Article(id=1236333408834605600, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236333405122646435, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2023.01.010, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1662998400000, receivedDateStr=2022-09-13, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1772694454629, onlineDateStr=2026-03-05, pubDate=1675180800000, pubDateStr=2023-02-01, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1772694454629, onlineIssueDateStr=2026-03-05, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1772694454629, creator=13701087609, updateTime=1772694454629, updator=13701087609, issue=Issue{id=1236333405122646435, tenantId=1146029695717560320, journalId=1235980550691926019, year='2023', volume='43', issue='1', pageStart='1', pageEnd='159', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1772694453745, creator=13701087609, updateTime=1772694772892, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1236334743785099547, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236333405122646435, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1236334743785099548, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236333405122646435, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=45, endPage=49, ext={EN=ArticleExt(id=1236333409119818293, articleId=1236333408834605600, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Influence of Ultrasonic Treatment on Flotation Behavior of Calcite in Sodium Silicate and Sodium Oleate Systems and Mechanism, columnId=1236276106932842717, journalTitle=Mining and Metallurgical Engineering, columnName=MINERAL PROCESSING, runingTitle=null, highlight=null, articleAbstract=
An experiment on flotation of calcite in pulp with pH of 8.0 and the dosages for sodium silicate and sodium oleate respectively at 300 mg/L and 1.5 × 10-4 mol/L was performed by using ultrasonic wave with the frequency at 40 kHz, for investigating the influence of ultrasonic power and sonication duration on the flotation behavior. The variation of sodium oleate content on the surface of calcite was analyzed by adsorption measurement, the chemical status of elements on the calcite surface was analyzed by XPS, and the variation of adsorbed reagents was also analyzed by zeta potential measurement. After 15 min-ultrasonication (40 kHz, 150 W), the flotation recovery of calcite can be increased from 8.5% to 82.7%. It is found that ultrasonication can bring in an increase in the adsorbed amount of sodium oleate on calcite, a decrease in the intensity of Si2p on calcite, and also an increase in the content of C1s. Meanwhile, the deconvolution of O1s spectrum shows reduction in the peak area of sodium silicate, but an increase in that of sodium oleate, and the surface zeta potential of calcite almost unchanged. The results indicate that the ultrasonication can induce a desorption of sodium silicate from the depressed calcite in the pulp containing both sodium silicate and sodium oleate, thus the freshly vacancy can be adsorbed by sodium oleate, leading to the significant improvement in floatability of calcite.
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选用频率40 kHz的超声波，探究了不同超声功率以及不同超声处理时间对pH=8.0、水玻璃用量300 mg/L、油酸钠用量1.5 × 10-4mol/L的药剂体系中方解石浮选行为的影响；通过吸附量测定分析了方解石表面的油酸钠含量变化，借助XPS测试分析了方解石表面元素的变化，采用Zeta电位测试分析了方解石表面吸附药剂的变化。经超声频率40 kHz、功率150 W、超声时间15 min处理后，方解石浮选回收率可由无超声处理时的8.5%增加至82.7%。超声处理使方解石表面油酸钠吸附量增加、方解石表面Si2p含量减少、C1s含量增加、O1s分峰拟合图中水玻璃组分的峰面积减小、油酸钠组分的峰面积增大，方解石表面Zeta电位几乎无变化。超声处理能使水玻璃和油酸钠混合体系中受抑制方解石表面的水玻璃解吸，空出的吸附位点被油酸钠吸附，使得方解石可浮性显著提升。
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崔瑞（1984—），男，湖北襄阳人，博士，副教授，主要从事矿物分选原理及工艺相关研究工作。
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施佳（1999—），女，湖北孝感人，硕士研究生，主要研究方向为超声浮选。
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1.College of Resources and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, Hubei, China
2.Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan 430081, Hubei, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1236340790037893451, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, authorId=1236340789815595321, language=CN, stringName=施佳, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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1．武汉科技大学 资源与环境工程学院，湖北 武汉 430081
2．冶金矿产资源高效利用与造块湖北省重点实验室，湖北 武汉 430081, bio={"content":"
施佳（1999—），女，湖北孝感人，硕士研究生，主要研究方向为超声浮选。
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施佳（1999—），女，湖北孝感人，硕士研究生，主要研究方向为超声浮选。
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1.College of Resources and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, Hubei, China
2.Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan 430081, Hubei, China
3.Changsha Research Institute of Mining and Metallurgy Co Ltd, Changsha 410012, Hunan, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1236340790352466281, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, authorId=1236340790134362451, language=CN, stringName=李茂林, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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1．武汉科技大学 资源与环境工程学院，湖北 武汉 430081
2．冶金矿产资源高效利用与造块湖北省重点实验室，湖北 武汉 430081
3．长沙矿冶研究院有限责任公司，湖南 长沙 410012, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1236340789350027541, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, xref=1., ext=[AuthorCompanyExt(id=1236340789358416150, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, companyId=1236340789350027541, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
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3.Changsha Research Institute of Mining and Metallurgy Co Ltd, Changsha 410012, Hunan, China), AuthorCompanyExt(id=1236340789668794673, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, companyId=1236340789652017455, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
3．长沙矿冶研究院有限责任公司，湖南 长沙 410012)])]), Author(id=1236340790465712504, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, orderNo=2, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1236340790595735937, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, authorId=1236340790465712504, language=EN, stringName=Zhehui YANG, firstName=Zhehui, middleName=null, lastName=YANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
1, 2, address=
1.College of Resources and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, Hubei, China
2.Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan 430081, Hubei, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1236340790721565065, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, authorId=1236340790465712504, language=CN, stringName=杨哲辉, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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1．武汉科技大学 资源与环境工程学院，湖北 武汉 430081
2．冶金矿产资源高效利用与造块湖北省重点实验室，湖北 武汉 430081, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1236340789350027541, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, xref=1., ext=[AuthorCompanyExt(id=1236340789358416150, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, companyId=1236340789350027541, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
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1, 2, address=
1.College of Resources and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, Hubei, China
2.Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan 430081, Hubei, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1236340791216492970, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, authorId=1236340790956446099, language=CN, stringName=姚伟, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=
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1．武汉科技大学 资源与环境工程学院，湖北 武汉 430081
2．冶金矿产资源高效利用与造块湖北省重点实验室，湖北 武汉 430081, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1236340789350027541, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, xref=1., ext=[AuthorCompanyExt(id=1236340789358416150, tenantId=1146029695717560320, journalId=1235980550691926019, articleId=1236333408834605600, companyId=1236340789350027541, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
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