Article(id=1236327867248857577, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236327863171993957, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2023.02.011, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1665763200000, receivedDateStr=2022-10-15, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1772693133413, onlineDateStr=2026-03-05, pubDate=1680278400000, pubDateStr=2023-04-01, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1772693133413, onlineIssueDateStr=2026-03-05, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1772693133413, creator=13701087609, updateTime=1772693133413, updator=13701087609, issue=Issue{id=1236327863171993957, tenantId=1146029695717560320, journalId=1235980550691926019, year='2023', volume='43', issue='2', pageStart='1', pageEnd='170', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1772693132441, creator=13701087609, updateTime=1772693403732, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1236329001107640372, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236327863171993957, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1236329001107640373, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236327863171993957, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=48, endPage=51, ext={EN=ArticleExt(id=1236327867500515830, articleId=1236327867248857577, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Effect of Ce³⁺ in Sodium Oleate System on Flotation of Fluorite and Calcite, columnId=1236276106932842717, journalTitle=Mining and Metallurgical Engineering, columnName=MINERAL PROCESSING, runingTitle=null, highlight=null, articleAbstract=

The influence of Ce³⁺ in the sodium oleate system on the flotation of fluorite and calcite was investigated by flotation test, zeta potential measurement, solution chemistry study and X-ray photoelectron spectroscopy analysis. The results reveal that in the sodium oleate system, Ce³⁺ with a low concentration exists on fluorite surface in the form of CeF₃·0.5H₂O(s) under acidic and neutral conditions, therewith, fluorite can be activated to generate more active sites for the adsorption of sodium oleate. Meanwhile, Ce³⁺ can be adsorbed onto calcite in the form of Ce₂ (CO₃)₃·8H₂O(s). There are more active sites generated as well, but calcite may be depressed as the hydrophilic nature of Ce₂ (CO₃)₃·8H₂O(s) and the spatial site barrier effect of crystalline water hinder the adsorption of sodium oleate. In alkaline pulp, Ce³⁺ is mostly precipitated to form Ce(OH)₃(s) and depresses both fluorite and calcite as Ce(OH)₃ (s) can consume sodium oleate and reduce its adsorption on both minerals.

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通过浮选试验、Zeta电位测试、溶液化学分析以及X射线光电子能谱分析等手段，研究了油酸钠体系中铈离子对萤石和方解石浮选行为的影响。结果表明，在油酸钠体系中，较低浓度的铈离子在酸性以及中性条件下以CeF₃·0.5H₂O（s）形式存在于萤石表面，为油酸钠的吸附提供了更多的活性位点，可对萤石产生活化作用；同时也会以Ce₂（CO₃）₃·8H₂O（s）形式存在于方解石表面，虽然也提供了更多的活性位点，但Ce₂（CO₃）₃·8H₂O（s）的亲水性以及结晶水的空间位阻效应阻碍了油酸钠在方解石表面的吸附，对方解石产生抑制作用。铈离子在碱性条件下多以Ce（OH）₃（s）形式存在于矿浆体系中，消耗了油酸钠，减少了油酸钠在萤石和方解石表面的吸附量，对二者均产生抑制作用。

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汤家焰（1989—），男，湖北荆州人，博士，讲师，研究方向为复杂矿产资源综合回收利用。

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汤家焰（1989—），男，湖北荆州人，博士，讲师，研究方向为复杂矿产资源综合回收利用。

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