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Based on the analysis of existence forms of molybdenum and iron ions in acidic solution with different pH, the solvent extraction processes available for separating molybdenum from iron were classified, for which the principles, effects, advantages and disadvantages were also discussed in detail. Moreover, the potential development trend of the solvent extraction for molybdenum and iron separation in the future is prospected, thus providing ideas for the research and development of a green and efficient process for separating molybdenum and iron from acidic solutions.

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分析了不同溶液酸度条件下钼、铁离子的存在形态,并依此对现有的钼/铁溶剂萃取分离方法进行了分类,讨论了各方法的原理、效果及其优缺点。并对未来溶剂萃取法钼/铁分离可能的发展方向进行了展望,以期能为绿色、高效的酸溶液中钼/铁萃取分离新工艺研发及应用提供思路。

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李飞(1984—),男,湖南新宁人,博士,副教授,主要从事湿法冶金与相似元素分离研究。

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李飞(1984—),男,湖南新宁人,博士,副教授,主要从事湿法冶金与相似元素分离研究。

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李飞(1984—),男,湖南新宁人,博士,副教授,主要从事湿法冶金与相似元素分离研究。

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酸溶液中溶剂萃取法分离钼(Ⅵ)/铁(Ⅲ)的研究进展
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李飞 1, 2 , 彭苗苗 1 , 胡智怡 1 , 刘纯 1 , 肖莉琼 1 , 刘志雄 1, 2 , 颜文斌 1, 2
矿冶工程杂志 | 冶金 2023,43(2): 118-124
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矿冶工程杂志 | 冶金 2023, 43(2): 118-124
酸溶液中溶剂萃取法分离钼(Ⅵ)/铁(Ⅲ)的研究进展
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李飞1, 2, 彭苗苗1, 胡智怡1, 刘纯1, 肖莉琼1, 刘志雄1, 2, 颜文斌1, 2
作者信息
  • 1.吉首大学 化学化工学院,湖南 吉首 416000
  • 2.吉首大学 矿物清洁生产与绿色功能材料开发湖南省重点实验室,湖南 吉首 416000
  • 李飞(1984—),男,湖南新宁人,博士,副教授,主要从事湿法冶金与相似元素分离研究。

Research Progress in Separation of Molybdenum (Ⅵ) and Iron (Ⅲ) in Acidic Solutions by Solvent Extraction
Fei LI1, 2, Miaomiao PENG1, Zhiyi HU1, Chun LIU1, Liqiong XIAO1, Zhixiong LIU1, 2, Wenbin YAN1, 2
Affiliations
  • 1.School of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, Hunan, China
  • 2.Hunan Key Laboratory of Cleaner Mineral Production and Development of Green Functional Materials, Jishou University, Jishou 416000, Hunan, China
出版时间: 2023-04-01 doi: 10.3969/j.issn.0253-6099.2023.02.027
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分析了不同溶液酸度条件下钼、铁离子的存在形态,并依此对现有的钼/铁溶剂萃取分离方法进行了分类,讨论了各方法的原理、效果及其优缺点。并对未来溶剂萃取法钼/铁分离可能的发展方向进行了展望,以期能为绿色、高效的酸溶液中钼/铁萃取分离新工艺研发及应用提供思路。

酸法提钼  /  溶剂萃取  /  钼/铁分离  /  离子液体  /  抑制效应  /  Mo(Ⅵ)  /  Fe(Ⅲ)

Based on the analysis of existence forms of molybdenum and iron ions in acidic solution with different pH, the solvent extraction processes available for separating molybdenum from iron were classified, for which the principles, effects, advantages and disadvantages were also discussed in detail. Moreover, the potential development trend of the solvent extraction for molybdenum and iron separation in the future is prospected, thus providing ideas for the research and development of a green and efficient process for separating molybdenum and iron from acidic solutions.

extraction of molybdenum from acid solution  /  solvent extraction  /  separation of molybdenum from iron  /  ionic liquid  /  inhibiting effect  /  Mo (Ⅵ)  /  Fe (Ⅲ)
李飞, 彭苗苗, 胡智怡, 刘纯, 肖莉琼, 刘志雄, 颜文斌. 酸溶液中溶剂萃取法分离钼(Ⅵ)/铁(Ⅲ)的研究进展. 矿冶工程杂志, 2023 , 43 (2) : 118 -124 . DOI: 10.3969/j.issn.0253-6099.2023.02.027
Fei LI, Miaomiao PENG, Zhiyi HU, Chun LIU, Liqiong XIAO, Zhixiong LIU, Wenbin YAN. Research Progress in Separation of Molybdenum (Ⅵ) and Iron (Ⅲ) in Acidic Solutions by Solvent Extraction[J]. Mining and Metallurgical Engineering, 2023 , 43 (2) : 118 -124 . DOI: 10.3969/j.issn.0253-6099.2023.02.027
  • 湖南省自然科学基金(2020JJ5456; 2020JJ4507)
  • 湖南省研究生科研创新项目(CX20221108)
2023年第43卷第2期
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doi: 10.3969/j.issn.0253-6099.2023.02.027
  • 接收时间:2022-11-08
  • 首发时间:2026-03-05
  • 出版时间:2023-04-01
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  • 收稿日期:2022-11-08
基金
湖南省自然科学基金(2020JJ5456; 2020JJ4507)
湖南省研究生科研创新项目(CX20221108)
作者信息
    1.吉首大学 化学化工学院,湖南 吉首 416000
    2.吉首大学 矿物清洁生产与绿色功能材料开发湖南省重点实验室,湖南 吉首 416000
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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