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The problems of oxidation and corrosion of LIBs copper foil in its production and application have restricted its service life and battery safety. Based on the research status of anti-oxidation technologies for LIBs copper foil in recent years, the mechanism of different passivation methods is summarized. After an introduction of the corrosion mechanism of copper foil fluid in Li-ion battery electrolyte, the research progress in improving corrosion resistance by modification of copper foil surface is reviewed. On this basis, the prospects of chromium-free passivation technology and surface modification technologies for copper foil are presented. At last, a clean, eco-friendly and efficient anti-oxidation and anti-corrosion concept is proposed.
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针对锂电铜箔在生产和应用环节存在氧化、腐蚀,影响其服役寿命和电池安全性的问题,归纳了锂电铜箔防氧化处理技术,总结了不同钝化方法的机理;概述了铜箔集流体在锂电池电解液中的腐蚀机理,综述了铜箔表面改性增强耐腐性能的研究进展;对铜箔无铬钝化处理技术及表面改性技术进行了展望;提出了清洁环保、高效的锂电铜箔防氧化、防腐蚀设想。
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朱茂兰(1978—),女,江西赣州人,副教授,硕士研究生导师,主要从事电极功能材料等研究。
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衷水平(1977—),男,江西赣州人,博士,高级工程师,主要从事稀贵金属提取、利用研究等。
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衷水平(1977—),男,江西赣州人,博士,高级工程师,主要从事稀贵金属提取、利用研究等。
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1.Zijin School of Geology and Mining, Fuzhou University, Fuzhou 350108, Fujian, China
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1.Zijin School of Geology and Mining, Fuzhou University, Fuzhou 350108, Fujian, China
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1.福州大学 紫金地质与矿业学院,福建 福州 350108
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