Article(id=1236319265687663287, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236316193171239730, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2023.03.033, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1669219200000, receivedDateStr=2022-11-24, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1772691082640, onlineDateStr=2026-03-05, pubDate=1685548800000, pubDateStr=2023-06-01, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1772691082640, onlineIssueDateStr=2026-03-05, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1772691082640, creator=13701087609, updateTime=1772691082640, updator=13701087609, issue=Issue{id=1236316193171239730, tenantId=1146029695717560320, journalId=1235980550691926019, year='2023', volume='43', issue='3', pageStart='1', pageEnd='179', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1772690350096, creator=13701087609, updateTime=1772691872061, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1236322576809652696, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236316193171239730, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1236322576809652697, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1236316193171239730, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=145, endPage=150, ext={EN=ArticleExt(id=1236319267587683099, articleId=1236319265687663287, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Research Status of Anti-oxidation and Anti-corrosion Treatment Technology for LIBs Copper Foil, columnId=1236276108207902848, journalTitle=Mining and Metallurgical Engineering, columnName=MATERIALS, runingTitle=null, highlight=null, articleAbstract=

The problems of oxidation and corrosion of LIBs copper foil in its production and application have restricted its service life and battery safety. Based on the research status of anti-oxidation technologies for LIBs copper foil in recent years, the mechanism of different passivation methods is summarized. After an introduction of the corrosion mechanism of copper foil fluid in Li-ion battery electrolyte, the research progress in improving corrosion resistance by modification of copper foil surface is reviewed. On this basis, the prospects of chromium-free passivation technology and surface modification technologies for copper foil are presented. At last, a clean, eco-friendly and efficient anti-oxidation and anti-corrosion concept is proposed.

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针对锂电铜箔在生产和应用环节存在氧化、腐蚀,影响其服役寿命和电池安全性的问题,归纳了锂电铜箔防氧化处理技术,总结了不同钝化方法的机理;概述了铜箔集流体在锂电池电解液中的腐蚀机理,综述了铜箔表面改性增强耐腐性能的研究进展;对铜箔无铬钝化处理技术及表面改性技术进行了展望;提出了清洁环保、高效的锂电铜箔防氧化、防腐蚀设想。

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朱茂兰(1978—),女,江西赣州人,副教授,硕士研究生导师,主要从事电极功能材料等研究。
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衷水平(1977—),男,江西赣州人,博士,高级工程师,主要从事稀贵金属提取、利用研究等。

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衷水平(1977—),男,江西赣州人,博士,高级工程师,主要从事稀贵金属提取、利用研究等。

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衷水平 1, 2, 3 , 朱焕林 1, 2 , 杨蕾 1, 2 , 翁威 1, 2 , 迟晓鹏 1, 2 , 朱茂兰 4
矿冶工程杂志 | 材料 2023,43(3): 145-150
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矿冶工程杂志 | 材料 2023, 43(3): 145-150
锂电铜箔防氧化抗腐蚀处理技术研究现状
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衷水平1, 2, 3, 朱焕林1, 2, 杨蕾1, 2, 翁威1, 2, 迟晓鹏1, 2, 朱茂兰4
作者信息
  • 1.福州大学 紫金地质与矿业学院,福建 福州 350108
  • 2.福建省新能源金属绿色提取与高值利用重点实验室,福建 福州 350108
  • 3.紫金矿业集团股份有限公司,福建 龙岩 364200
  • 4.厦门理工学院 材料科学与工程学院,福建 厦门 361024
  • 衷水平(1977—),男,江西赣州人,博士,高级工程师,主要从事稀贵金属提取、利用研究等。

通讯作者:

朱茂兰(1978—),女,江西赣州人,副教授,硕士研究生导师,主要从事电极功能材料等研究。
Research Status of Anti-oxidation and Anti-corrosion Treatment Technology for LIBs Copper Foil
Shuiping ZHONG1, 2, 3, Huanlin ZHU1, 2, Lei YANG1, 2, Wei WENG1, 2, Xiaopeng CHI1, 2, Maolan ZHU4
Affiliations
  • 1.Zijin School of Geology and Mining, Fuzhou University, Fuzhou 350108, Fujian, China
  • 2.Fujian Provincial Key Laboratory of Green Extraction and High Value Utilization of New Energy Metals, Fuzhou 350108, Fujian, China
  • 3.Zijin Mining Group Co Ltd, Longyan 364200, Fujian, China
  • 4.School of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361024, Fujian, China
出版时间: 2023-06-01 doi: 10.3969/j.issn.0253-6099.2023.03.033
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针对锂电铜箔在生产和应用环节存在氧化、腐蚀,影响其服役寿命和电池安全性的问题,归纳了锂电铜箔防氧化处理技术,总结了不同钝化方法的机理;概述了铜箔集流体在锂电池电解液中的腐蚀机理,综述了铜箔表面改性增强耐腐性能的研究进展;对铜箔无铬钝化处理技术及表面改性技术进行了展望;提出了清洁环保、高效的锂电铜箔防氧化、防腐蚀设想。

锂离子电池  /  铜箔  /  负极集流体  /  表面处理  /  防氧化  /  防腐蚀

The problems of oxidation and corrosion of LIBs copper foil in its production and application have restricted its service life and battery safety. Based on the research status of anti-oxidation technologies for LIBs copper foil in recent years, the mechanism of different passivation methods is summarized. After an introduction of the corrosion mechanism of copper foil fluid in Li-ion battery electrolyte, the research progress in improving corrosion resistance by modification of copper foil surface is reviewed. On this basis, the prospects of chromium-free passivation technology and surface modification technologies for copper foil are presented. At last, a clean, eco-friendly and efficient anti-oxidation and anti-corrosion concept is proposed.

Li-ion battery  /  copper foil  /  negative collector  /  surface treatment  /  anti-oxidation  /  anti-corrosion
衷水平, 朱焕林, 杨蕾, 翁威, 迟晓鹏, 朱茂兰. 锂电铜箔防氧化抗腐蚀处理技术研究现状. 矿冶工程杂志, 2023 , 43 (3) : 145 -150 . DOI: 10.3969/j.issn.0253-6099.2023.03.033
Shuiping ZHONG, Huanlin ZHU, Lei YANG, Wei WENG, Xiaopeng CHI, Maolan ZHU. Research Status of Anti-oxidation and Anti-corrosion Treatment Technology for LIBs Copper Foil[J]. Mining and Metallurgical Engineering, 2023 , 43 (3) : 145 -150 . DOI: 10.3969/j.issn.0253-6099.2023.03.033
  • 国家自然科学基金(52274349)
  • 国家自然科学基金面上项目(51874101)
2023年第43卷第3期
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doi: 10.3969/j.issn.0253-6099.2023.03.033
  • 接收时间:2022-11-24
  • 首发时间:2026-03-05
  • 出版时间:2023-06-01
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  • 收稿日期:2022-11-24
基金
国家自然科学基金(52274349)
国家自然科学基金面上项目(51874101)
作者信息
    1.福州大学 紫金地质与矿业学院,福建 福州 350108
    2.福建省新能源金属绿色提取与高值利用重点实验室,福建 福州 350108
    3.紫金矿业集团股份有限公司,福建 龙岩 364200
    4.厦门理工学院 材料科学与工程学院,福建 厦门 361024

通讯作者:

朱茂兰(1978—),女,江西赣州人,副教授,硕士研究生导师,主要从事电极功能材料等研究。
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https://castjournals.cast.org.cn/joweb/kygczz/CN/10.3969/j.issn.0253-6099.2023.03.033
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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