Article(id=1236327869371175547, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236327863171993957, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2023.02.014, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1665936000000, receivedDateStr=2022-10-17, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1772693133919, onlineDateStr=2026-03-05, pubDate=1680278400000, pubDateStr=2023-04-01, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1772693133919, onlineIssueDateStr=2026-03-05, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1772693133919, creator=13701087609, updateTime=1772693133919, updator=13701087609, issue=Issue{id=1236327863171993957, tenantId=1146029695717560320, journalId=1235980550691926019, year='2023', volume='43', issue='2', pageStart='1', pageEnd='170', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1772693132441, creator=13701087609, updateTime=1772693403732, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1236329001107640372, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236327863171993957, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1236329001107640373, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236327863171993957, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=61, endPage=65, ext={EN=ArticleExt(id=1236327869631222416, articleId=1236327869371175547, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Dispersion Mechanism of Sodium Hexametaphosphate on Potassium Feldspar and Hematite, columnId=1236276106932842717, journalTitle=Mining and Metallurgical Engineering, columnName=MINERAL PROCESSING, runingTitle=null, highlight=null, articleAbstract=

By performing settling rate test, turbidity test, zeta potential measurements, solution chemistry study and extended DLVO theoretical analysis, the mechanism for sodium hexametaphosphate (SHMP) to disperse ultrafine potassium feldspar and hematite was investigated. It is shown that, Nam (PO3)nm-n (m<n) anions derived from SHMP ionization can wrap around mineral grains in a form of spiral long-chain polymers, forming thick hydrophilic macromolecule protective films. Meanwhile, HPO42-formed by hydrolysis can be adsorbed onto ore grains, leading to decrease of the surface potential and increase of the interparticle electrostatic and steric repulsions. In this case, mineral particles need to overcome a higher potential barrier to reach a stable condensed state. Therewith, the non-selective agglomeration of ore particles weakens, resulting in a significant improvement in dispersion stability.

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通过沉降率实验、浊度实验、Zeta电位测定、溶液化学分析以及扩展DLVO理论分析,揭示了六偏磷酸钠对微细粒钾长石和赤铁矿的分散作用。结果表明,六偏磷酸钠电离产生的Nam(PO3nm-nm<n)阴离子会以螺旋状长链聚合体形式包裹在矿粒表面,形成厚厚的大分子亲水保护膜;水解生成的HPO42-会吸附在矿粒表面,导致矿粒表面电位降低、矿粒间静电斥力以及空间位阻效应增强,矿粒达到稳定凝聚态需要克服的势垒增大,矿粒间非选择性团聚现象减弱,分散体系稳定性显著增强。

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黄红军(1980-),男,湖南永州人,博士,副教授,主要研究方向为矿物加工工程学、二次资源综合利用等。
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舒有顺(1995—),男,云南昭通人,硕士研究生,主要研究方向为矿产资源综合利用。

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舒有顺(1995—),男,云南昭通人,硕士研究生,主要研究方向为矿产资源综合利用。

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六偏磷酸钠对钾长石和赤铁矿的分散作用机理
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舒有顺 , 曾海鹏 , 黄红军
矿冶工程杂志 | 选矿 2023,43(2): 61-65
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矿冶工程杂志 | 选矿 2023, 43(2): 61-65
六偏磷酸钠对钾长石和赤铁矿的分散作用机理
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舒有顺, 曾海鹏, 黄红军
作者信息
  • 中南大学 资源加工与生物工程学院,湖南 长沙 410083
  • 舒有顺(1995—),男,云南昭通人,硕士研究生,主要研究方向为矿产资源综合利用。

通讯作者:

黄红军(1980-),男,湖南永州人,博士,副教授,主要研究方向为矿物加工工程学、二次资源综合利用等。
Dispersion Mechanism of Sodium Hexametaphosphate on Potassium Feldspar and Hematite
Youshun SHU, Haipeng ZENG, Hongjun HUANG
Affiliations
  • School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, Hunan, China
出版时间: 2023-04-01 doi: 10.3969/j.issn.0253-6099.2023.02.014
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通过沉降率实验、浊度实验、Zeta电位测定、溶液化学分析以及扩展DLVO理论分析,揭示了六偏磷酸钠对微细粒钾长石和赤铁矿的分散作用。结果表明,六偏磷酸钠电离产生的Nam(PO3nm-nm<n)阴离子会以螺旋状长链聚合体形式包裹在矿粒表面,形成厚厚的大分子亲水保护膜;水解生成的HPO42-会吸附在矿粒表面,导致矿粒表面电位降低、矿粒间静电斥力以及空间位阻效应增强,矿粒达到稳定凝聚态需要克服的势垒增大,矿粒间非选择性团聚现象减弱,分散体系稳定性显著增强。

分散  /  六偏磷酸钠  /  钾长石  /  赤铁矿  /  扩展DLVO理论

By performing settling rate test, turbidity test, zeta potential measurements, solution chemistry study and extended DLVO theoretical analysis, the mechanism for sodium hexametaphosphate (SHMP) to disperse ultrafine potassium feldspar and hematite was investigated. It is shown that, Nam (PO3)nm-n (m<n) anions derived from SHMP ionization can wrap around mineral grains in a form of spiral long-chain polymers, forming thick hydrophilic macromolecule protective films. Meanwhile, HPO42-formed by hydrolysis can be adsorbed onto ore grains, leading to decrease of the surface potential and increase of the interparticle electrostatic and steric repulsions. In this case, mineral particles need to overcome a higher potential barrier to reach a stable condensed state. Therewith, the non-selective agglomeration of ore particles weakens, resulting in a significant improvement in dispersion stability.

dispersion  /  sodium hexametaphosphate  /  potassium feldspar  /  hematite  /  extended DLVO theory
舒有顺, 曾海鹏, 黄红军. 六偏磷酸钠对钾长石和赤铁矿的分散作用机理. 矿冶工程杂志, 2023 , 43 (2) : 61 -65 . DOI: 10.3969/j.issn.0253-6099.2023.02.014
Youshun SHU, Haipeng ZENG, Hongjun HUANG. Dispersion Mechanism of Sodium Hexametaphosphate on Potassium Feldspar and Hematite[J]. Mining and Metallurgical Engineering, 2023 , 43 (2) : 61 -65 . DOI: 10.3969/j.issn.0253-6099.2023.02.014
  • 高等学校学科创新引智计划资助(B14034)
2023年第43卷第2期
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doi: 10.3969/j.issn.0253-6099.2023.02.014
  • 接收时间:2022-10-17
  • 首发时间:2026-03-05
  • 出版时间:2023-04-01
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  • 收稿日期:2022-10-17
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高等学校学科创新引智计划资助(B14034)
作者信息
    中南大学 资源加工与生物工程学院,湖南 长沙 410083

通讯作者:

黄红军(1980-),男,湖南永州人,博士,副教授,主要研究方向为矿物加工工程学、二次资源综合利用等。
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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