,湖南 长沙 410083
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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