Article(id=1314908301754725032, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, articleNumber=null, orderNo=null, doi=10.3969/j.issn.0253-6099.2026.04.022, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1771084800000, receivedDateStr=2026-02-15, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1791428168952, onlineDateStr=2026-10-08, pubDate=null, pubDateStr=null, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1791428168952, onlineIssueDateStr=2026-10-08, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1791428168952, creator=13701087609, updateTime=1791428168952, updator=13701087609, issue=Issue{id=1314908074188562588, tenantId=1146029695717560320, journalId=1235980550691926019, year='2026', volume='46', issue='4', pageStart='1', pageEnd='266', issueExtLink='null', onlineDate='null', pubDate='1785513600000', pubDateStr='2026-08-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1791428114697, creator='13701087609', updateTime=1791430419337, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1314917740654191268, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1314917740654191269, tenantId=1146029695717560320, journalId=1235980550691926019, issueId=1314908074188562588, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=145, endPage=149, ext={EN=ArticleExt(id=1314908303579247273, articleId=1314908301754725032, tenantId=1146029695717560320, journalId=1235980550691926019, language=EN, title=Synthesis of 4-(Chloromethyl) Benzohydroxamic Acid and Its Flotation Performance for Wolframite, columnId=1236276106932842717, journalTitle=Mining and Metallurgical Engineering, columnName=MINERAL PROCESSING, runingTitle=null, highlight=null, articleAbstract=

Conventional hydroxamic acid collectors suffer from weak collecting capacity and high dosage consumption. To address these drawbacks, 4-(chloromethyl) benzohydroxamic acid was synthesized, and its flotation performance for wolframite was systematically investigated. With methyl 4-(chloromethyl) benzoate, hydroxylamine hydrochloride and sodium hydroxide as raw materials, the optimal synthesis conditions were determined as follows:methyl 4-(chloromethyl) benzoate, hydroxylamine hydrochloride and sodium hydroxide in a molar ratio of 1∶1.2∶ 2.35, reaction temperature of 35 ℃, reaction time of 4 h, and pH of 5 at the terminal acidification. Tests on flotation of wolframite indicate that 4-(chloromethyl) benzohydroxamic acid outperforms benzohydroxamic acid in collecting ability. To achieve equivalent flotation indices, the required dosage of the synthesized reagent is lower than that of benzohydroxamic acid.

, authors=Lei HAN1, 2, 3, Yunbo LUO1, 2, 3, 4, Ruipeng CHEN1, 2, 3, Faming ZHANG1, 2, 3, Zhenxuan XIE1, authorsList=Lei HAN, Yunbo LUO, Ruipeng CHEN, Faming ZHANG, Zhenxuan XIE, authorCompany=null, correspAuthors=Yunbo LUO, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1314908304233558698, articleId=1314908301754725032, tenantId=1146029695717560320, journalId=1235980550691926019, language=CN, title=对氯甲基苯甲羟肟酸的合成及其对黑钨矿的浮选性能, columnId=1236276107125780707, journalTitle=矿冶工程杂志, columnName=选矿, runingTitle=null, highlight=null, articleAbstract=

针对现有羟肟酸类捕收剂捕收能力不足、用量大等问题,合成了对氯甲基苯甲羟肟酸,并考察了其对黑钨矿的浮选性能。以对氯甲基苯甲酸甲酯、盐酸羟胺、氢氧化钠为原料,合成对氯甲基苯甲羟肟酸的适宜条件为:对氯甲基苯甲酸甲酯、盐酸羟胺、氢氧化钠物质的量比1∶1.2∶2.35,反应温度35 ℃,反应时间4 h,酸化终点pH值为5。黑钨矿浮选试验结果表明,对氯甲基苯甲羟肟酸对黑钨矿的浮选性能优于苯甲羟肟酸,在浮选指标相当的情况下,对氯甲基苯甲羟肟酸比苯甲羟肟酸用量更低。

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韩雷(1987—),男,安徽亳州人,硕士,工程师,主要从事选矿药剂与工艺开发工作。E-mail:

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罗云波(1987—),男,湖南永州人,博士研究生,高级工程师,主要从事选矿工艺与药剂研发工作。E-mail:
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对氯甲基苯甲羟肟酸的合成及其对黑钨矿的浮选性能
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韩雷 1, 2, 3 , 罗云波 1, 2, 3, 4 , 陈锐鹏 1, 2, 3 , 张发明 1, 2, 3 , 谢臻璇 1
矿冶工程杂志 | 选矿 2026,46(4): 145-149
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矿冶工程杂志 |选矿 2026 , 46 (4) : 145 -149
对氯甲基苯甲羟肟酸的合成及其对黑钨矿的浮选性能
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韩雷(1987—),男,安徽亳州人,硕士,工程师,主要从事选矿药剂与工艺开发工作。E-mail:

