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Arsenic-iron slag were treated by using magnetizing reduction for recovering arsenic and iron therein, and the experimental conditions were optimized as follows: roasting at 650 ℃ for 180 min, adding carbon at an amount of 25% and protecting with argon. Under such conditions, the arsenic volatilization rate reached 97.25% and arsenic content in the roasted slag decreased to 0.61%. It is found that arsenic can be recovered in the form of As₂O₃, with purity up to 99.13%, while iron therein is magnetized and can be recovered in the form of Fe₃O₄ by magnetic separation. Therefore, this process can actualize the resource utilization of arsenic-iron slag.

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采用磁化还原法回收砷铁渣中的砷和铁，优化实验条件为：焙烧温度650 ℃、碳加入量25%、焙烧时间180 min、氩气保护，此条件下砷挥发率达97.25%，焙烧渣中砷含量降至0.61%；砷以As_2O3形式回收，纯度为99.13%；砷铁渣中铁被磁化，可采用磁选法以Fe₃O₄形式回收。该工艺实现了砷铁渣资源化利用。

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李学鹏（1985—）男，江西丰城人，博士，高级工程师，主要从事含砷物料处理工作。

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李学鹏（1985—）男，江西丰城人，博士，高级工程师，主要从事含砷物料处理工作。

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