Article(id=1236330609283486471, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236330603000418795, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2023.04.036, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1678464000000, receivedDateStr=2023-03-11, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1772693787165, onlineDateStr=2026-03-05, pubDate=1690819200000, pubDateStr=2023-08-01, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1772693787165, onlineIssueDateStr=2026-03-05, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1772693787165, creator=13701087609, updateTime=1772693787165, updator=13701087609, issue=Issue{id=1236330603000418795, tenantId=1146029695717560320, journalId=1235980550691926019, year='2023', volume='43', issue='4', pageStart='1', pageEnd='189', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1772693785667, creator=13701087609, updateTime=1772696855253, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1236343477835985022, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236330603000418795, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1236343477835985023, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236330603000418795, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=169, endPage=173, ext={EN=ArticleExt(id=1236330609627419417, articleId=1236330609283486471, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Electrochemical Performance of Coconut Shell Carbon as Anode Material for Lithium-Ion Batteries, columnId=1236276108207902848, journalTitle=Mining and Metallurgical Engineering, columnName=MATERIALS, runingTitle=null, highlight=null, articleAbstract=

Activated carbon derived from coconut shell was prepared as anode material by adopting high temperature pyrolysis and activation. The effects of activation on the structure, morphology and electrochemical properties of coconut shell carbon were investigated by using X-ray diffraction, Raman spectroscopy, scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The results show that the coconut shell carbon after activation process is highly disordered, and also microporous and mesoporous. It delivers an initial discharge specific capacity of 918.22 mAh/g at a current density of 0.1 A/g, and retains a specific capacity of 447 mAh/g after 200 cycles discharge at a current density of 1 A/g.

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以椰壳为原料,采用高温热解法和活化法制备了椰壳活性炭负极材料。通过X射线衍射、拉曼光谱、扫描电子显微镜、循环伏安法和电化学阻抗谱图等手段考察了活化处理对椰壳炭结构、形貌以及电化学性能的影响。结果表明,经活化处理的椰壳炭无序化程度高,富含微孔、介孔多孔结构,在0.1 A/g电流密度下,首次放电比容量达到918.22 mAh/g,在1 A/g电流密度下循环200次后放电比容量仍有447 mAh/g。

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刘洁群(1975—),女,江西吉安人,硕士,实验师,主要研究方向为海洋船舶动力电池材料等。
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张舰(1997—),男,山东日照人,硕士研究生,主要研究方向为资源综合利用与新材料制备。

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张舰(1997—),男,山东日照人,硕士研究生,主要研究方向为资源综合利用与新材料制备。

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张舰(1997—),男,山东日照人,硕士研究生,主要研究方向为资源综合利用与新材料制备。

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椰壳炭作为锂离子电池负极材料的电化学性能研究
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张舰 1, 2 , 陈旭 1, 2 , 史世和 1, 2 , 白世伟 1, 2 , 陈庆荣 1, 2 , 钟胜奎 1, 2 , 刘洁群 1, 2
矿冶工程杂志 | 材料 2023,43(4): 169-173
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矿冶工程杂志 | 材料 2023, 43(4): 169-173
椰壳炭作为锂离子电池负极材料的电化学性能研究
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张舰1, 2, 陈旭1, 2, 史世和1, 2, 白世伟1, 2, 陈庆荣1, 2, 钟胜奎1, 2, 刘洁群1, 2
作者信息
  • 1.海南热带海洋学院 海洋科学技术学院,海南 三亚 572022
  • 2.海南热带海洋学院 崖州湾创新研究院,海南 三亚 572022
  • 张舰(1997—),男,山东日照人,硕士研究生,主要研究方向为资源综合利用与新材料制备。

通讯作者:

刘洁群(1975—),女,江西吉安人,硕士,实验师,主要研究方向为海洋船舶动力电池材料等。
Electrochemical Performance of Coconut Shell Carbon as Anode Material for Lithium-Ion Batteries
Jian ZHANG1, 2, Xu CHEN1, 2, Shihe SHI1, 2, Shiwei BAI1, 2, Qingrong CHEN1, 2, Shengkui ZHONG1, 2, Jiequn LIU1, 2
Affiliations
  • 1.College of Marine Science and Technology, Hainan Tropical Ocean University, Sanya 572022, Hainan, China
  • 2.Yazhouwan Research Institute of Innovation, Hainan Tropical Ocean University, Sanya 572022, Hainan, China
出版时间: 2023-08-01 doi: 10.3969/j.issn.0253-6099.2023.04.036
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以椰壳为原料,采用高温热解法和活化法制备了椰壳活性炭负极材料。通过X射线衍射、拉曼光谱、扫描电子显微镜、循环伏安法和电化学阻抗谱图等手段考察了活化处理对椰壳炭结构、形貌以及电化学性能的影响。结果表明,经活化处理的椰壳炭无序化程度高,富含微孔、介孔多孔结构,在0.1 A/g电流密度下,首次放电比容量达到918.22 mAh/g,在1 A/g电流密度下循环200次后放电比容量仍有447 mAh/g。

锂离子电池  /  负极材料  /  椰壳炭  /  电化学性能  /  活性炭

Activated carbon derived from coconut shell was prepared as anode material by adopting high temperature pyrolysis and activation. The effects of activation on the structure, morphology and electrochemical properties of coconut shell carbon were investigated by using X-ray diffraction, Raman spectroscopy, scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The results show that the coconut shell carbon after activation process is highly disordered, and also microporous and mesoporous. It delivers an initial discharge specific capacity of 918.22 mAh/g at a current density of 0.1 A/g, and retains a specific capacity of 447 mAh/g after 200 cycles discharge at a current density of 1 A/g.

lithium-ion battery  /  anode material  /  coconut shell carbon  /  electrochemical performance  /  activated carbon
张舰, 陈旭, 史世和, 白世伟, 陈庆荣, 钟胜奎, 刘洁群. 椰壳炭作为锂离子电池负极材料的电化学性能研究. 矿冶工程杂志, 2023 , 43 (4) : 169 -173 . DOI: 10.3969/j.issn.0253-6099.2023.04.036
Jian ZHANG, Xu CHEN, Shihe SHI, Shiwei BAI, Qingrong CHEN, Shengkui ZHONG, Jiequn LIU. Electrochemical Performance of Coconut Shell Carbon as Anode Material for Lithium-Ion Batteries[J]. Mining and Metallurgical Engineering, 2023 , 43 (4) : 169 -173 . DOI: 10.3969/j.issn.0253-6099.2023.04.036
  • 国家自然科学基金(52074099; 52164029)
  • 海南省自然科学基金(821MS0782; 221MS048; 221RC585)
  • 海南热带海洋学院引进人才科研启动资助项目(RHDRC202002)
  • 海南省大学生创新创业训练计划(S202111100049)
2023年第43卷第4期
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doi: 10.3969/j.issn.0253-6099.2023.04.036
  • 接收时间:2023-03-11
  • 首发时间:2026-03-05
  • 出版时间:2023-08-01
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  • 收稿日期:2023-03-11
基金
国家自然科学基金(52074099; 52164029)
海南省自然科学基金(821MS0782; 221MS048; 221RC585)
海南热带海洋学院引进人才科研启动资助项目(RHDRC202002)
海南省大学生创新创业训练计划(S202111100049)
作者信息
    1.海南热带海洋学院 海洋科学技术学院,海南 三亚 572022
    2.海南热带海洋学院 崖州湾创新研究院,海南 三亚 572022

通讯作者:

刘洁群(1975—),女,江西吉安人,硕士,实验师,主要研究方向为海洋船舶动力电池材料等。
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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