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韩雷1, 2, 3 , 罗云波1, 2, 3, 4 , 陈锐鹏1, 2, 3, 张发明1, 2, 3, 谢臻璇1
作者信息
  • 1.广州粤有研矿物资源科技有限公司,广东 广州 510650
  • 2.广东省科学院资源利用与稀土开发研究所,广东 广州 510650
  • 3.稀有金属分离与综合利用国家重点实验室,广东 广州 510650
  • 4.郑州大学 化工学院,河南 郑州 450001
通讯作者:
罗云波(1987—),男,湖南永州人,博士研究生,高级工程师,主要从事选矿工艺与药剂研发工作。E-mail:
作者简介:

韩雷(1987—),男,安徽亳州人,硕士,工程师,主要从事选矿药剂与工艺开发工作。E-mail:

Synthesis of 4-(Chloromethyl) Benzohydroxamic Acid and Its Flotation Performance for Wolframite
Lei HAN1, 2, 3 , Yunbo LUO1, 2, 3, 4 , Ruipeng CHEN1, 2, 3, Faming ZHANG1, 2, 3, Zhenxuan XIE1
Affiliations
  • 1.Guangzhou Yueyouyan Mineral Resources Technology Co., Ltd., Guangzhou 510650, Guangdong, China
  • 2.Guangdong Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences, Guangzhou 510650, Guangdong, China
  • 3.State Key Laboratory of Rare Metals Separation and Comprehensive Utilization, Guangzhou 510650, Guangdong, China
  • 4.School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China
doi: 10.3969/j.issn.0253-6099.2026.04.022
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针对现有羟肟酸类捕收剂捕收能力不足、用量大等问题,合成了对氯甲基苯甲羟肟酸,并考察了其对黑钨矿的浮选性能。以对氯甲基苯甲酸甲酯、盐酸羟胺、氢氧化钠为原料,合成对氯甲基苯甲羟肟酸的适宜条件为:对氯甲基苯甲酸甲酯、盐酸羟胺、氢氧化钠物质的量比1∶1.2∶2.35,反应温度35 ℃,反应时间4 h,酸化终点pH值为5。黑钨矿浮选试验结果表明,对氯甲基苯甲羟肟酸对黑钨矿的浮选性能优于苯甲羟肟酸,在浮选指标相当的情况下,对氯甲基苯甲羟肟酸比苯甲羟肟酸用量更低。

对氯甲基苯甲羟肟酸  /  合成  /  黑钨矿  /  钨  /  浮选  /  捕收剂

Conventional hydroxamic acid collectors suffer from weak collecting capacity and high dosage consumption. To address these drawbacks, 4-(chloromethyl) benzohydroxamic acid was synthesized, and its flotation performance for wolframite was systematically investigated. With methyl 4-(chloromethyl) benzoate, hydroxylamine hydrochloride and sodium hydroxide as raw materials, the optimal synthesis conditions were determined as follows:methyl 4-(chloromethyl) benzoate, hydroxylamine hydrochloride and sodium hydroxide in a molar ratio of 1∶1.2∶ 2.35, reaction temperature of 35 ℃, reaction time of 4 h, and pH of 5 at the terminal acidification. Tests on flotation of wolframite indicate that 4-(chloromethyl) benzohydroxamic acid outperforms benzohydroxamic acid in collecting ability. To achieve equivalent flotation indices, the required dosage of the synthesized reagent is lower than that of benzohydroxamic acid.

4-(chloromethyl) benzohydroxamic acid  /  synthesis  /  wolframite  /  tungsten  /  flotation  /  collector
韩雷, 罗云波, 陈锐鹏, 张发明, 谢臻璇. 对氯甲基苯甲羟肟酸的合成及其对黑钨矿的浮选性能. 矿冶工程杂志, 2026 , 46 (4) : 145 -149 . DOI: 10.3969/j.issn.0253-6099.2026.04.022
Lei HAN, Yunbo LUO, Ruipeng CHEN, Faming ZHANG, Zhenxuan XIE. Synthesis of 4-(Chloromethyl) Benzohydroxamic Acid and Its Flotation Performance for Wolframite[J]. Mining and Metallurgical Engineering, 2026 , 46 (4) : 145 -149 . DOI: 10.3969/j.issn.0253-6099.2026.04.022

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doi: 10.3969/j.issn.0253-6099.2026.04.022
  • 接收时间:2026-02-15
  • 首发时间:2026-10-08
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  • 收稿日期:2026-02-15
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    1.广州粤有研矿物资源科技有限公司,广东 广州 510650
    2.广东省科学院资源利用与稀土开发研究所,广东 广州 510650
    3.稀有金属分离与综合利用国家重点实验室,广东 广州 510650
    4.郑州大学 化工学院,河南 郑州 450001

通讯作者:

罗云波(1987—),男,湖南永州人,博士研究生,高级工程师,主要从事选矿工艺与药剂研发工作。E-mail:
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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